인화 알루미늄

한글명:인화 알루미늄

카스 번호20859-73-8

상품명:Aluminum phosphide

CBNumberCB5319619

분자식AlP

포뮬러 무게57.96

MOL 파일20859-73-8.mol

동의어(한글)

모노인산알루미늄

인화알루미늄

화학적 성질

녹는점	2000℃
밀도	2.42
용해도	reacts with H2O
물리적 상태	녹색 또는 노란색 입방 결정
색상	녹색 또는 노란색
수용성	H2O와 반응하여 포스핀을 생성함 [MER06]
Crystal Structure	Cubic, Sphalerite Structure - Space Group F(-4)3m
안정성	가연성 고체. 산과 접촉하면 독성이 강한 가스(포스핀)가 방출됩니다. 산, 습기, 산화제와 호환되지 않습니다.
CAS 데이터베이스	20859-73-8(CAS DataBase Reference)
NIST	Aluminum monophosphide(20859-73-8)
EPA	Aluminum phosphide (20859-73-8)

위험 및 안전 성명

위험품 표기

F,T+,N

위험 카페고리 넘버

15/29-28-32-50

안전지침서

3/9/14-30-36/37-45-61

유엔번호(UN No.)

1397

위험 등급

4.3

포장분류

유해 물질 데이터

20859-73-8(Hazardous Substances Data)

NFPA 704:

	4
4		2
	W

그림문자(GHS)

그림문자(GHS)
신호 어

Danger
유해·위험 문구

H260：물과 접촉시 자연 발화성 인화성 가스를 발생시킴

H300：삼키면 치명적임

H311：피부와 접촉하면 유독함

H330：흡입하면 치명적임

H400：수생생물에 매우 유독함
예방조치문구

P223：물과 접촉하지 마시오.

P231+P232：불활성 기체 하에서 취급하고, 습기를 방지하시오.

P260：분진·흄·가스·미스트·증기·...·스프레이를 흡입하지 마시오.

P264：취급 후에는 손을 철저히 씻으시오.

P264：취급 후에는 손을 철저히 씻으시오.

P270：이 제품을 사용할 때에는 먹거나, 마시거나 흡연하지 마시오.

P271：옥외 또는 환기가 잘 되는 곳에서만 취급하시오.

P273：환경으로 배출하지 마시오.

P280：보호장갑/보호의/보안경/안면보호구를 착용하시오.

P284：호흡 보호구를 착용하시오.

P301+P310：삼켰다면 즉시 의료기관(의사)의 진찰을 받으시오.

P302+P352：피부에 묻으면 다량의 물로 씻으시오.

P304+P340：흡입하면 신선한 공기가 있는 곳으로 옮기고 호흡하기 쉬운 자세로 안정을 취하시오.

P310：즉시 의료기관(의사)의 진찰을 받으시오. 삼켰다면 즉시 의료기관(의사)의 도움을 받으시오.

P312：불편함을 느끼면 의료기관(의사)의 진찰을 받으시오.

P320：긴급히 (…) 처치를 하시오.

P321：(…) 처치를 하시오.

P322：특정 조치(라벨의 … 참조)

P330：입을 씻어내시오.

P335+P334：피부에 묻은 물질을 털어내고, 차가운 물에 담그거나 젖은 붕대로 감싸시오.

P361：즉시 오염된 의복을 모두 벗을 것

P363：다시 사용전 오염된 의류는 세척하시오.

P370+P378：화재 시 불을 끄기 위해 (Section 5. 폭발, 화재시 대처방법의 적절한 소화제)을(를) 사용하시오.

P391：누출물을 모으시오.

P402+P404：건조한 장소에 보관하시오. 밀폐된 용기에 보관하시오.

P403+P233：용기는 환기가 잘 되는 곳에 단단히 밀폐하여 저장하시오.

P405：밀봉하여 저장하시오.

P501：...에 내용물 / 용기를 폐기 하시오.

인화 알루미늄 MSDS

인화 알루미늄 화학적 특성, 용도, 생산

개요
Aluminum phosphide, is a binary salt, one of the NCHP acronyms (see Chapter 2). These salts have the specific hazard of giving off poisonous and pyrophoric phosphine gas when in contact with moist air, water, or steam. They will also ignite spontaneously upon contact with air. This compound is composed of gray or dark yellow crystals and is a dangerous fire risk. Aluminum phosphide decomposes upon contact with water and has a specific gravity of 2.85, which is heavier than water. The four-digit UN identification number is 1397. The NFPA 704 designation is health 4, flammability 4, and reactivity 2. The white section at the bottom of the diamond has a W with a slash through it, indicating water reactivity. Aluminum phosphide is used in insecticides, fumigants, and semiconductor technology.
화학적 성질
Aluminum phosphide is a pyrophoric, dark gray or dark yellow crystalline solid
용도
Source of phosphine; in semiconductor research; as fumigant.
일반 설명
Aluminum phosphide is a dark gray or dry, yellow, crystalline solid. Aluminum phosphide reacts with moisture to give phosphine, a flammable and poisonous gas. Normally, phosphine will spontaneously ignite upon contact with air. If there is an excess of water, the phosphine fire will not normally ignite any surrounding combustible material.
공기와 물의 반응
Decomposed by water or moist air, evolving phosphine, a toxic gas that often ignites [Merck 11th ed. 1989].
반응 프로필
Aluminum phosphide is a reducing agent. Contact with mineral acids causes explosive evolution of toxic phosphine [Wang, C. C. et al., J. Inorg. Nucl. Chem., 1963, 25, p. 327]. Heating produces highly toxic fumes of phosphorus oxides. Can react vigorously upon contact with oxidizing agents. [Sax, 9th ed., p. 119].
위험도
Dangerous fire risk. It evolves phosphine.
건강위험
Acute toxicity occurs primarily by the inhalation route when Aluminum phosphide decomposes into the toxic gas, phosphine. The human median lethal dose for Aluminum phosphide has been reported to be 20 mg/kg. Rated as super toxic: probable oral lethal dose is less than 5 mg/kg or less than 7 drops for a 70 kg (150 lb.) person.
화재위험
Releases toxic fumes on exposure to moist air, water, or acids. Decomposes to produce phosphine gas. Avoid water, dilute mineral acids, dilute or concentrated hydrochloric acid. Stable when dry. Avoid moist air.
농업용
Fumigant, Fungicide, Rodenticide, Insecticide: Used as an insecticidal fumigant for grain, peanuts, processed food, animal feed, leaf tobacco, cottonseed, and as space fumigant for flour mills, warehouses and railcars. It is also used in baits for rodent and mole control in crops. Used as a source of phosphine; in semiconductor research. Zinc phosphide is often mixed with bait food such as cornmeal, which can be a danger to pets and children. When phosphides are ingested or exposed to moisture, they release phosphine gas. A U.S. EPA restricted Use Pesticide (RUP). Metallic phosphides on clothes, skin, or hair can react with water or moisture to generate phosphine gas.
상품명
AL-PHOS®; CELPHIDE®; CELPHOS®; DELICIA®; DETIA®; DETIA-EX-B®; DETIA GAS EX®; DETIA-GAS-EX-B®; DELICIA GASTOXIN; FARMOZ®; FUMITOXIN®; PHOSTOXIN®; PHOSTOXIN-A®; QUICKPHOS®; QUICK TOX®; RENTOKIL GASTION®
Safety Profile
A human poison by inhalation and ingestion. Dangerous; in contact with water, steam, or alkali it slowly yields PH3, which is spontaneously flammable in air. Explosive reaction on contact with mineral acids produces phosphine. When heated to decomposition it yields toxic PO,. See also ALUMINUM COMPOUNDS, PHOSPHIDES, and PHOSPHINE. AHGOOO
잠재적 노출
Used as a rodenticide; wood preservative; as a source of phosphine; as an insecticidal fumigant for grain, peanuts, processed food, animal feed, leaf tobacco, cottonseed; and as space fumigant for flour mills, warehouses and railcars. Used in semiconductor research
환경귀착
Phosphine is known to bind to and inhibit cytochrome oxidase and changes the valence of the hem component of hemoglobin. Oxidative stress is one of the main mechanisms of action of AlP toxicity, which boosts extramitochondrial release of free oxygen radicals resulting in lipid peroxidation and protein denaturation of the cell membrane in various organs. Furthermore, AlP reduces glutathione, which is one of the main antioxidant defenses. AlP causes toxic stress, accompanied by changes in glucose metabolism. It also disrupts protein synthesis and enzymatic activity, particularly in the lung and heart cell mitochondria, which leads to blockage of the mitochondrial electron transport chain. Phosphine may cause denaturing of various enzymes; it is involved in cellular respiration and metabolism, and may be responsible for denaturation of the oxyhemoglobin molecule.
운송 방법
UN1397 Aluminum phosphide, Hazard Class: 4.3; Labels: 4.3-Dangerous when wet material, 6.1-Poisonous materials.
비 호환성
Able to ignite spontaneously in moist air; forms toxic and explosive phosphine gas on contact with moisture in air. Reacts violently with water, steam, carbon dioxide; acids, alcohols, and foam fire extinguishers. Contact with water and bases slowly releases highly flammable and toxic phosphine gas.
폐기물 처리
Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal. Allow to react slowly with moisture in the open, being sure that phosphine gas evolved is dissipated. Alternatively, mix with dry diluent and incinerate at temperature above 1000 C with effluent gas scrubbing. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed of properly by following package label directions or bycontacting your local or federal environmental control agency, or by contacting your regional EPA office.

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