ジメチルジチオカルバミン酸鉄(III)

危険有害性情報のコード(GHS)

• 絵表示(GHS)

  

• 注意喚起語

  Warning

• 危険有害性情報

  H302：飲み込むと有害

  H315：皮膚刺激

  H319：強い眼刺激

  H330：吸入すると生命に危険

  H335：呼吸器への刺激のおそれ

  H361：生殖能または胎児への悪影響のおそれの疑い

  H373：長期にわたる、または反復暴露により臓器の障 害のおそれ

  H410：長期的影響により水生生物に非常に強い毒性

• 注意書き

  P201：使用前に取扱説明書を入手すること。

  P202：全ての安全注意を読み理解するまで取り扱わないこ と。

  P260：粉じん/煙/ガス/ミスト/蒸気/スプレーを吸入しないこ と。

  P261：粉じん/煙/ガス/ミスト/蒸気/スプレーの吸入を避ける こと。

  P264：取扱い後は皮膚をよく洗うこと。

  P264：取扱い後は手や顔をよく洗うこと。

  P270：この製品を使用する時に、飲食または喫煙をしないこ と。

  P271：屋外または換気の良い場所でのみ使用すること。

  P273：環境への放出を避けること。

  P280：保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。

  P284：呼吸用保護具を着用すること。

  P305+P351+P338：眼に入った場合：水で数分間注意深く洗うこと。次にコ ンタクトレンズを着用していて容易に外せる場合は外す こと。その後も洗浄を続けること。

  P308+P313：暴露または暴露の懸念がある場合：医師の診断/手当てを 受けること。

  P391：漏出物を回収すること。

  P403+P233：換気の良い場所で保管すること。容器を密閉 しておくこと。

  P405：施錠して保管すること。

  P501：内容物/容器を．．．に廃棄すること。

ジメチルジチオカルバミン酸鉄(III) 価格

ジメチルジチオカルバミン酸鉄(III) 化学特性,用途語,生産方法

• 外観

  黒色粉末～結晶

• 用途

  農薬(殺菌剤)、有機ゴム薬品(加硫促進剤)

• 化学的特性

  Ferbam is a combustible, odorless dark brown to black powder or granular solid

• 使用

  Ferbam is a protective fungicide applied to foliage to control scab on pome fruit, peach leaf curl, blue mould on tobacco and other diseases on many other crops. It is often used in combinations with other dithiocarbamates to extend the spectrum of activity.

• 定義

  A wettable powder containing 76% ferbam.

• 一般的な説明

  Ferbam is a carbamate fungicide. It is a stable, black powder and combustible and gives off irritating or toxic fumes (or gases) in a fire. Ferbam is incompatible with strong oxidants. It is used for foliar protectant against scab, rust, mould, and many fungal diseases on fruits, vegetables, melons, and ornamentals. Also, it works as a repellent towards Japanese beetles. The major uses of ferbam are in the control of apple scab and cedar apple rust, peach leaf curl, tobacco blue mould, and cranberry diseases. Ferbam is a broad-spectrum registered fungicide for the control of certain diseases in fruit trees, small fruit and berry crops, potatoes, ornamentals, conifers, and tobacco and for use on citrus, pome, stone fruits, and cranberries. Major areas of use include Florida, Massachusetts, New Jersey, and other countries. Ferbam is used as water-dispersible granule, 76WG.

• 空気と水の反応

  Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids.

• 反応プロフィール

  FERBAM is a dithiocarbamate. Flammable gases are generated by the combination of thiocarbamates and dithiocarbamates with aldehydes, nitrides, and hydrides. Thiocarbamates and dithiocarbamates are incompatible with acids, peroxides, and acid halides.

• 危険性

  Irritant to eyes and mucous membranes. Questionable carcinogen.

• 健康ハザード

  Ferbam is an irritant of the eyes and respiratory tract; in animals it causes central nervous system depression, and it is expected that severe exposure will cause the same effect in humans.

• 农业用途

  Fungicide: Registered for use in the U.S. and Canada. Not approved for use in EU countries. A dimethyl-dithiocarbamate fungicide. It is widely used, together with other fungicides, to control Postbloom Fruit Drop (PFD) on citrus crops, and as a foliar protectant against scab, rust, mold and many fungus disease on fruits, vegetables, melons and ornamentals. It is registered in several states for use on currents and gooseberries to control leaf spot disease, and on apple, crabapple, hawthorn and quince to control cedar-apple rust disease. It is used to control rust disease on shrubs and ornamentals.

• 製品名

  AI3-14689®; AAFERTIS®; APPLE DUST No. 1®[C]; BERCEMA FERTAM 50®; CASWELL No. 458®; FERBAM 50®; FERBECK®; FERMATE FERBAM FUNGICIDE®[C]; FERMOCIDE®; FERRADOUR®; FERRADOW®; FUKLASIN ULTRA®; HEXAFERB®; HOKMATE®; KARBAM BLACK®; KARBAM CARBAMATE®; KNOCKMATE®; NIACIDE®; STAUFFER FERBAM®; SUP’R-FLO FERBAM FLOWABLE®; TRICARBAMIX®[C]; TRIFUNGOL®; VANCIDE FE95®[C]

• 安全性プロファイル

  Poison by intraperitoneal route. Moderately toxic by ingestion. Experimental teratogenic and reproductive effects. Questionable carcinogen with experimental carcinogenic and tumorigenic data. Mutation data reported. A fungicide. When heated to decomposition it emits very toxic fumes of NOx and SOx. See also CARBAiMATES.

• 職業ばく露

  A dithiocarbamate. A potential danger to those involved in the production, formulation and application of this dithiocarbamate; used as a fungicide, rubber accelerator, and plastics prodegradant. Some dithiocarbamates have been used as rubber components

• 環境運命予測

  Plant. Decomposes in plants to ethylene thiourea, ethylene thiuram monosul?de, ethylene thiuram disul?de and sulfur (Hartley and Kidd, 1987).
  Chemical/Physical. Hydrolyzes in acidic media releasing carbon disul?de. Decomposes in water forming ethylene thiourea (Hartley and Kidd, 1987).
  Decomposes >180°C (Windholz et al., 1983) emitting toxic fumes of nitrogen and sulfur oxides (Lewis, 1990; Sax and Lewis, 1987).

• 代謝経路

  Ferbam generates dimethyldithiocarbamic acid by being cleaved in acidic conditions and in biological media. The acid is conjugated with glucose and alanine in plants and with glucuronic acid in mammals. Dimethyldithiocarbamic acid is further degraded to dimethylamine and CS2. An extensive review of the properties of the dithiocarbamate pesticides was published by the World Health Organisation (WHO, 1988) from which much of the following information is taken.

• 輸送方法

  UN2771 Dithiocarbamate and Thiocarbamate pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required

• 不和合性

  Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine,bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Heat alkalies (lime); moisture can cause decomposition. Decomposes on prolonged storage. Dithiocarbamate esters are combustible. They react violently with powerful oxidizers such as calcium hypochlorite. Poisonous gases are generated by the thermal decomposition of Dithiocarbamate compounds, including carbon disulfide, oxides of sulfur, oxides of nitrogen, hydrogen sulfide, ammonia, and methylamine. Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids. Flammable gases are generated by the combination of dithiocarbamate with aldehydes, nitrides, and hydrides. Dithiocarbamate are incompatible with acids, peroxides, and acid halides.

• 廃棄物の処理

  Ferbam is hydrolyzed by alkali and is unstable to moisture, lime and heat. Ferbam can be incinerated. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal

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