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4-Nitrobenzyl chloride

CAS No.100-14-1
Chemical Name:4-Nitrobenzyl chloride
CBNumber:CB9852554
Molecular Formula:C7H6ClNO2
Formula Weight:171.58
MOL File:100-14-1.mol

4-Nitrobenzyl chloride Property

Melting point 71 °C
Boiling point 112 °C (0.6 mmHg)
Density 1.3246 (rough estimate)
refractive index 1.5647 (estimate)
solubility chloroform: soluble50mg/mL, clear to very slightly hazy, faintly yellow
form Crystalline Needles or Powder
color Light yellow
BRN 387187
Stability Stable. Incompatible with strong oxidizing agents, bases, amines, moisture, alcohols. Corrodes steel. Reacts slowly with water. Combustible.
CAS DataBase Reference 100-14-1(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 3BLD9LVT3X
NIST Chemistry Reference 4-Nitrobenzyl chloride(100-14-1)
EPA Substance Registry System 1-(Chloromethyl)-4-nitrobenzene (100-14-1)
UNSPSC Code 12352100
NACRES NA.22

Safety

Hazard Codes :C
Risk Statements :22-34-36
Safety Statements :26-36/37/39-45-27
RIDADR :UN 3261 8/PG 2
WGK Germany :3
RTECS :XS9093000
F :4.8-19-21
TSCA :Yes
HazardClass :8
PackingGroup :II
HS Code :29049090
Hazardous Substances Data :100-14-1(Hazardous Substances Data)

NFPA 704:

	1
3		0

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal wordDanger
Hazard statements H302-H314
Precautionary statements P260-P270-P280-P301+P312-P303+P361+P353-P305+P351+P338

4-Nitrobenzyl chloride Price More Price(9)

Brand: Sigma-Aldrich
Product number: 140112
Product name : 4-Nitrobenzyl chloride
Purity: 99%
Packaging: 25G
Price: ₹2321
Updated: 2022/06/14
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Brand: Sigma-Aldrich(India)
Product number: 140112
Product name : 4-Nitrobenzyl chloride
Purity: 99%
Packaging: 25G
Price: ₹2321
Updated: 2022/06/14
Buy: Buy

Brand: Sigma-Aldrich
Product number: 140112
Product name : 4-Nitrobenzyl chloride
Purity: 99%
Packaging: 100G
Price: ₹15772.25
Updated: 2022/06/14
Buy: Buy

Brand: Sigma-Aldrich(India)
Product number: 140112
Product name : 4-Nitrobenzyl chloride
Purity: 99%
Packaging: 100G
Price: ₹15772.25
Updated: 2022/06/14
Buy: Buy

Brand: ALFA India
Product number: ALF-A15749-30
Product name : 4-Nitrobenzyl chloride, 99%
Purity:
Packaging: 250g
Price: ₹25220
Updated: 2022/05/26
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4-Nitrobenzyl chloride Chemical Properties,Usage,Production

Description Benzene, 1-(chloromethyl)-4-nitro- is a crystalline solid. Molecular weight= 171.58; Freezing/Meltingpoint =71℃. Slightly soluble in water; slow reaction.
Chemical Properties white to light yellow crystal powde
Chemical Properties Benzene, 1-(chloromethyl)-4-nitro-, is a crystalline solid.
Uses 4-Nitrobenzyl chloride was used to prepare unsymmetrically N,N′-bis(substituted) 4,13-diaza-18-crown-6-ether derivatives.
Production Methods Chlorination of 4-nitrotoluene at 190 ℃ without catalyst gives 4-Nitrobenzyl chloride. The alternative process of nitration of benzylchloride coproduces 2-nitrobenzyl chloride and requires a difficult separation stage.
Definition ChEBI: A C-nitro compound that is nitrobenzene in which the hydrogen at position 4 is replaced by a chloromethyl group.
General Description Solid.
Air & Water Reactions May react slowly with water.
Reactivity Profile Incompatible with sodium hydroxide. [EPA, 1998]. A halogenated aromatic nitro compound. Aromatic nitro compounds range from slight to strong oxidizing agents. If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation. The aromatic nitro compounds may explode in the presence of a base such as sodium hydroxide or potassium hydroxide even in the presence of water or organic solvents. The explosive tendencies of aromatic nitro compounds are increased by the presence of multiple nitro groups.
Health Hazard Poisonous if swallowed or dust is inhaled.
Fire Hazard Incompatible with sodium hydroxide.
Potential Exposure A chloronitrobenzene compound, used in organic synthesis.
First aid If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention.
storage Color Code—Blue: Health Hazard/Poison: Storein a secure poison location. Store in a refrigerator or in acool, dry place and protect from prolonged exposure tomoisture.
Shipping UN3261 Corrosive solid, acidic, organic, n.o.s., Hazard class: 8; Labels: 8—Corrosive material, Technical Name Required. UN1578 Chloronitrobenzenes, solid or liquid, Hazard Class: 6.1; Labels: 6.1—Poisonous materials.
Purification Methods Crystallise the chloride from CCl4, dry diethyl ether, or n-heptane, and dry it under vacuum. IRRITANT.[Beilstein 5 IV 856.]
Incompatibilities Can react with sulfuric acid. Keep away from oxidizers, amines, bases: sodium hydroxide, and potassium hydroxide; may cause fire and explosions. Incompatible with strong oxidizing and reducing agents such as hydrides, certain amines, nitrides, azo/diazo compounds, alkali metals (potassium), and epoxides. Corrodes steel, some plastics and human tissue.