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NICKELOCENE

CAS No.1271-28-9
Chemical Name:NICKELOCENE
CBNumber:CB9136861
Molecular Formula:C10H10Ni10*
Formula Weight:188.88
MOL File:1271-28-9.mol

NICKELOCENE Property

Melting point 171-173 °C(lit.)
storage temp. 2-8°C
Water Solubility Insoluble in water
form crystal
color dark green
Sensitive Air & Moisture Sensitive
CAS DataBase Reference 1271-28-9(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII JR8F745XV5
Proposition 65 List Nickelocene
NIST Chemistry Reference Nickelocene(1271-28-9)
EPA Substance Registry System Nickelocene (1271-28-9)
UNSPSC Code 12352103
NACRES NA.23

Safety

Hazard Codes :F,T
Risk Statements :49-11-22-43
Safety Statements :53-36/37/39-45
RIDADR :UN 1325 4.1/PG 2
WGK Germany :3
RTECS :QR6500000
F :10-23
TSCA :Yes
HazardClass :4.2
PackingGroup :I
HS Code :29319090
Toxicity :mouse,LD50,intraperitoneal,86mg/kg (86mg/kg),Proceedings of the Western Pharmacology Society. Vol. 11, Pg. 39, 1968.

NFPA 704:

	3
2		3

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal wordDanger
Hazard statements H228-H302-H317-H350
Precautionary statements P201-P210-P280-P301+P312+P330-P302+P352-P308+P313

NICKELOCENE Price More Price(3)

Brand: Sigma-Aldrich(India)
Product number: N7524
Product name : Bis(cyclopentadienyl)nickel(II)
Purity:
Packaging: 5G
Price: ₹6733.15
Updated: 2022/06/14
Buy: Buy

Brand: TCI Chemicals (India)
Product number: D1574
Product name : Nickelocene
Purity:
Packaging: 1G
Price: ₹2400
Updated: 2022/05/26
Buy: Buy

Brand: TCI Chemicals (India)
Product number: D1574
Product name : Nickelocene
Purity:
Packaging: 5G
Price: ₹6600
Updated: 2022/05/26
Buy: Buy

NICKELOCENE Chemical Properties,Usage,Production

Chemical Properties GREEN TO DARK GREEN CRYSTALS OR CRYST. POWDER
Chemical Properties Nickelocene is a solid crystalline substance of dark green color, insoluble in water or carbon tetrachloride, slightly soluble in alcohol and liquid ammonia, and readily soluble in nonpolar organic solvents.
Uses Nickelocene is obtained through reacting nickel halides with sodium cyclopentadienide. It is used as a catalyst or as a complexing agent.
Uses Catalyst, complexing agent.
Uses This metal alkyl may be used to synthesize hybrid organic-inorganic polymeric molecular layer deposition (MLD). Bis(cyclopentadienyl) nickel (Cp 2 Ni) may be used as a Ni precursor for the atomic layer deposition (ALD) of NiO/carbon nanotubes hybrids.
General Description Dark liquid in an 8-10% solution in toluene. Insoluble in water.
Air & Water Reactions Highly flammable. The neat material is sensitive to air. . Insoluble in water.
Reactivity Profile Organometallics, such as NICKELOCENE, are reactive with many other groups. Incompatible with acids and bases. Organometallics are good reducing agents and therefore incompatible with oxidizing agents. Often reactive with water to generate toxic or flammable gases.
Hazard Toxic by inhalation and skin contact, a carcinogen (OSHA).
Health Hazard ACUTE/CHRONIC HAZARDS: NICKELOCENE can be absorbed through the skin.
Fire Hazard NICKELOCENE is flammable.
reaction suitability core: nickel
reagent type: catalyst
Safety Profile Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Poison by intraperitoneal and intramuscular routes. Moderately toxic by ingestion. When heated to decomposition it emits acrid smoke and irritating fumes. See also NICKEL COMPOUNDS.
Purification Methods Dissolve the complex in Et2O, filter and evaporate in a vacuum. Purify it rapidly by recrystallisation from pet ether using a solid CO2/Me2CO bath, m 171-173o(in an evacuated tube). Also purify it by vacuum sublimation. [Wilkinson et al. J Am Chem Soc 76 1970 1954, Beilstein 16 IV 1831.]