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BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL

BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL Structure
BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL
  • CAS No.13007-90-4
  • Chemical Name:BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL
  • CBNumber:CB0687047
  • Molecular Formula:C38H30NiO2P2
  • Formula Weight:639.28
  • MOL File:13007-90-4.mol
BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL Property
  • Melting point 206-209 °C (lit.)
  • storage temp. 2-8°C
  • solubility Soluble in HMPA, THF, diglyme, triglyme, benzene, acetonitrile, ethanol, and cyclohexane.
  • form crystal
  • color light yellow
  • Sensitive air sensitive
  • Merck 14,1304
  • Exposure limits NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
  • CAS DataBase Reference 13007-90-4
  • FDA UNII 1QB0TWF7LY
  • UNSPSC Code 12161600
  • NACRES NA.22
Safety
  • Hazard Codes  :T
  • Risk Statements  :45-42/43
  • Safety Statements  :53-22-36/37-45
  • RIDADR  :3281
  • WGK Germany  :3
  • HazardClass  :6.1
  • PackingGroup  :II
  • NFPA 704:
    0
    2 0
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal wordDanger
  • Hazard statements H317-H350
  • Precautionary statements P201-P280-P302+P352-P308+P313
BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL Price More Price(1)
  • Brand: Sigma-Aldrich(India)
  • Product number: 213934
  • Product name : Bis(triphenylphosphine)dicarbonylnickel
  • Purity: 
  • Packaging: 10G
  • Price: ₹9959
  • Updated: 2022/06/14
  • Buy: Buy

BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL Chemical Properties,Usage,Production

  • Chemical Properties light yellow crystals or crystalline powder
  • Uses Catalyst for:
    • Cyclotrimerization reactions
    • Cyclooligomerization reactions
  • Uses Catalyst in polymerization of acetylene to benzene and styrene, trimerization of ethynyl Compounds, cyclization of butadiene.
  • reaction suitability core: nickel
    reagent type: catalyst
  • Synthesis The preparative method of Bis(triphenylphosphine)dicarbonylnickel: by treating Tetracarbonylnickel with 2 equiv of Triphenylphosphine or by dissolving Dichlorobis(triphenylphosphine)nickel(II) in ethanol and treating it with CO in the presence of MeSNa. Purification: recrystallize from benzene.
  • Precautions Catalytic activity decreases with storage. It is likely to be toxic, similar to nickel carbonyl, but its low volatility makes it easy to avoid ingestion. Use in a fume hood.
BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL Preparation Products And Raw materials
Raw materials
Preparation Products
BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL Suppliers
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BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL Spectrum
13007-90-4, BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKELRelated Search:
  • metal carbonyl complexes
  • 高端化学
  • Catalysis and Inorganic Chemistry
  • C38H30NiO2P2
  • C6H53P2NiCO2
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  • 13007-90-4
  • BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL ISO 9001：2015 REACH
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  • Bis(triphenylphosphine)dicarbonylnickel,98%
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  • BIS(TRIPHENYLPHOSPHINE)NICKEL &
  • DICARBONYL-BIS(TRIPHENYLPHOSPHINE)NICKEL
  • BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL
  • BIS(TRIPHENYLPHOSPHINE)NICKEL DICARBONYL
  • NICKEL-BIS(TRIPHENYLPHOSPHINE) DICARBONYL

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