Reaction
ChemicalBook > CAS DataBase List > (R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny

(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny

Reaction
(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny Structure
(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny
  • CAS No.352655-61-9
  • Chemical Name:(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny
  • CBNumber:CB6972437
  • Molecular Formula:C74H104O6P2
  • Formula Weight:1151.56
  • MOL File:352655-61-9.mol
(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny Property
  • Boiling point 951.5±65.0 °C(Predicted)
  • form crystal
  • color white
  • UNSPSC Code 12352112
  • NACRES NA.22
Safety
  • WGK Germany  :3
  • HS Code  :29319090
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal wordWarning
  • Hazard statements H302-H315-H319-H335
  • Precautionary statements P261-P280-P301+P312-P302+P352-P305+P351+P338

(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny Chemical Properties,Usage,Production

  • Reaction
    1. Rh-catalyzed reductive coupling of acetylene to aldehydes and ketones.
    2. Pt-catalyzed intramolecular hydroarylation of unactivated alkenes with indoles.
    3. Enantioselective C-C bond activation of allenyl cyclobutanes.
    4. Enantioselective ring-opening of rac-ethynyl epoxides.
    5. Enantioselective Au-catalyzed allylic alkylation of indoles with alcohols.
    6. Enantioselective Rh-catalyzed conjugate alkynylation with TMS-acetylene.
    7. Enantioselective Rh-catalyzed [3+2] annulation of aromatic ketimines.
    8. Asymmetric Rh-catalyzed Pausan-Khand reaction. 
    Reactions of 352655-61-9_1
    Reactions of 352655-61-9_2
    Reactions of 352655-61-9_3
  • Chemical Properties Off-white powder
  • Uses Atropisomeric MeOBIPHEP ligands

    • Asymmetrical conjugate addition of arylboronic acids to maleimides and enones catalyzed by rhodium complexes
    • Intramolecular ketone hydroacylation
    • Desymmetrization through enantioselective C-C bond activation and ring expansion of allenyl cyclobutanols
    • Hydroamination of bicyclic alkenes and dienes with anilines
    • 1,4-addition/asymmetric protonation of amino acrylates
  • General Description sold in collaboration with Solvias AG
(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny Preparation Products And Raw materials
Raw materials
Preparation Products
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(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny Spectrum
352655-61-9, (R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxyphenyRelated Search:
  • MeOBIPHEP Series
  • Chiral Phosphine
  • 高端化学
  • 有机配体
  • 膦配体
  • C74H104O6P2
  • (R)-(6,6'-二甲氧基联苯-2,2'-二基)二[双(3,5-二-叔丁基-4-甲氧苯基)膦
  • (R)-(-)-2,2'-双[二 (3,5-二-叔丁基-4-甲氧基苯基)膦基]-(二苯基膦)-6,6'-二甲氧基-1,1'-联苯
  • (R)-(-)二[双(3,5-二叔丁基-4-甲氧苯基)膦]--6,6'-二甲氧基-1,1'-联苯
  • (R)-[6,6′-二甲氧基(1,1′-联苯基)-2,2′-二基]二{双[3,5-二(1,1-二甲基乙基)-4-甲氧苯基]膦}
  • (R)-(6,6′-二甲氧基联苯-2,2′-二基)二[双(3,5-二-叔丁基-4-甲氧苯基)膦]
  • (R)-(-)-2,2'-双[二(3,5-二叔丁基-4-甲氧基苯基)磷]-6,6'-二甲氧基-1,1'-联苯
  • (R)-(-)-2,2'-双[二- (3,5-二-叔丁基-4-甲氧基苯基)膦基]-(二苯基膦)-6,6′-二甲氧基-1,1'-联苯
  • 352655-61-9
  • (<i>R</i>)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis[bis(3,5-di-<i>tert</i>-butyl-4-methoxyphenyl)phosphine]
  • (R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine
  • -diyl)bis[bis(3，5-di-tert-butyl-4-methoxyphenyl)phosphine
  • (R)-3,5-t-Bu-4-MeO-MeOBIPHEP
  • (R)-2,2'-Bis[bis(3,5-di-tert-butyl-4-methoxyphenyl) phosphino]-6,6'-dimethoxy-1,1'-biphenyl
  • Phosphine, 1,1'-[(1R)-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-bis[3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl]-
  • (R)-(6,6'-DiMethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-Methoxyphenyl)phosphine] >=97%, optical purity ee: >=99%
  • (R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl
  • (R)-(-)-2,2'-Bis[di-(3,5-di-t-butyl-4-methoxy- phenyl)phosphino]-(diphenylphosphino)-6,6'- dimethoxy-1,1'-biphenyl
  • SL-A109-1
  • (R)-(-)-2,2'-Bis[di-(3,5-di-tert-butyl-4-methoxy-phenyl)phosphino]-(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl
  • (R)-3,5-t-Bu-4-MeO-MeOBIPHEP, SL-A109-1, (R)-[6,6μ-Dimethoxy(1,1μ-biphenyl)-2,2μ-diyl]bis{bis[3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl]phosphine}
  • (R)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine]
  • (S)-3,5-t-Bu-4-MeO-MeOBIPHEP, SL-A109-2, (S)-[6,6μ-Dimethoxy(1,1μ-biphenyl)-2,2μ-diyl]bis{bis[3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl]phosphine}
  • (S)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine]
  • (R)-(-)-2,2''-BIS[DI(3,5-DI-T-BUTYL-4-METHOXYPHENYL)PHOSPHINO]-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97%
  • (R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%
  • (R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny

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