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ChemicalBook > CAS DataBase List > (R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%

(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%

Reactions
(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Structure
(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
  • CAS No.150971-45-2
  • Chemical Name:(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
  • CBNumber:CB51180977
  • Molecular Formula:C26H40O2P2
  • Formula Weight:446.54
  • MOL File:150971-45-2.mol
(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Property
  • Boiling point 517.2±50.0 °C(Predicted)
  • storage temp. under inert gas (nitrogen or Argon) at 2-8°C
  • form Powder
  • color white
  • UNSPSC Code 12352112
Safety
  • HS Code  :29319090
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal word
  • Hazard statements
  • Precautionary statements

(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Chemical Properties,Usage,Production

  • Reactions In many respects the catalytic profile of the MeOBIPHEP ligands is similar to that of other atropisomeric diphosphines such as binap and its many analogs. The nature of the PR2 group strongly influences the catalytic performance of the metal complexes. The rhodium and ruthenium MeO-BIPHEP catalysts are highly effective for the hydrogenation of various C=O, C=C and C=N bonds and several synthetically useful C-C coupling reactions.
    1. Ru and Ir catalyzed dynamic kinetic resolution for the synthesis of hydroxy, amino acid derivatives.
    2. Ru-catalyzed asymmetric hydrogenation of ketones and alkenes.
    3. Ir catalyzed enantioselective hydrogenation of heteroaromatic compounds.
    4. Conjugate addition using 2-heteroaryl titanates and zinc reagents.
    5. Enantio- and regioselective heck-type reaction of aryl boronic acids with 2,3-dihydrofuran
    6. Rhodium-catalyzed carbonyl Z-dienylation.
    7. Rhodium-catalyzed asymmetric 1,4 addition of arylboronic acids to maleimides and enones.
    Reactions of 150971-45-2_1
    Reactions of 150971-45-2_2
  • Chemical Properties Off-white powder
  • Uses Atropisomeric MeOBIPHEP ligands
  • General Description sold in collaboration with Solvias AG
(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Preparation Products And Raw materials
Raw materials
Preparation Products
(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Suppliers
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(R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Spectrum
150971-45-2, (R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%Related Search:
  • MeOBIPHEP Series
  • Chiral Phosphine
  • 有机配体
  • 膦配体
  • (R)-(6,6'-二甲氧联苯-2,2'-二基)双(二异丙基膦)
  • (R)-2,2'-二(二异丙基)-6,6'-二甲氧基-1,1'-联苯
  • (R)-(+)-2,2′-双(二异丙基膦基) -6,6′-二甲氧基-1,1'-联苯
  • (R)-(6,6′-二甲氧联苯-2,2′-二基)双(二异丙基膦)
  • -2,2'-双(二-丙基磷酰)-6,6'-二甲氧基-1,1'-联苯
  • R-(+)-2,2'-双(二-丙基磷酰)-6,6'-二甲氧基-1,1'-联苯
  • (R)-2,2′-双(二异丙基膦)-6,6′-二甲氧-1,1′-联苯
  • 150971-45-2
  • (<i>R</i>)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diisopropylphosphine)
  • (R)-2,2'-Bis(diisopropylphosphino)-6,6'-dimethoxy-1,1'-biphenyl
  • (R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl
  • Phosphine, 1,1'-[(1R)-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-bis(1-methylethyl)-
  • (R)-(+)-2,2'-Bis(di-isopropylphosphino)-6,6'-dimethoxy-1,1'-biphenyl
  • (R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diisopropylphosphine) >=97%
  • (R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'- dimethoxy-1,1'-biphenyl
  • SL-A116-1
  • (R)-iPr-MeOBIPHEP
  • (R)-iPr-MeOBIPHEP, SL-A116-1, (R)-2,2μ-Bis(diisopropylphosphino)-6,6μ-dimethoxy-1,1μ-biphenyl
  • (R)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis(diisopropylphosphine)
  • (R)-(+)-2,2''-BIS(DI-I-PROPYLPHOSPHINO)-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97%
  • (R)-(+)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%

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