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Trifluoroacetic anhydride Structure

Trifluoroacetic anhydride

  • Product NameTrifluoroacetic anhydride
  • CAS407-25-0
  • CBNumberCB6853606
  • MFC4F6O3
  • MW210.03
  • EINECS206-982-9
  • MDL NumberMFCD00000416
  • MOL File407-25-0.mol

Chemical Properties

Melting point: −65 °C (−85 °F; 208 K)
Boiling point: 40 °C (104 °F; 313 K)
Density  1.511 g/mL (20°C)
vapor pressure  6.28 psi ( 20 °C)
refractive index  n 20/D 1.3 (lit.)
Flash point: -26 °C
storage temp.  2-8°C
solubility  Miscible with benzene, dichloromethane, diethyl ether, dimethylformamide, terahydrofuran and acetonitrile.
form  liquid
pka 0.43[at 20 ℃]
color  colorless
Specific Gravity 1.487
Water Solubility  Hydrolysis
Sensitive  Moisture Sensitive
BRN  746197
Stability: Stable, but moisture sensitive. Reacts with water to liberate hydrogen (flammable!). Incompatible with water, strong oxidizing agents.
InChI 1S/C4F6O3/c5-3(6,7)1(11)13-2(12)4(8,9)10
InChIKey QAEDZJGFFMLHHQ-UHFFFAOYSA-N
SMILES FC(F)(F)C(=O)OC(=O)C(F)(F)F
LogP 0.79 at 25℃
CAS DataBase Reference 407-25-0(CAS DataBase Reference)
NIST Chemistry Reference Acetic acid, trifluoro-, anhydride(407-25-0)
EPA Substance Registry System Acetic acid, trifluoro-, anhydride (407-25-0)

Safety

Symbol(GHS)  Corrosion (GHS05)Exclamation Mark (GHS07)
GHS05,GHS07
Signal word  Danger
Hazard statements  H302+H312+H332-H314-H412-H290
Precautionary statements  P501-P261-P273-P270-P234-P271-P264-P280-P390-P362+P364-P303+P361+P353-P301+P330+P331-P301+P312+P330-P304+P340+P310-P305+P351+P338+P310-P406-P405
PPE Faceshields, Gloves, Goggles
Hazard Codes  C,T
Risk Statements  14-20-35-52/53-34-23/24/25
Safety Statements  26-36/37/39-43-45-61-9-8-28A-27
RIDADR  UN 3265 8/PG 1
WGK Germany  2
RTECS  AJ9800000
F  3-10
Hazard Note  Corrosive/Moisture Sensitive
TSCA  TSCA listed
HazardClass  8
PackingGroup  I
HS Code  2915900090
Storage Class 8B - Non-combustible corrosive hazardous materials
Hazard Classifications Acute Tox. 4 Inhalation
Aquatic Chronic 3
Eye Dam. 1
Skin Corr. 1A
Toxicity skn-rbt 500 mg/24H SEV 28ZPAK -,91,72
REACH Registrations Active
Excepted Quantities Not Permitted as Excepted Quantity
NFPA 704:
0
3 1

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