ChemicalBook > CAS DataBase List > Ethyl (triphenylphosphoranylidene)acetate
Ethyl (triphenylphosphoranylidene)acetate
Ethyl (triphenylphosphoranylidene)acetate
- CAS No.1099-45-2
- Chemical Name:Ethyl (triphenylphosphoranylidene)acetate
- CBNumber:CB5290828
- Molecular Formula:C22H21O2P
- Formula Weight:348.37
- MOL File:1099-45-2.mol
Ethyl (triphenylphosphoranylidene)acetate Property
- Melting point 128-130 °C (lit.)
- Boiling point 490.4±28.0 °C(Predicted)
- Density 1.086 g/cm3
- storage temp. 2-8°C
- solubility Chloroform, THF
- form Powder
- color White to light yellow
- Water Solubility Insoluble
- Sensitive Air Sensitive
- BRN 754639
- InChIKey IIHPVYJPDKJYOU-UHFFFAOYSA-N
- CAS DataBase Reference 1099-45-2(CAS DataBase Reference)
- FDA UNII WX75SQL8ZF
- EPA Substance Registry System Acetic acid, (triphenylphosphoranylidene)-, ethyl ester (1099-45-2)
- UNSPSC Code 12352108
- NACRES NA.22
Safety
- Hazard Codes :T,Xi,Xn
- Risk Statements :36/37/38-25-20/21/22
- Safety Statements :22-24/25-45-37/39-26-36
- RIDADR :UN2811
- WGK Germany :3
- Hazard Note :Irritant
- TSCA :Yes
- HS Code :29310095
-
NFPA 704:
1 0 0
-
Symbol(GHS)
- Signal wordDanger
- Hazard statements H319-H411-H373-H300-H317
- Precautionary statements P264-P270-P301+P310-P321-P330-P405-P501-P264-P280-P305+P351+P338-P337+P313P-P261-P272-P280-P302+P352-P333+P313-P321-P363-P501-P260-P314-P501
Ethyl (triphenylphosphoranylidene)acetate Price
More Price(8)
- Brand: Sigma-Aldrich(India)
- Product number: C5106
- Product name : (Carbethoxymethylene)triphenylphosphorane
- Purity: 95%
- Packaging: 5G
- Price: ₹1612.93
- Updated: 2022/06/14
- Buy: Buy
- Brand: Sigma-Aldrich(India)
- Product number: C5106
- Product name : (Carbethoxymethylene)triphenylphosphorane
- Purity: 95%
- Packaging: 25G
- Price: ₹8973.93
- Updated: 2022/06/14
- Buy: Buy
- Brand: Sigma-Aldrich(India)
- Product number: C5106
- Product name : (Carbethoxymethylene)triphenylphosphorane
- Purity: 95%
- Packaging: 100G
- Price: ₹29249.15
- Updated: 2022/06/14
- Buy: Buy
- Brand: ALFA India
- Product number: ALF-A12896-30
- Product name : (Ethoxycarbonylmethylene)triphenylphosphorane, 98+%
- Purity:
- Packaging: 250g
- Price: ₹23688
- Updated: 2022/05/26
- Buy: Buy
- Brand: ALFA India
- Product number: ALF-A12896-18
- Product name : (Ethoxycarbonylmethylene)triphenylphosphorane, 98+%
- Purity:
- Packaging: 50g
- Price: ₹8110
- Updated: 2022/05/26
- Buy: Buy
Ethyl (triphenylphosphoranylidene)acetate Chemical Properties,Usage,Production
- Description Ethyl (triphenylphosphoranylidene)acetate is a common Wittig reagent in organic synthesis as well as a cholinesterase inhibitor that inhibits both AChE and BChE. It is used in the preparation of indole from o-nitrobenzaldehydes, coumarins from o-hydroxy acetophenone.
- Chemical Properties Off-White Solid
- Uses A common Wittig reagent. A cholinesterase inhibitor.
- Uses (Ethoxycarbonylmethylene)triphenylphosphoran is used as a Wittig reagent in organic synthesis. It is used in the preparation of indole from o-nitrobenzaldehydes, coumarins from o-hydroxy acetophenone. It acts as an inhibitor and inhibits the activity of cholinesterase.
- reaction suitability reaction type: C-C Bond Formation
- Purification Methods Crystallise it by dissolving it in AcOH and adding pet ether (b 40-50o) to give colourless plates. UV (A 1% ): 222nm (865) and 268nm (116) [Isler et max 1mm al. Helv Chim Acta 40 1242 1957]. [Beilstein 16 IV 977.]
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Raw materials
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- 1099-45-2
- (Carbethoxymethylene)triphenylphosphine
- Ethoxylmethylenemalononitrile
- Ethyl (triphenylphosphoranylidene) acetate, 10 mM in DMSO
- (Carbethoxymethylene)triphenylphosph
- Ethoxyformylmethylene triphenylphosphine
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