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Borane-methyl sulfide complex

Borane-methyl sulfide complex Structure
Borane-methyl sulfide complex
  • CAS No.13292-87-0
  • Chemical Name:Borane-methyl sulfide complex
  • CBNumber:CB3700534
  • Molecular Formula:C2H10BS
  • Formula Weight:76.97
  • MOL File:13292-87-0.mol
Borane-methyl sulfide complex Property
  • Melting point -40--37°C
  • Boiling point ~34 °C
  • Density 1.287 g/mL at 25 °C
  • refractive index 1.4570
  • Flash point 65 °F
  • storage temp. 2-8°C
  • solubility Miscible with ethyl ether, tetrahydrofurane, dichloromethane, benzene, xylene, hexane, diglyme, dimethyl ether, ethyl acetate, toluene, methylene chloride and other aprotic solvents.
  • form Solution
  • color Colorless to pale yellow
  • Specific Gravity 0.801
  • Water Solubility reacts
  • Sensitive Air & Moisture Sensitive
  • BRN 3663489
  • InChIKey RMHDLBZYPISZOI-UHFFFAOYSA-N
  • CAS DataBase Reference 13292-87-0(CAS DataBase Reference)
  • EWG's Food Scores 1
  • FDA UNII 6AVE9SRR08
  • NIST Chemistry Reference Borane-methyl sulfide complex(13292-87-0)
  • EPA Substance Registry System Boron, trihydro[thiobis[methane]]-, (T-4)- (13292-87-0)
  • UNSPSC Code 12352112
  • NACRES NA.22
Safety
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal wordDanger
  • Hazard statements H225-H260-H301+H311-H318-H360FD-H412
  • Precautionary statements P210-P231+P232-P273-P280-P301+P310-P305+P351+P338
Borane-methyl sulfide complex Price More Price(24)
  • Brand: Sigma-Aldrich(India)
  • Product number: 775118
  • Product name : Borane dimethyl sulfide complex solution
  • Purity: 1.0?M in 2-methyltetrahydrofuran
  • Packaging: 4X25ML
  • Price: ₹5519.5
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich(India)
  • Product number: 775118
  • Product name : Borane dimethyl sulfide complex solution
  • Purity: 1.0?M in 2-methyltetrahydrofuran
  • Packaging: 100ML
  • Price: ₹9788.8
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich(India)
  • Product number: 775118
  • Product name : Borane dimethyl sulfide complex solution
  • Purity: 1.0?M in 2-methyltetrahydrofuran
  • Packaging: 500ML
  • Price: ₹31215.1
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich(India)
  • Product number: 192120
  • Product name : Borane dimethyl sulfide complex solution
  • Purity: 2.0?M in THF
  • Packaging: 100ML
  • Price: ₹5856.33
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich(India)
  • Product number: 192120
  • Product name : Borane dimethyl sulfide complex solution
  • Purity: 2.0?M in THF
  • Packaging: 4X25ML
  • Price: ₹5964.58
  • Updated: 2022/06/14
  • Buy: Buy

Borane-methyl sulfide complex Chemical Properties,Usage,Production

  • Chemical Properties clear colorless to light yellow solution
  • Uses Borane-dimethyl sulfide (BH3 Me2S) can be used as a reagent:
    • For the selective synthesis of 1,3,5-oxygenated compounds from dimethyl 3-oxoglutarate.
    • For the conversion of ozonides to alcohols.
    • In the CBS-catalyzed asymmetric reduction of ferrocenyl-1,3-diketones to 1,3-diols.
    • For enantioselective reduction of ketones to chiral secondary alcohols in the presence of C3-symmetric tripodal hydroxyamide as a ligand.
    • For the hydroboration reduction and other applications.
    • With a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones.
  • Uses Borane-dimethyl sulfide complex is used for hydroborations and reductions. Used with a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones. CBS-catalyzed asymmetric reduction of ferrocenyl-1,3-diketones to 1,3-diols. Highly enantioselective reduction of ketones catalyzed by C3-symmetric tripodal hydroxyamides.
  • General Description Borane dimethyl sulfide complex (BMS) acts as a highly efficient and selective reducing agent in the presence of catalytic sodium tetrahydroborate for α-hydroxy esters. Asymmetric borane reduction of a variety of prochiral ketones with BMS using spiroborate esters as catalyst has been reported.
  • reaction suitability reagent type: reductant
Borane-methyl sulfide complex Preparation Products And Raw materials
Raw materials
Preparation Products
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Borane-methyl sulfide complex Spectrum
13292-87-0, Borane-methyl sulfide complexRelated Search:
  • API intermediates
  • Synthetic Organic Chemistry
  • Reduction
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