Reaction
- Ligand for synthesis of polycyclic indoles via Pd-catalyzed intramolecular heteroannulation.
- Ligand for the palladium-catalyzed intramolecular arylation of aryl bromides under mild conditions.
- Ligand for cross-coupling reactions between bromoarenes and potassium allyltrifluoroborates promoted by a catalyst prepared from Pd(OAc)2 and DTBPF selectively providing γ-coupling products.
- Ligand for the copper-catalyzed system for the ß-boration of of a variety of α,ß-unsaturated amides.
- Ligand for the synthesis of Paucifloral F and related indanone analogues via palladium-catalyzed α-arylation.
- Ligand for the Pd-carbon monoxide complex catalyzed hydroxycarbonylation of aryl halides.
- Ligand for the palladium-catalyzed β-C-glycosylation by decarboxylative allylation to normal pyran systems,and cis-2,6-disubstituted tetrahydropyrans.
- Pd-catalyzed dearomative indole bisfunctionalization via a diastereoselective arylcyanation.
- Ligand for the copper- DTBPF catalyzed C–H activation and carboxylation of terminal alkynes.
Chemical Properties
1,1'-Bis(di-tert-butylphosphino)ferrocene has good stability and reactivity and can participate in a variety of organometallic catalytic reactions, such as diene complex formation, carbonyl insertion, addition, reduction and deoxygenation reactions.
Uses
1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE is an organophosphine compound and can be used as an organometallic ligand.
Uses
The rate of palladium-catalyzed amination of unactivated aryl chlorides is accelerated by sterically hindered chelating alkyl phosphines, ie, 1,1'-bis(di-tert-butylphosphino)ferrocene.
reaction suitability
reaction type: Cross Couplings
reagent type: ligand
reaction type: Arylations
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reagent type: ligand
reaction type: Indole Forming Reactions
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling
