ChemicalBook > CAS DataBase List > TRIBUTYLBORANE
TRIBUTYLBORANE
TRIBUTYLBORANE
- CAS No.122-56-5
- Chemical Name:TRIBUTYLBORANE
- CBNumber:CB1725849
- Molecular Formula:C12H27B
- Formula Weight:182.15
- MOL File:122-56-5.mol
TRIBUTYLBORANE Property
- Melting point -34 °C
- Boiling point 109 °C20 mm Hg(lit.)
- Density 0.834 g/mL at 25 °C
- refractive index 1.4285
- Flash point 1 °F
- storage temp. Flammables area
- solubility Benzene, Tetrahydrofuran
- form Solution
- color Clear colorless to light yellow
- Water Solubility Not miscible or difficult to mix with water.
- Sensitive Air Sensitive
- Exposure limits ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3) - InChIKey CMHHITPYCHHOGT-UHFFFAOYSA-N
- CAS DataBase Reference 122-56-5
- EWG's Food Scores 1
- EPA Substance Registry System Borane, tributyl- (122-56-5)
- UNSPSC Code 12352001
- NACRES NA.22
Safety
- Hazard Codes :F,Xn,C
- Risk Statements :17-34-40-36/37/38-20/21/22-11-22-19-37
- Safety Statements :7-23-26-36/37/39-43-45-16
- RIDADR :UN 2845 4.2/PG 1
- WGK Germany :1
- RTECS :ED1850000
- TSCA :Yes
- HazardClass :4.2
- PackingGroup :I
- HS Code :29310099
-
NFPA 704:
4 3 1
-
Symbol(GHS)
- Signal wordDanger
- Hazard statements H250-H302-H314
- Precautionary statements P210-P231+P232-P280-P301+P312-P303+P361+P353-P305+P351+P338
TRIBUTYLBORANE Price
More Price(3)
- Brand: Sigma-Aldrich
- Product number: 297976
- Product name : Tributylborane solution
- Purity: 1.0?M in diethyl ether
- Packaging: 100ML
- Price: ₹4660
- Updated: 2022/06/14
- Buy: Buy
- Brand: Sigma-Aldrich(India)
- Product number: 297976
- Product name : Tributylborane solution
- Purity: 1.0?M in diethyl ether
- Packaging: 100ML
- Price: ₹4660
- Updated: 2022/06/14
- Buy: Buy
- Brand: Sigma-Aldrich(India)
- Product number: 179906
- Product name : Tributylborane solution
- Purity: 1.0?M in THF
- Packaging: 100ML
- Price: ₹15255.1
- Updated: 2022/06/14
- Buy: Buy
TRIBUTYLBORANE Chemical Properties,Usage,Production
- Chemical Properties Colorless pyrophoric fluid. Insoluble in water; soluble in most organic solvents.
- Uses Petrochemical industry, organic reactions, catalyst.
- Uses Tributylborane is a reducing agent used in the controlled radical polymerization of alkyl acrylates.
-
Synthesis Reference(s)
The Journal of Organic Chemistry, 51, p. 427, 1986 DOI: 10.1021/jo00354a002
Tetrahedron Letters, 26, p. 4311, 1985 DOI: 10.1016/S0040-4039(00)98721-5 - Hazard Flammable, dangerous fire risk, store and use in inert atmosphere, ignites spontaneously in air.
- reaction suitability reagent type: reductant
- Safety Profile Poison by intravenous route. Moderately toxic by ingestion. A very dangerous fire hazard when exposed to heat or flame; can ignite spontaneously. When heated to decomposition it emits acrid smoke and irritating fumes. See also BORANES.
TRIBUTYLBORANE Preparation Products And Raw materials
Raw materials
Preparation Products
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122-56-5, TRIBUTYLBORANERelated Search:
- Tributyltin Hydride Boron trifluoride diethyl etherate 1,2,4-Trimethylbenzene Trifluoromethanesulfonic acid TRIPHENYLBORANE Trimethylaluminium TRIMETHYLBORON Triethylborane Tributyltin chloride Triethylaluminum Tributyl citrate Tributyl phosphate TRI-N-BUTYLALUMINUM B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE TRIBUTYLBORANE B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE LITHIUM HYDRIDO(9-BBN-NOPOL BENZYL ETHER ADDUCT) LITHIUM B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONYL HYDRIDE
- Synthetic Reagents
- Reduction
- Boranes
- 超干溶剂
- 化学助剂
- 化工中间体
- 硼酸及其衍生物
- Reduction
- Synthetic Reagents
- Boranes
- CH3CH233B
- C12H27B
- 三丁基硼烷 溶液
- 三正丁基硼烷, 1M THF溶液
- 三正丁基硼烷
- TRIBUTYLBORANE (1.0M IN THF)
- 三正丁基硼
- 三丁基硼烷
- 三丁基硼, 1.0 M SOLUTION IN THF, SPCSEAL
- 三丁基硼
- 122-56-5
- TIANFU CHEM-- TRIBUTYLBORANE
- Tributylborane (1.0M in THF)
- Tri-n-butylborane, 1M soln. in THF
- Tributylborane, 1M solution in THF, AcroSeal
- Tributylborane,98%
- Tributylborane1M solution in THFAcroSeal§3
- Tributylborane, 1M solution in THF
- 1.0Msolutionintetrahydrofuran
- TRIBUTYLBORANE, 1.0M SOLUTION IN TETRAHY DROFURAN
- TRIBUTYLBORANE, 1.0M SOLUTION IN DIETHYL ETHER
- Tributylborane solution
- Boronbutoxide
- tri-n-butylborane,tnbb
- tri-n-butylborane,
- Tri-n-butylborane
- Tributylborine
- tributyl-boran
- Borane,tributyl-
- Tributylborane, 1M Solution in Tetrahydrofuran
- Tributylborane solution 1.0 M in THF
- Tributylborane, 1.0 M solution in THF, SpcSeal
- Borane, tributyl-
- TRI-N-BUTYLBORON
- Tributylboron
- TRIBUTYLBORANE