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TRIPHENYLBORANE
TRIPHENYLBORANE
- CAS No.960-71-4
- Chemical Name:TRIPHENYLBORANE
- CBNumber:CB4265993
- Molecular Formula:C18H15B
- Formula Weight:242.12
- MOL File:960-71-4.mol
TRIPHENYLBORANE Property
- Melting point 145 °C (lit.)
- Boiling point 203 °C/15 mmHg (lit.)
- Density 0.898 g/mL at 25 °C
- Flash point 1 °F
- form Powder
- color off-white
- Water Solubility Soluble in aromatic solvents. Insoluble in water.
- Sensitive Air Sensitive
- Hydrolytic Sensitivity 4: no reaction with water under neutral conditions
- BRN 1961313
- CAS DataBase Reference 960-71-4(CAS DataBase Reference)
- EWG's Food Scores 1
- FDA UNII 6282553L0G
- EPA Substance Registry System Borane, triphenyl- (960-71-4)
- UNSPSC Code 12352300
- NACRES NA.23
Safety
- Hazard Codes :F,Xn
- Risk Statements :11-36/37/38-22-19-40-36/37
- Safety Statements :16-26-33-36-24/25-22-36/37
- RIDADR :UN 1993 3/PG 2
- WGK Germany :3
- RTECS :ED2367500
- F :10-23
- TSCA :No
- HazardClass :4.1
- PackingGroup :III
-
NFPA 704:
1 2 0
-
Symbol(GHS)
- Signal wordDanger
- Hazard statements H228
- Precautionary statements P210
TRIPHENYLBORANE Price
More Price(6)
- Brand: Sigma-Aldrich(India)
- Product number: T82201
- Product name : Triphenylborane
- Purity: powder, <2% H2O
- Packaging: 2.5G
- Price: ₹6603.25
- Updated: 2022/06/14
- Buy: Buy
- Brand: Sigma-Aldrich(India)
- Product number: T82201
- Product name : Triphenylborane
- Purity: powder, <2% H2O
- Packaging: 10G
- Price: ₹15544.7
- Updated: 2022/06/14
- Buy: Buy
- Brand: Sigma-Aldrich(India)
- Product number: 442445
- Product name : Triphenylborane solution
- Purity: 0.25?M in THF
- Packaging: 25ML
- Price: ₹11225.2
- Updated: 2022/06/14
- Buy: Buy
- Brand: Sigma-Aldrich(India)
- Product number: 442445
- Product name : Triphenylborane solution
- Purity: 0.25?M in THF
- Packaging: 100ML
- Price: ₹18779.6
- Updated: 2022/06/14
- Buy: Buy
- Brand: ottokemi
- Product number: T 8781
- Product name : Triphenylborane powder, <2% H2O
- Purity:
- Packaging: 2.5gm
- Price: ₹7101
- Updated: 2022/05/26
- Buy: Buy
TRIPHENYLBORANE Chemical Properties,Usage,Production
- Uses Triphenylborane is used as a precursor in the production of pyridine-triphenylborane complex, which is used as a catalyst for the polymerization of acrylic esters. It is also used in the hydrocyanation of butadiene to adiponitrile. It is involved in the synthesis of 3-phenyl-cyclohexene by reacting with acetic acid cyclohex-2-enyl ester in presence of palladium bis(dibenzylideneacetone) and triphenylphosphine as a catalyst.
- Uses TRIPHENYLBORANE is a type of Lewis acid used as catalyst and intermediate.
- Synthesis Reference(s) The Journal of Organic Chemistry, 52, p. 5564, 1987 DOI: 10.1021/jo00234a011
- Hazard TRIPHENYLBORANE is a severe eye irritant.
- Purification Methods Recrystallise the borane three times from Et2O or *C6H6 under N2 and dry it at 130o. It can be distilled in a high vacuum at 300-350o and has been distilled (b 195-215o/~15mm) in vacuum using a bath temperature of 240-330o. N2 is introduced into the apparatus before dismantling. It forms complexes with amines. [Nielsen et al. Chem Ind (London) 1069 1957, Wittig et al. Justus Liebigs Ann Chem 563 110 1949, Bent & Dorfman J Am Chem Soc 57 1259 1935, Beilstein 16 IV 1623.]
TRIPHENYLBORANE Preparation Products And Raw materials
Raw materials
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960-71-4, TRIPHENYLBORANERelated Search:
- TETRAPHENYLPHOSPHONIUM TETRAPHENYLBORATE TRIS(PENTAFLUOROPHENYL)BORANE Potassium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate TRIPHENYLBORANE Sodium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate TRIMESITYLBORANE TETRA-N-BUTYLAMMONIUM TETRAPHENYLBORATE Sodium tetraphenylboron Triphenylborane-sodium hydroxide adduct SODIUM TETRAKIS(4-FLUOROPHENYL)BORATE POTASSIUM TETRAKIS(4-CHLOROPHENYL)BORATE Dimethylanilinium tetrakis(pentafluorophenyl)borate TRIS(4-CHLOROPHENYL)BORON LITHIUM TETRAPHENYLBORATE TRIS(1,2-DIMETHOXYETHANE) TRIPHENYLBORANE, 0.25M SOLUTION IN TETRA Pyridine-triphenylborane(1/1),Pyridine-triphenylborane ,PYRIDINE-TRIPHENYLBORANE COMPLEX TRIPHENYLBORANE-TRIPHENYLPHOSPHINE COMPLEX,Triphenylphosphine triphenylborane,Triphenylphosphine triphenylborane COMPLEX Boron
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- BoronAlphabetic
- organoboron and borato-metal complexes
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- 合成材料中间体
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- C18H15B
- C6H53B
- BC6H53
- 三苯硼[烷]
- 三苯基硼烷 溶液
- 三苯基硼烷
- 三苯基硼
- 960-71-4
- TRIPHENYLBORON
- C18H15B TRIPHENYLBORANE 960-71-4
- Triphenylborane, min. 95%
- Triphenylbor
- Methylquecksilber(II)-chlorid 13% Cl
- TRIPHENYLBORON, POWDER, WATER <2%
- triphenyl-boran
- Triphenyboron
- borine,triphenyl
- TRIPHENYLBORINE
- TRIPHENYLBORANE
- BORON TRIPHENYL
- TRIPHENYLBORANE,MIN.95%
- Triphenylborane solution 0.25 M in THF
- Triphenylborane powder, <2% H2O
- Triphenylboron, min. 95%
- triphenylborane solution
- Borane, triphenyl-
- Triphenylboron,min.95%