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TRIPHENYLBORANE

TRIPHENYLBORANE Structure
TRIPHENYLBORANE
  • CAS No.960-71-4
  • Chemical Name:TRIPHENYLBORANE
  • CBNumber:CB4265993
  • Molecular Formula:C18H15B
  • Formula Weight:242.12
  • MOL File:960-71-4.mol
TRIPHENYLBORANE Property
  • Melting point 145 °C (lit.)
  • Boiling point 203 °C/15 mmHg (lit.)
  • Density 0.898 g/mL at 25 °C
  • Flash point 1 °F
  • form Powder
  • color off-white
  • Water Solubility Soluble in aromatic solvents. Insoluble in water.
  • Sensitive Air Sensitive
  • Hydrolytic Sensitivity 4: no reaction with water under neutral conditions
  • BRN 1961313
  • CAS DataBase Reference 960-71-4(CAS DataBase Reference)
  • EWG's Food Scores 1
  • FDA UNII 6282553L0G
  • EPA Substance Registry System Borane, triphenyl- (960-71-4)
  • UNSPSC Code 12352300
  • NACRES NA.23
Safety
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal wordDanger
  • Hazard statements H228
  • Precautionary statements P210
TRIPHENYLBORANE Price More Price(6)
  • Brand: Sigma-Aldrich(India)
  • Product number: T82201
  • Product name : Triphenylborane
  • Purity: powder, <2% H2O
  • Packaging: 2.5G
  • Price: ₹6603.25
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich(India)
  • Product number: T82201
  • Product name : Triphenylborane
  • Purity: powder, <2% H2O
  • Packaging: 10G
  • Price: ₹15544.7
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich(India)
  • Product number: 442445
  • Product name : Triphenylborane solution
  • Purity: 0.25?M in THF
  • Packaging: 25ML
  • Price: ₹11225.2
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich(India)
  • Product number: 442445
  • Product name : Triphenylborane solution
  • Purity: 0.25?M in THF
  • Packaging: 100ML
  • Price: ₹18779.6
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: ottokemi
  • Product number:  T 8781
  • Product name : Triphenylborane powder, <2% H2O
  • Purity: 
  • Packaging: 2.5gm
  • Price: ₹7101
  • Updated: 2022/05/26
  • Buy: Buy

TRIPHENYLBORANE Chemical Properties,Usage,Production

  • Uses Triphenylborane is used as a precursor in the production of pyridine-triphenylborane complex, which is used as a catalyst for the polymerization of acrylic esters. It is also used in the hydrocyanation of butadiene to adiponitrile. It is involved in the synthesis of 3-phenyl-cyclohexene by reacting with acetic acid cyclohex-2-enyl ester in presence of palladium bis(dibenzylideneacetone) and triphenylphosphine as a catalyst.
  • Uses TRIPHENYLBORANE is a type of Lewis acid used as catalyst and intermediate.
  • Synthesis Reference(s) The Journal of Organic Chemistry, 52, p. 5564, 1987 DOI: 10.1021/jo00234a011
  • Hazard TRIPHENYLBORANE is a severe eye irritant.
  • Purification Methods Recrystallise the borane three times from Et2O or *C6H6 under N2 and dry it at 130o. It can be distilled in a high vacuum at 300-350o and has been distilled (b 195-215o/~15mm) in vacuum using a bath temperature of 240-330o. N2 is introduced into the apparatus before dismantling. It forms complexes with amines. [Nielsen et al. Chem Ind (London) 1069 1957, Wittig et al. Justus Liebigs Ann Chem 563 110 1949, Bent & Dorfman J Am Chem Soc 57 1259 1935, Beilstein 16 IV 1623.]
TRIPHENYLBORANE Preparation Products And Raw materials
Raw materials
Preparation Products
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TRIPHENYLBORANE Spectrum
960-71-4, TRIPHENYLBORANERelated Search:
  • TP - TZ
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  • C18H15B
  • C6H53B
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  • 960-71-4
  • TRIPHENYLBORON
  • C18H15B TRIPHENYLBORANE 960-71-4
  • Triphenylborane, min. 95%
  • Triphenylbor
  • Methylquecksilber(II)-chlorid 13% Cl
  • TRIPHENYLBORON, POWDER, WATER <2%
  • triphenyl-boran
  • Triphenyboron
  • borine,triphenyl
  • TRIPHENYLBORINE
  • TRIPHENYLBORANE
  • BORON TRIPHENYL
  • TRIPHENYLBORANE,MIN.95%
  • Triphenylborane solution 0.25 M in THF
  • Triphenylborane powder, <2% H2O
  • Triphenylboron, min. 95%
  • triphenylborane solution
  • Borane, triphenyl-
  • Triphenylboron,min.95%