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Methanesulfonic anhydride

Methanesulfonic anhydride  Structure
Methanesulfonic anhydride
  • CAS No.7143-01-3
  • Chemical Name:Methanesulfonic anhydride
  • CBNumber:CB1109276
  • Molecular Formula:C2H6O5S2
  • Formula Weight:174.19
  • MOL File:7143-01-3.mol
Methanesulfonic anhydride Property
  • Melting point 64-67 °C (lit.)
  • Boiling point 125 °C/4 mmHg (lit.)
  • Density 1,36 g/cm3
  • vapor density 3.3 (vs air)
  • refractive index 1.5300 (estimate)
  • Flash point 125°C/4mm
  • storage temp. Store at <= 20°C.
  • solubility Soluble in organic solvents.
  • form Powder, Crystals and/or Chunks
  • color White to light brown to gray
  • Sensitive Moisture Sensitive
  • BRN 972316
  • InChIKey IZDROVVXIHRYMH-UHFFFAOYSA-N
  • CAS DataBase Reference 7143-01-3(CAS DataBase Reference)
  • FDA UNII J492U7J4PB
  • NIST Chemistry Reference Methanesulfonic anhydride(7143-01-3)
  • EPA Substance Registry System Methanesulfonic acid, anhydride (7143-01-3)
  • UNSPSC Code 12352106
  • NACRES NA.22
Safety
  • Hazard Codes  :C
  • Risk Statements  :14-35
  • Safety Statements  :26-36/37/39-45
  • RIDADR  :UN 3261 8/PG 2
  • WGK Germany  :3
  • F  :3-10
  • TSCA  :Yes
  • HazardClass  :8
  • PackingGroup  :III
  • HS Code  :29041000
  • NFPA 704:
    1
    3 2
    W
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal wordDanger
  • Hazard statements H314
  • Precautionary statements P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363
Methanesulfonic anhydride Price More Price(9)
  • Brand: Sigma-Aldrich(India)
  • Product number: 269190
  • Product name : Methanesulfonic anhydride
  • Purity: 97%
  • Packaging: 5G
  • Price: ₹1909.55
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich(India)
  • Product number: 269190
  • Product name : Methanesulfonic anhydride
  • Purity: 97%
  • Packaging: 25G
  • Price: ₹4874.1
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: ALFA India
  • Product number: ALF-A13328-30
  • Product name : Methanesulfonic anhydride, 98%
  • Purity: 
  • Packaging: 250g
  • Price: ₹58857
  • Updated: 2022/05/26
  • Buy: Buy
  • Brand: ALFA India
  • Product number: ALF-A13328-18
  • Product name : Methanesulfonic anhydride, 98%
  • Purity: 
  • Packaging: 50g
  • Price: ₹9990
  • Updated: 2022/05/26
  • Buy: Buy
  • Brand: ALFA India
  • Product number: ALF-A13328-14
  • Product name : Methanesulfonic anhydride, 98%
  • Purity: 
  • Packaging: 25g
  • Price: ₹3790
  • Updated: 2022/05/26
  • Buy: Buy

Methanesulfonic anhydride Chemical Properties,Usage,Production

  • Chemical Properties white to light brown to grey powder, crystals and/
  • Uses Methanesulfonic anhydride is used to prepare methylsulfonyl esters called as mesylates. It finds application in the reaction of aromatic alkylation. It reacts with dimethylsulfoxide to get sulfoxonium complex, which is a useful oxidizing agent.
  • Preparation Methanesulfonic anhydride may be prepared by the dehydration of methanesulfonic acid with phosphorus pentoxide.
    P2O5 + 6 CH3SO3H → 3 (CH3SO2)2O + 2 H3PO4
    Methanesulfonic anhydride can be purified by distillation under vacuum (distillation of a solid) or by recrystallized from Methyl tert-butyl ether/toluene.
  • Safety Not only is Methanesulfonic anhydride corrosive, posing potential risks to skin, eyes, and mucous membranes, but it is also sensitive to moisture. As a hygroscopic substance, exposure to water can lead to degradation, compromising its efficacy and safety. Therefore, meticulous storage conditions are paramount to ensure the stability of the compound. To safeguard the integrity of methanesulfonic anhydride, storing it in a cool and dry environment is recommended. The storage facility should be adequately ventilated to prevent the accumulation of vapors and maintain optimal conditions for the compound. Furthermore, the storage containers must be tightly sealed to prevent moisture ingress and subsequent degradation.
Methanesulfonic anhydride Preparation Products And Raw materials
Raw materials
Preparation Products
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