Synthesis
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(1S)-(+)-Camphor-10-sulphonic acid

Synthesis
(1S)-(+)-Camphor-10-sulphonic acid Structure
(1S)-(+)-Camphor-10-sulphonic acid
  • CAS No.3144-16-9
  • Chemical Name:(1S)-(+)-Camphor-10-sulphonic acid
  • CBNumber:CB0395928
  • Molecular Formula:C10H16O4S
  • Formula Weight:232.3
  • MOL File:3144-16-9.mol
(1S)-(+)-Camphor-10-sulphonic acid Property
  • Melting point 196-200 °C (dec.)(lit.)
  • Boiling point 344.46°C (rough estimate)
  • alpha 22 º (589nm, c=20, H2O 25 ºC)
  • Density 1.2981 (rough estimate)
  • refractive index 21.5 ° (C=5, H2O)
  • storage temp. Store below +30°C.
  • solubility Exhibit moderate solubility in HCCl.
  • pka 1.17±0.50(Predicted)
  • form Crystalline Powder
  • color White to off-white
  • PH 0.3 (200g/l, H2O)
  • optical activity [α]20/D +21.5±1°, c = 10% in H2O
  • biological source human
  • Water Solubility SOLUBLE
  • Sensitive Hygroscopic
  • Merck 14,1734
  • BRN 2809675
  • Stability Stable. Protect from moisture. Incompatible with strong oxidizing agents, strong bases.
  • InChIKey MIOPJNTWMNEORI-GMSGAONNSA-N
  • CAS DataBase Reference 3144-16-9(CAS DataBase Reference)
  • FDA UNII 9TLZ01S15L
  • EPA Substance Registry System Bicyclo[2.2.1]heptane-1-methanesulfonic acid, 7,7-dimethyl-2-oxo-, (1S,4R)- (3144-16-9)
  • UNSPSC Code 41116107
  • NACRES NA.32
Safety
  • Hazard Codes  :C
  • Risk Statements  :34
  • Safety Statements  :26-36/37/39-45-25-27
  • RIDADR  :UN 3261 8/PG 2
  • WGK Germany  :3
  • RTECS  :ED1550000
  • F  :3-10
  • TSCA  :Yes
  • HazardClass  :8
  • PackingGroup  :III
  • HS Code  :29147090
  • NFPA 704:
    0
    3 0
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal wordDanger
  • Hazard statements H290-H314
  • Precautionary statements P234-P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
(1S)-(+)-Camphor-10-sulphonic acid Price More Price(18)
  • Brand: Sigma-Aldrich(India)
  • Product number: C2107
  • Product name : (1S)-(+)-10-Camphorsulfonic acid
  • Purity: 99%
  • Packaging: 5G
  • Price: ₹2002.63
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich(India)
  • Product number: C2107
  • Product name : (1S)-(+)-10-Camphorsulfonic acid
  • Purity: 99%
  • Packaging: 100G
  • Price: ₹4719.7
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich(India)
  • Product number: SRP5102
  • Product name : Mortalin (47-end), GST tagged human
  • Purity: recombinant, expressed in baculovirus infected Sf9 cells, ≥70% (SDS-PAGE), buffered aqueous glycerol solution
  • Packaging: 50μG
  • Price: ₹36502.4
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich(India)
  • Product number: C2107
  • Product name : (1S)-(+)-10-Camphorsulfonic acid
  • Purity: 99%
  • Packaging: 500G
  • Price: ₹15717.9
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich(India)
  • Product number: 8.22311
  • Product name : (1S)-(+)-Camphor-10-sulfonic acid
  • Purity: for resolution of racemates for synthesis
  • Packaging: 100G
  • Price: ₹12240
  • Updated: 2022/06/14
  • Buy: Buy

(1S)-(+)-Camphor-10-sulphonic acid Chemical Properties,Usage,Production

  • Synthesis (1S)-(+)-Camphor-10-sulphonic acid can be obtained from natural camphor by brominated sulfonation .
  • Chemical Properties white to light beige powder
  • Uses (1S)-(+)-Camphor-10-sulfonic acid is used as stabilizer. (+)-(1S)-camphor-10-sulfonic acid being a very effective resolving agent. . Chiral polyaniline(PANI) nanofibers were synthesized via facilely potentiostatic electropolymerization method without template in the presence of(1S)-(+)camphor-10-sulfonic acid(D-CSA) or(1R)-(-)camphor-10-sulfonic acid(L-CSA) as the dopant. Synthesis of QUATs derived from (1S)-(+)camphor-10-sulfonic acid.
  • Uses Used as a resolving agent, and as a catalyst for coupling dipeptides.
  • Definition ChEBI: (S)-camphorsulfonic acid is the S enantiomer of camphorsulfonic acid. It is a conjugate acid of a (S)-camphorsulfonate. It is an enantiomer of a (R)-camphorsulfonic acid.
  • Purification Methods Crystallise the acid from ethyl acetate and dry it under vacuum (deliquescent). [Loudon J Chem Soc 823 1933, Komppa J Prakt Chem 162 19 1943, Beilstein 11 IV 642.] See above for RS-isomer.
(1S)-(+)-Camphor-10-sulphonic acid Preparation Products And Raw materials
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(1S)-(+)-Camphor-10-sulphonic acid Suppliers
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(1S)-(+)-Camphor-10-sulphonic acid Spectrum
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