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Borane-tetrahydrofuran complex Structure

Borane-tetrahydrofuran complex

Chemical Properties

Melting point -17 °C
Boiling point 35 °C
Density  0.898 g/mL at 25 °C
Flash point 1 °F
storage temp.  Store at <= 20°C.
form  Liquid
color  Colorless
Water Solubility  REACTS
Sensitive  Air & Moisture Sensitive
BRN  3668402
Exposure limits ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)
Stability Stable, but may form explosive peroxides in contact with air. Incompatible with acids, acid chlorides, acid anhydrides, oxidizing agents, alcohols. Reacts violently with water. Highly flammable. Store under inert gas.
CAS DataBase Reference 14044-65-6(CAS DataBase Reference)
FDA UNII 5EAR4ERR1L
EPA Substance Registry System Boron, trihydro(tetrahydrofuran)-, (T-4)- (14044-65-6)

Safety

Symbol(GHS)
Signal wordDanger
Hazard statements H225-H260-H302-H315-H318-H335-H351-H319-H333
Precautionary statements P223-P303+P361+P353-P305+P351+P338-P405-P501a-P210-P231+P232-P280-P370+P378-P402+P404-P403+P235
Hazard Codes  F,Xn,Xi
Risk Statements  14/15-19-22-36/37/38-41-37/38-11-67-66-40-36/37
Safety Statements  16-33-36/37/39-7/9-7/8-43-37/39-26-36-29-36/37
RIDADR  UN 3399 4.3/PG 1
WGK Germany  3
1-10-13-34
TSCA  Yes
HazardClass  4.3
PackingGroup  I
HS Code  29321900
NFPA 704:
3
2 2
W

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