(1S,2R)-(-)-cis-1-Amino-2-indanol

Reaction

1. Ligand component used in the chromium-catalyzed highly selective asymmetric ene reactions between aryl aldehydes and alkoxy- and silyloxyalkenes.
2. Ligand component for the chromium-catalyzed highly enantioselective o inverse-demand hetero-Diels-Alder reactions of α,β-unsaturated aldehydes.
3. Ligand component for the magnesium-catalyzed conjugate addition reaction of 1,3-dicarbonyl compounds to nitroalkenes.
4. Component for stereoselective asymmetric 6π-azaelectrocyclization through the reaction between the (E)-3-
5. carbonyl-2,4,6-trienal compounds and the (-)-7-alkyl-cis-1-amino-2-indanol derivatives.
6. Ligand component for palladium-catalzyed asymmetric azaelectrocyclization for the preparation of 2,4-
7. disubstituted chiral 1,2,5,6-tetrahydropyridines.
8. Component for organocatalytic conjugate addition of formaldehyde N,N-dialkylhydrazones to β,γ -Unsaturated α-keto esters.
9. N-Sulfinyl urea organocatalyst component for enantioselective aza-henry reaction.
10. Component for organocatalytic enantioselective additions of indoles to nitroalkenes.

Chemical Properties

Uses

Uses

• (-)-1,2,5,6-Tetrahydropyridine by reacting with methyl (E,E)-4-oxo-2-[(2,6,6-trimethylcyclohex-1-enyl)vinyl}but-2-enoate.
• Oxazaborolidine catalysts, which can catalyze the asymmetric reduction of aromatic ketones with high enantioselectivity.
• (R_S,1S,2R)-(-)-2,4,6-Trimethylbenzenesulfinic acid 1-(2,4,6-trimethylbenzenesulfonylamino)indan-2-yl ester.

General Description