CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I)

Reaction

1. Catalyst for the intramolecular carbonylative [2+2+1] cycloaddition of allenynes.
2. Catalyst for the selective hydrogenation of myrcene.
3. Catalyst for silylation of ortho-functionalized aryl halides with hydrosilanes.
4. Catalyst for synthesis of aldenamines from carboxamides by silane-reduction/dehydration under mild conditions.
5. Hydrogen atom transfer catalyst for radical cyclizations.
6. Complex for photocatalytic alkane dehydrogenation.
7. Catalyst for chemoselective reductive nucleophilic addition to N-methoxyamides.
8. Catalyst for chemoselective reductive alkynylation of tertiary amides.

Chemical Properties

Uses