ChemicalBook CAS DataBase List Cyclopropanecarboxaldehyde

Cyclopropanecarboxaldehyde

Product NameCyclopropanecarboxaldehyde
CAS1489-69-6
CBNumberCB4132338
MFC4H6O
MW70.09
EINECS620-777-5
MDL NumberMFCD00012261
MOL File1489-69-6.mol
MSDS FileSDS

Chemical Properties

Boiling point	98-101 °C (lit.)
Density	0.938 g/mL at 25 °C (lit.)
refractive index	n20/D 1.4298(lit.)
Flash point	45 °F
storage temp.	2-8°C
solubility	soluble in Chloroform
form	clear liquid
color	Colorless to Light orange to Yellow
Water Solubility	Soluble in water.
Sensitive	Air Sensitive
BRN	906781
Stability	Volatile
InChI	1S/C4H6O/c5-3-4-1-2-4/h3-4H,1-2H2
InChIKey	JMYVMOUINOAAPA-UHFFFAOYSA-N
SMILES	O=CC1CC1
CAS DataBase Reference	1489-69-6(CAS DataBase Reference)
EWG's Food Scores	1
NIST Chemistry Reference	Cyclopropanecarboxaldehyde(1489-69-6)
EPA Substance Registry System	Cyclopropanecarboxaldehyde (1489-69-6)
UNSPSC Code	12352100
NACRES	NA.22

Safety

Symbol(GHS)

Signal word

Danger

Hazard statements

H225-H314

Precautionary statements

P210-P233-P240-P280-P303+P361+P353-P305+P351+P338

Hazard Codes

F,C

Risk Statements

11-34

Safety Statements

16-26-36/37/39-45

RIDADR

UN 2924 3/PG 2

WGK Germany

RTECS

GZ1005000

TSCA

TSCA listed

HazardClass

PackingGroup

HS Code

29122990

Storage Class

3 - Flammable liquids

Hazard Classifications

Flam. Liq. 2
Skin Corr. 1B

NFPA 704:

	3
3		0

Cyclopropanecarboxaldehyde Price

Product number	Packaging	Price	Product description	Buy
Sigma-Aldrich 272213	1g	$52.6	Cyclopropanecarboxaldehyde 98%	Buy
Sigma-Aldrich 272213	5g	$139	Cyclopropanecarboxaldehyde 98%	Buy
TCI Chemical C1707	1g	$38	Cyclopropanecarboxaldehyde >97.0%(GC)	Buy
TCI Chemical C1707	5g	$109	Cyclopropanecarboxaldehyde >97.0%(GC)	Buy
TRC TRC-C989650-5G	5g	$140	Cyclopropanecarboxaldehyde	Buy

Cyclopropanecarboxaldehyde Chemical Properties,Usage,Production

Chemical Properties

clear colorless liquid

Uses

Cyclopropanecarboxaldehyde reacts with Grignard or organolithium reagents to give the expected secondary alcohols. These are susceptible to ring opening in the presence of HBr, providing stereoselective access to homoallylic bromides. It is also used in the synthesis of eta(2)-enonenickel complexes by reacting with [Ni(cod)(2)] (cod = 1,5-cyclooctadiene) and PBu(3) and to prepare a cyclopropylidene tetralone which underwent an enantioselective palladium-catalyzed [3+2] TMM cycloaddition providing a chiral spiro-fused cyclopentene.

Definition

ChEBI: Cyclopropanecarbaldehyde is an organooxygen compound.

Application

Cyclopropanecarboxaldehyde is a reagent in the preparation of N-alkylphenylalaninamides of pyridinylphenyland oxobipyridinylamines as human GPR 142 agonists for potential use as anti-diabetic agents and the cytochrome P 450 inhibition.

Preparation

Cyclopropanecarboxaldehyde is prepared by reaction of cyclopropylmethanol. The reaction needs reagent pyridinium chlorochromate and solvent CH2Cl2 with other condition of ambient temperature for 3 hours. The yield is about 60%.

General Description

Cyclopropanecarboxaldehyde is a bifunctional compound containing a cyclopropane ring and an aldehyde group. It serves as an important intermediate in the synthesis of various cyclopropane derivatives and can participate in a range of reactions, such as condensation, reduction and oxidation, to build more complex molecules.

Cyclopropanecarboxaldehyde synthesis

Preparation Products And Raw materials

Cyclopropanecarboxaldehyde Supplier

Supplier	Tel	Email	Country	ProdList	Advantage
Sichuan Weibo Science and Technology Co.,Ltd	028-65199188 13880582998	ellnn@163.com	China	19	58
Lanzhou Hongsheng Fine Chemical Co., Ltd.	15693160370; 15693160393	lzhschemical@163.com	China	58	58
Chengdu Apis Pharmaceutical Technology Co.,Ltd	13568817957	dudes@163.com	China	300	58
Zhejiang zetian fine chemical co. LTD	0571-87322520 18957127338	June@zetchem.com	China	382	58
Zhejiang Karry Pharmachem Co., Ltd.	19157666807	info@karrypharma.com	China	37	58
Shanghai Chainpharm Bio-medical Technology Co., Ltd.	+86-021-61727342 13611721451	sales@chainpharm.com	China	985	58
GT Chemical & Technology (changzhou) Co.,Ltd	0519-86889226 18015049226	jifuzhong01@163.com	China	41	58
Shanghai RC Chemicals Co., Ltd.	21-58661250 18217085189;	3059772675@qq.com	China	131	64
Xi 'an billiton biological technology co., LTD	029-88764766	wang.yali@xatuochao.com	China	522	58
J & K SCIENTIFIC LTD.	18210857532 18210857532	jkinfo@jkchemical.com	China	96815	76

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Cyclopropanecarboxaldehyde

Chemical Properties

Safety

Cyclopropanecarboxaldehyde Price

Cyclopropanecarboxaldehyde Chemical Properties,Usage,Production

Cyclopropanecarboxaldehyde synthesis

Preparation Products And Raw materials

Cyclopropanecarboxaldehyde Supplier

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