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Cyclopropanecarboxaldehyde

Basic information Description Safety Related Supplier
Cyclopropanecarboxaldehyde Basic information
Cyclopropanecarboxaldehyde Chemical Properties
Safety Information
  • Hazard Codes F,C
  • Risk Statements 11-34
  • Safety Statements 16-26-36/37/39-45
  • RIDADR UN 2924 3/PG 2
  • WGK Germany 3
  • RTECS GZ1005000
  • TSCA Yes
  • HazardClass 3
  • PackingGroup II
  • HS Code 29122990
MSDS
Cyclopropanecarboxaldehyde Usage And Synthesis
  • DescriptionCyclopropanecarboxaldehyde can react with Grignard or organolithium reagents to give the expected secondary alcohols. These are susceptible to ring opening in the presence of HBr, providing stereoselective access to homoallylic bromides. It is also used in the synthesis of eta(2)-enonenickel complexes by reacting with [Ni(cod)(2)] (cod = 1,5-cyclooctadiene) and PBu(3) and to prepare a cyclopropylidene tetralone which underwent an enantioselective palladium-catalyzed [3+2] TMM cycloaddition providing a chiral spiro-fused cyclopentene1-2. It is also a reagent in the preparation of N-alkylphenylalaninamides of pyridinylphenyland oxobipyridinylamines as human GPR 142 agonists for potential use as anti-diabetic agents and the cytochrome P 450 inhibition3.
  • Chemical Propertiesclear colorless liquid
  • Usessuzuki reaction
Cyclopropanecarboxaldehyde Preparation Products And Raw materials
Cyclopropanecarboxaldehyde(1489-69-6)Related Product Information
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