Acetamiprid

Bezeichnung:Acetamiprid

CAS-Nr135410-20-7

Englisch Name:Acetamiprid

CBNumberCB9351350

SummenformelC10H11ClN4

Molgewicht222.67

MOL-Datei135410-20-7.mol

Acetamiprid physikalisch-chemischer Eigenschaften

Schmelzpunkt	101-103°C
Siedepunkt	352.4±52.0 °C(Predicted)
Dichte	1.17
Dampfdruck	<1 x 10^-6 Pa (25 °C)
storage temp.	Inert atmosphere,2-8°C
Löslichkeit	DMSO: Soluble; Methanol: Soluble
Aggregatzustand	A solid
pka	-0.44±0.10(Predicted)
Wasserlöslichkeit	4200 mg l^-1 (25 °C)
Farbe	White to off-white
InChI	InChI=1S/C10H11ClN4/c1-8(14-7-12)15(2)6-9-3-4-10(11)13-5-9/h3-5H,6H2,1-2H3/b14-8+
InChIKey	WCXDHFDTOYPNIE-RIYZIHGNSA-N
SMILES	C(/N(CC1=CC=C(Cl)N=C1)C)(=N\C#N)\C
CAS Datenbank	135410-20-7(CAS DataBase Reference)
NIST chemische Informationen	Acetamipride(135410-20-7)
EPA chemische Informationen	Acetamiprid (135410-20-7)

Sicherheit

Kennzeichnung gefährlicher	T
R-Sätze:	23/25-57-52/53
S-Sätze:	45-61
RIDADR	2588
RTECS-Nr.	KJ4235200
HazardClass	6.1(b)
PackingGroup	III
HS Code	29333990
Giftige Stoffe Daten	135410-20-7(Hazardous Substances Data)

Gefahreninformationscode (GHS)

Acetamiprid Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R23/25:Giftig beim Einatmen und Verschlucken.
R57:Giftig für Bienen.
S-Sätze Betriebsanweisung:
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
Chemische Eigenschaften
Pale Yellow Solid
Verwenden
A novel neonicotinid insecticide against Holotrichia consanguinea in sugarcane. Reports show that when exposed to neonicotinid pesticides honeybees have probelms returnign home after foraging and bumb lebee colonies grow poorly and produce fewer queens.
Verwenden
Acetamiprid is a systemic insecticide for soil and foliar application. It is used to control Hemiptera, especially aphids, Thysanoptera and Lepidoptera on a wide range of crops, especially vegetables, fruit and tea.
Definition
ChEBI: The (E)-stereoisomer of acetamiprid.
Landwirtschaftliche Anwendung
Insecticide: This class of pesticides are chemically related to nicotine and used on corn and soybean seeds and are used to control sucking and chewing insects, and soil insects including aphids, beetles, fruit moth, leaf-hoppers and-miners, thrips, whiteflies [83] . Also used to control fleas on domestic animals.
Stoffwechselwegen
Acetamiprid is relatively stable to hydrolysis and to photodegradation by sunlight. It is rapidly degraded in soils to form 6-chloropyridinyldimethylamine and 6-chloronicotinic acid. The main pathways of metabolism in plants are N-demethylation and subsequent oxidation affording 6-chloronicotinic acid and 6-chloropicolyl alcohol. Two N-cyanoamidines were formed after application of acetamiprid to cabbage leaves. No information is available on the fate of the insecticide in insects or mammals.
Degradation
Acetamiprid is stable in buffer solutions at pH 4, 5 and 7 and under sunlight. It is degraded slowly at pH 9 (45 °C) (PM). In a study of its hydrolysis acetamiprid was converted quantitatively to N-methyl- (6-chloro-3-pyridyl)methylamine (2) in 0.5-1 N sodium hydroxide at 90-95°C in 2 hours (see Scheme 1). N-Demethyl-acetamiprid (3) was converted to (6-chloro-3-pyridyl)methylamine(4) at the same rate and under similar conditions (Tokieda et al., 1997).

Acetamiprid Upstream-Materialien And Downstream Produkte

Acetamiprid Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

135410-20-7, Acetamiprid Verwandte Suche:

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