Cyanamid

Gefahreninformationscode (GHS)

• Bildanzeige (GHS)

  

• Alarmwort

  Achtung

• Gefahrenhinweise

  H314：Verursacht schwere Verätzungen der Haut und schwere Augenschäden.

  H317：Kann allergische Hautreaktionen verursachen.

  H351：Kann vermutlich Krebs verursachen.

  H373：Kann die Organe schädigen bei längerer oder wiederholter Exposition.

  H412：Schädlich für Wasserorganismen, mit langfristiger Wirkung.

• Sicherheit

  P260：Dampf/Aerosol/Nebel nicht einatmen.

  P273：Freisetzung in die Umwelt vermeiden.

  P280：Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.

  P303+P361+P353：BEI BERÜHRUNG MIT DER HAUT (oder dem Haar): Alle kontaminierten Kleidungsstücke sofort ausziehen. Haut mit Wasser abwaschen oder duschen.

  P305+P351+P338：BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach Möglichkeit entfernen. Weiter spülen.

Cyanamide Chemische Eigenschaften,Einsatz,Produktion Methoden

• ERSCHEINUNGSBILD

  FARBLOSE, HYGROSKOPISCHE, ZERFLIESSLICHE KRISTALLE

• ARBEITSPLATZGRENZWERTE

  TLV: 2 mg/m?(als TWA); (ACGIH 2007).
  MAK: 1 mg/m?(Einatembare Fraktion); Spitzenbegrenzung: überschreitungsfaktor II(2); Hautresorption; Sensibilisierung der Haut (Sh); Schwangerschaft: Gruppe C; (DFG 2007).
  EG Arbeitsplatz-Richtgrenzwerte: 0.58 ppm; 1 mg/m?(als TWA) Hautresorption (EU 2006).
  

• AUFNAHMEWEGE

  Aufnahme in den Körper durch Inhalation des Aerosols, über die Haut und durch Verschlucken.

• INHALATIONSGEFAHREN

  Eine gesundheitsschädliche Partikelkonzentration in der Luft kann schnell erreicht werden beim Dispergieren, vor allem als Pulver.

• WIRKUNGEN BEI KURZZEITEXPOSITION

  WIRKUNGEN BEI KURZZEITEXPOSITION:
  Die Substanz reizt stark die Augen und die Haut und reizt die Atemwege. (siehe ANMERKUNGEN).

• WIRKUNGEN NACH WIEDERHOLTER ODER LANGZEITEXPOSITION

  Wiederholter oder andauernder Kontakt kann zu Hautsensibilisierung führen. Tierversuche zeigen, dass die Substanz möglicherweise fruchtbarkeitsschädigend oder entwicklungsschädigend wirken kann.

• LECKAGE

  Persönliche Schutzausrüstung: Vollschutzanzug mit umgebungsluftunabhängigem Atemschutzgerät. Verschüttetes Material aufsaugen. Reste sorgfältig sammeln. An sicheren Ort bringen. NICHT in die Umwelt gelangen lassen.

• R-Sätze Betriebsanweisung:

  R21:Gesundheitsschädlich bei Berührung mit der Haut.
  R25:Giftig beim Verschlucken.
  R36/38:Reizt die Augen und die Haut.
  R43:Sensibilisierung durch Hautkontakt möglich.

• S-Sätze Betriebsanweisung:

  S3:Kühl aufbewahren.
  S22:Staub nicht einatmen.
  S36/37:Bei der Arbeit geeignete Schutzhandschuhe und Schutzkleidung tragen.
  S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).

• Beschreibung

  Cyanamide and its salts are used on various occasions, such as in chemistry, in anti-rust solutions or in drugs for treating alcoholism (Come).

• Chemische Eigenschaften

  Cyanamide is a combustible crystalline solid, but it is usually found as a 25% liquid solution.

• Chemische Eigenschaften

  white crystalline solid

• Verwenden

  Fumigants, metal cleaners, production of synthetic rubber, chemical synthesis

• Verwenden

  Cyanamide is commonly used in liquid solution and is expected to be soluble in water, ether, benzene, acetone, phenols, amines, ketones, and alcohols. It is used mainly in agriculture as a restbreaking agent and in pharmaceutical industries in the production of antihistamines, antihelminthics, and many other drugs.

• Verwenden

  In Europe, cyanamide is used as a fertilizer, weed killer, and defoliant. In North America, these applications have been practically discontinued. It is also used to produce cationic starch and calcium cyanide, dicyandiamide, and melamine. New uses include intermediates for pesticides; detergents; medicines such as antihistamines, hypertension, sedatives, and contraceptives; photography industry; additive for fuels and lubricants; paper preservative; and cement additive. Dormex is a common rest-breaking agent applied in spring to stimulate uniform opening of buds.
  Cyanamide has been tested as an effective and welltolerated pharmacological adjunct to treat alcohol-dependent patients. It is a potent aldehyde dehydrogenase inhibitor, and alters cholinergic function in the frontal cortex and hippocampus of rats exposed to ethanol.

• Vorbereitung Methode

  The basic process for the manufacture of cyanamide comprises four steps. The first three steps produce calcium cyanamide: lime is made from high grade limestone; (2) calcium carbide is manufactured from lime and coal or coke; calcium cyanamide is produced by passing gaseous nitrogen through a bed of calcium carbide with 1% calcium fluorspar, which is heated to 1000–1100°C to start the reaction—the heat source is then removed and the reaction continues because of its strong exothermic character; and cyanamide is manufactured from calcium cyanamide by continuous carbonation in an aqueous medium.

• Definition

  cyanamide: 1. An inorganic saltcontaining the ion CN₂^{2-. See calciumcyanamide. 2. A colourless crystallinesolid, H₂NCN, made by the actionof carbon dioxide on hotsodamide. It is a weakly acidic compound(the parent acid of cyanamidesalts) that is soluble in water andethanol. It is hydrolysed to urea inacidic solutions.}

• Reaktionen

  Cyanamide reacts (1) as a base with strong acids forming salts, (2) as an acid forming metallic salts, such as calcium cyanamide CaCN2. Cyanamide is formed (1) by reaction of cyanogen chloride CN·Cl plus ammonia (ammonium chloride also formed), (2) by reaction of thiourea plus lead hydroxide (lead sulfide also formed).

• Allgemeine Beschreibung

  Colorless deliquescent crystals. Mp: 45°C; bp: 260°C. Density: 1.282 g cm-3. Quite soluble in water (77 g / 100 g solution at 15°C). Soluble in butanol, methyl ethyl ketone, ethyl acetate, alcohols, phenols, amines, ethers. Note: The term "Cyanamide" is also used to refer to the important compound calcium Cyanamide, which is a different chemical.

• Reaktivität anzeigen

  Cyanamide is the amide of cyanic acid. Non-flammable but combustible (flash point: 140°C). Decomposes on warming above 49°C. Emits toxic fumes of CN- and NOx when heated to decomposition or on contact with acids or acid fumes (Hazardous Chemicals Desk Reference, p. 353 (1987)). Contact with moisture, acids or bases may cause a violent reaction at temperatures above about 40°C. Dry solid may polymerize at temperatures above 122°C. Rapid or explosive polymerization may occur during the evaporation of aqueous solutions. Reacts explosively with strong oxidizing agents and strong reducing agents. Attacks various metals (International Chemical Safety Card).

• Hazard

  Strong irritant to skin and mucous membranes; avoid inhalation or ingestion.

• Health Hazard

  Cyanamide is an irritant of the eyes, mucous membranes, and skin; it is an inhibitor of aldehyde dehydrogenase and can cause an “antabuse” effect with ethanol ingestion.
  Cyanamide is severely irritating and caustic to the eyes, skin, and respiratory tract.

• Flammability and Explosibility

  Not classified

• Landwirtschaftliche Anwendung

  Cyanamide, the trade name for calcium cyanamide, contains calcium hydroxide and carbon in small quantities as impurities. It is used as a fertilizer, the powdered form of which contains about 22% nitrogen.

• Landwirtschaftliche Anwendung

  Herbicide, Plant growth regulator: A U.S. EPA restricted Use Pesticide (RUP). Not currently approved for use in EU countries (re-submitted). Used primarily as a plant growth regulator. Cyanamide may be melted to give a dimer, dicyandiamide or cyanoguanidine. At higher temperatures it gives the trimer, melamine, a raw material for melamine-formaldehyde resins.

• Handelsname

  DORMEX®; SKW 83010®

• Kontakt-Allergie

  Cyanamide and its salts are used in various occasions such as in chemistry, in antirust solutions, or in a drug (Come?) for treating alcoholism (inhibition of alcohol deshydrogenase).

• Sicherheitsprofil

  Poison by ingestion, inhalation, and intraperitoneal routes. Moderately toxic by skin contact. Experimental reproductive effects. Combustible when exposed to heat or flame. To fight fire, use CO2, dry chemical. Thermally unstable. Contact with moisture (water), acids, or alkalies may cause a violent reaction above 40'. Concentrated aqueous solutions may undergo explosive polymerization. Mixture with 1,2 phenylenediamine salts may cause explosive polymerization. When heated to decomposition or on contact with acid or acid fumes, it emits toxic fumes of CNand NOx. See also CYANIDE and AMIDES.

• mögliche Exposition

  Cyanamide may be melted to give a dimer, dicyandiamide or cyanoguanidine. At higher tem- peratures it gives the trimer, melamine; a raw material for melamine-form aldehyde resins.

• Erste Hilfe

  If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit.

• Lager

  (1) Color Code—Yellow: Reactive Hazard; Storein a location separate from other materials, especially flammables and combustibles. (2) Color Code—Blue: HealthHazard/Poison: Store in a secure poison location. Prior toworking with this chemical you should be trained on itsproper handling and storage. Store in tightly closed containers in a cool well-ventilated area away from acids or acidfumes. Cyanamide can be stored in glass containers if it isstabilized with phosphoric, acetic, sulfuric, or boric acid; itattacks iron and steel, copper, and brass.
  Sources of ignition, such as smoking and open flames, areprohibited where cyanamide is used, handled, or stored in amanner that could create a potential fire or explosion hazard.Wherever cyanamide is used, handled, manufactured, orstored, use explosion-proof electrical equipment and fittings.

• Versand/Shipping

  UN3276 Nitriles, liquid, toxic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required, Potential Inhalation Hazard (Special Provision 5).

• läuterung methode

  Purify it by placing ca 15g in a Soxhlet thimble and extracting exhaustively (2-3hours) with two successive portions of Et2O (400mL, saturated with H2O by shaking before use) containing two drops of 1N acetic acid. Two successive portions of Et2O are used so that the NH2CN is not heated for too long. Each extract is dried over Na2SO4 (30g), then combined and evaporated under reduced pressure. The NH2CN may be stored unchanged at 0o in Et2O solution in the presence of a trace of AcOH. Extracts from several runs may be combined and evaporated together. The residue from evaporation of an Et2O solution is a colourless viscous oil which sets to a solid and can be recrystallised from a mixture of 2 parts of *C6H6 and 1 part of Et2O. Concentrating an aqueous solution of NH2CN at high temperatures causes EXPLOSIVE polymerisation. [Kurzer & Lawson Org Synth Coll Vol IV 645 1963, Pinck & Salissbury Inorg Synth III 39 1950, Soloway & Lipschitz J Org Chem 23 613 1958.] Hygroscopic.[Beilstein 3 IV 145.]

• Toxicity evaluation

  Adsorption–desorption studies in soil have estimated very low Koc values (0–6.81 ml g^-1 ) indicating low adsorption and high mobility potential of cyanamide in soil; however, soil column leaching studies indicate that cyanamide is only slightly mobile. Volatilization is not expected to be an important fate and transport process based on the Henry’s law constant and vapor pressure. When released into the air, vapor phase cyanamide is expected to have a half-life of less than 1 day. Aerobic biodegradation is expected to occur, with cyanamide serving as source of nitrogen and carbon. The estimated half-life of cyanamide from the water phase of the aquatic systems was 2.3 days for the river system and 4.3 days for the pond system, respectively. Bioconcentration and bioaccumulation potential is expected to be low, based on the estimated bioconcentration factor and experimental octanol–water partition coefficient.

• Inkompatibilitäten

  Cyanamide may polymerize at tempera- tures above 122℃ , or on evaporation of aqueous solutions. Reacts with acids, strong oxidants, strong reducing agents such as hydrides and water, causing explosion and toxic hazard. Attacks various metals. Decomposes when heated above 49℃ C, on contact with acids, bases, 1,2-phenylene diamine salts; and moisture; producing toxic fumes includ- ing nitrogen oxides and cyanides. Nitriles may polymerize in the presence of metals and some metal compounds. They are incompatible with acids; mixing nitriles with strong oxidizing acids can lead to extremely violent reac- tions. Nitriles are generally incompatible with other oxi- dizing agents such as peroxides and epoxides. The combination of bases and nitriles can produce hydrogen cyanide. Nitriles are hydrolyzed in both aqueous acid and base to give carboxylic acids (or salts of carboxylic acids). These reactions generate heat. Peroxides convert nitriles to amides. Nitriles can react vigorously with reducing agents. Acetonitrile and propionitrile are soluble in water, but nitriles higher than propionitrile have low aqueous solubility. They are also insoluble in aqueous acids .

• Waste disposal

  Add excess alkaline calcium hypochlorite with agitation. Flush to sewer after 24 hours. Cyanamide can also be destroyed in an incinerator equipped with afterburner and scrubber.

Cyanamide Upstream-Materialien And Downstream Produkte

Cyanamid Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global(411)Suppliers

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