Cyanamid Produkt Beschreibung

Cyanamide Struktur
420-04-2
  • CAS-Nr.420-04-2
  • Bezeichnung:Cyanamid
  • Englisch Name:Cyanamide
  • Synonyma:Cyanamid;Carbamonitril;Hydrogencyanamid;Carbodiimid
    tsaks;H2NCN;alzogur;CYANAMID;CYANAMIDE;cianamida;Cyanoamine;usafek-1995;USAF ek-1995;N-Cyanoamine
  • CBNumber:CB9256093
  • Summenformel:CH2N2
  • Molgewicht:42.04
  • MOL-Datei:420-04-2.mol
Cyanamid physikalisch-chemischer Eigenschaften
  • Schmelzpunkt: :45-46 °C(lit.)
  • Siedepunkt: :83 °C0.5 mm Hg(lit.)
  • Dichte :1,282 g/cm3
  • Brechungsindex :1.405
  • Flammpunkt: :>230 °F
  • storage temp.  :2-8°C
  • Löslichkeit :ethanol: soluble10%, clear to hazy, colorless to faintly yellow
  • pka :1.1(at 29℃)
  • Wichte :1.282
  • Wasserlöslichkeit :775 g/L
  • Sensitive  :Hygroscopic
  • Merck  :14,2684
  • BRN  :1732569
  • Stabilität: :Unstable - heat sensitive. Incompatible with strong oxidizing agents, strong reducing agents, bases, acids, iron and its salts, steel, brass, lead, moisture. Reacts with acids to produce very toxic gas.
  • InChIKey :XZMCDFZZKTWFGF-UHFFFAOYSA-N
  • CAS Datenbank :420-04-2(CAS DataBase Reference)
  • NIST chemische Informationen :Cyanamide(420-04-2)
  • EPA chemische Informationen :Cyanamide(420-04-2)
Sicherheit
  • Kennzeichnung gefährlicher :T
  • R-Sätze: :21-25-36/38-43
  • S-Sätze: :3-22-36/37-45-26
  • RIDADR  :UN 2811 6.1/PG 3
  • WGK Germany  :2
  • RTECS-Nr. :GS5950000
  • TSCA  :Yes
  • HazardClass  :8
  • PackingGroup  :III
  • HS Code  :29269090
  • Giftige Stoffe Daten :420-04-2(Hazardous Substances Data)
  • Toxizität :LD50 i.p. in male mice: 200-300 mg/kg (Doull)

Cyanamide Chemische Eigenschaften,Einsatz,Produktion Methoden

  • ERSCHEINUNGSBILD FARBLOSE, HYGROSKOPISCHE, ZERFLIESSLICHE KRISTALLE
  • ARBEITSPLATZGRENZWERTE TLV: 2 mg/m?(als TWA); (ACGIH 2007).
    MAK: 1 mg/m?(Einatembare Fraktion); Spitzenbegrenzung: überschreitungsfaktor II(2); Hautresorption; Sensibilisierung der Haut (Sh); Schwangerschaft: Gruppe C; (DFG 2007).
    EG Arbeitsplatz-Richtgrenzwerte: 0.58 ppm; 1 mg/m?(als TWA) Hautresorption (EU 2006).
  • AUFNAHMEWEGE Aufnahme in den Körper durch Inhalation des Aerosols, über die Haut und durch Verschlucken.
  • INHALATIONSGEFAHREN Eine gesundheitsschädliche Partikelkonzentration in der Luft kann schnell erreicht werden beim Dispergieren, vor allem als Pulver.
  • WIRKUNGEN BEI KURZZEITEXPOSITION WIRKUNGEN BEI KURZZEITEXPOSITION:
    Die Substanz reizt stark die Augen und die Haut und reizt die Atemwege. (siehe ANMERKUNGEN).
  • WIRKUNGEN NACH WIEDERHOLTER ODER LANGZEITEXPOSITION Wiederholter oder andauernder Kontakt kann zu Hautsensibilisierung führen. Tierversuche zeigen, dass die Substanz möglicherweise fruchtbarkeitsschädigend oder entwicklungsschädigend wirken kann.
  • LECKAGE Persönliche Schutzausrüstung: Vollschutzanzug mit umgebungsluftunabhängigem Atemschutzgerät. Verschüttetes Material aufsaugen. Reste sorgfältig sammeln. An sicheren Ort bringen. NICHT in die Umwelt gelangen lassen.
  • R-Sätze Betriebsanweisung: R21:Gesundheitsschädlich bei Berührung mit der Haut.
    R25:Giftig beim Verschlucken.
    R36/38:Reizt die Augen und die Haut.
    R43:Sensibilisierung durch Hautkontakt möglich.
  • S-Sätze Betriebsanweisung: S3:Kühl aufbewahren.
    S22:Staub nicht einatmen.
    S36/37:Bei der Arbeit geeignete Schutzhandschuhe und Schutzkleidung tragen.
    S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
  • Chemische Eigenschaften white crystalline solid
  • Chemische Eigenschaften Cyanamide is a combustible crystalline solid, but it is usually found as a 25% liquid solution.
  • Definition cyanamide: 1. An inorganic saltcontaining the ion CN22-. See calciumcyanamide. 2. A colourless crystallinesolid, H2NCN, made by the actionof carbon dioxide on hotsodamide. It is a weakly acidic compound(the parent acid of cyanamidesalts) that is soluble in water andethanol. It is hydrolysed to urea inacidic solutions.
  • Allgemeine Beschreibung Colorless deliquescent crystals. Mp: 45°C; bp: 260°C. Density: 1.282 g cm-3. Quite soluble in water (77 g / 100 g solution at 15°C). Soluble in butanol, methyl ethyl ketone, ethyl acetate, alcohols, phenols, amines, ethers. Note: The term "Cyanamide" is also used to refer to the important compound calcium Cyanamide, which is a different chemical.
  • Reaktivität anzeigen Cyanamide is the amide of cyanic acid. Non-flammable but combustible (flash point: 140°C). Decomposes on warming above 49°C. Emits toxic fumes of CN- and NOx when heated to decomposition or on contact with acids or acid fumes (Hazardous Chemicals Desk Reference, p. 353 (1987)). Contact with moisture, acids or bases may cause a violent reaction at temperatures above about 40°C. Dry solid may polymerize at temperatures above 122°C. Rapid or explosive polymerization may occur during the evaporation of aqueous solutions. Reacts explosively with strong oxidizing agents and strong reducing agents. Attacks various metals (International Chemical Safety Card).
  • Hazard Strong irritant to skin and mucous membranes; avoid inhalation or ingestion.
  • Landwirtschaftliche Anwendung Cyanamide, the trade name for calcium cyanamide, contains calcium hydroxide and carbon in small quantities as impurities. It is used as a fertilizer, the powdered form of which contains about 22% nitrogen.
  • Landwirtschaftliche Anwendung Herbicide, Plant growth regulator: A U.S. EPA restricted Use Pesticide (RUP). Not currently approved for use in EU countries (re-submitted). Used primarily as a plant growth regulator. Cyanamide may be melted to give a dimer, dicyandiamide or cyanoguanidine. At higher temperatures it gives the trimer, melamine, a raw material for melamine-formaldehyde resins.
  • Handelsname DORMEX®; SKW 83010®
  • Kontakt-Allergie Cyanamide and its salts are used in various occasions such as in chemistry, in antirust solutions, or in a drug (Come?) for treating alcoholism (inhibition of alcohol deshydrogenase).
  • Sicherheitsprofil Poison by ingestion, inhalation, and intraperitoneal routes. Moderately toxic by skin contact. Experimental reproductive effects. Combustible when exposed to heat or flame. To fight fire, use CO2, dry chemical. Thermally unstable. Contact with moisture (water), acids, or alkalies may cause a violent reaction above 40'. Concentrated aqueous solutions may undergo explosive polymerization. Mixture with 1,2 phenylenediamine salts may cause explosive polymerization. When heated to decomposition or on contact with acid or acid fumes, it emits toxic fumes of CNand NOx. See also CYANIDE and AMIDES.
  • mögliche Exposition Cyanamide may be melted to give a dimer, dicyandiamide or cyanoguanidine. At higher tem- peratures it gives the trimer, melamine; a raw material for melamine-form aldehyde resins.
  • Versand/Shipping UN3276 Nitriles, liquid, toxic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required, Potential Inhalation Hazard (Special Provision 5).
  • läuterung methode Purify it by placing ca 15g in a Soxhlet thimble and extracting exhaustively (2-3hours) with two successive portions of Et2O (400mL, saturated with H2O by shaking before use) containing two drops of 1N acetic acid. Two successive portions of Et2O are used so that the NH2CN is not heated for too long. Each extract is dried over Na2SO4 (30g), then combined and evaporated under reduced pressure. The NH2CN may be stored unchanged at 0o in Et2O solution in the presence of a trace of AcOH. Extracts from several runs may be combined and evaporated together. The residue from evaporation of an Et2O solution is a colourless viscous oil which sets to a solid and can be recrystallised from a mixture of 2 parts of *C6H6 and 1 part of Et2O. Concentrating an aqueous solution of NH2CN at high temperatures causes EXPLOSIVE polymerisation. [Kurzer & Lawson Org Synth Coll Vol IV 645 1963, Pinck & Salissbury Inorg Synth III 39 1950, Soloway & Lipschitz J Org Chem 23 613 1958.] Hygroscopic.[Beilstein 3 IV 145.]
  • Inkompatibilitäten Cyanamide may polymerize at tempera- tures above 122℃ , or on evaporation of aqueous solutions. Reacts with acids, strong oxidants, strong reducing agents such as hydrides and water, causing explosion and toxic hazard. Attacks various metals. Decomposes when heated above 49℃ C, on contact with acids, bases, 1,2-phenylene diamine salts; and moisture; producing toxic fumes includ- ing nitrogen oxides and cyanides. Nitriles may polymerize in the presence of metals and some metal compounds. They are incompatible with acids; mixing nitriles with strong oxidizing acids can lead to extremely violent reac- tions. Nitriles are generally incompatible with other oxi- dizing agents such as peroxides and epoxides. The combination of bases and nitriles can produce hydrogen cyanide. Nitriles are hydrolyzed in both aqueous acid and base to give carboxylic acids (or salts of carboxylic acids). These reactions generate heat. Peroxides convert nitriles to amides. Nitriles can react vigorously with reducing agents. Acetonitrile and propionitrile are soluble in water, but nitriles higher than propionitrile have low aqueous solubility. They are also insoluble in aqueous acids .
  • Waste disposal Add excess alkaline calcium hypochlorite with agitation. Flush to sewer after 24 hours. Cyanamide can also be destroyed in an incinerator equipped with afterburner and scrubber.
Cyanamide Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
Cyanamid Anbieter Lieferant Produzent Hersteller Vertrieb Händler.
Global(211)Suppliers
  • Firmenname:Alfa Aesar
  • Telefon:400-610-6006; 021-67582000
  • Fax:021-67582001/03/05
  • E-Mail:saleschina@alfa-asia.com
  • Land:China
  • Produktkatalog:30163
  • Edge Rate:84
  • Firmenname:Credit-Chem Co., Ltd.
  • Telefon:400-821-5857 021-64326257
  • Fax:021-64393586 QQ;2798200800
  • E-Mail:credit-chem@foxmail.com
  • Land:China
  • Produktkatalog:5230
  • Edge Rate:58
  • Firmenname:Hangzhou FandaChem Co.,Ltd.
  • Telefon:Mobile:0086 15858145714 (Whatsapp, Telegram)
  • Fax:0571-56059825 (QQ: 2949540382)
  • E-Mail:fandachem@gmail.com ; info@fandachem.com
  • Land:China
  • Produktkatalog:140
  • Edge Rate:55
  • Firmenname:AgileBioChem Co., Ltd.
  • Telefon:+86 18055517827
  • Fax:
  • E-Mail:sales@agilebiochem.com
  • Land:China
  • Produktkatalog:885
  • Edge Rate:50
  • Firmenname:J & K SCIENTIFIC LTD.
  • Telefon:400-666-7788 +86-10-82848833
  • Fax:86-10-82849933
  • E-Mail:jkinfo@jkchemical.com;market6@jkchemical.com
  • Land:China
  • Produktkatalog:96815
  • Edge Rate:76
  • Firmenname:Meryer (Shanghai) Chemical Technology Co., Ltd.
  • Telefon:+86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-62670440(Beijing)
  • Fax:+86-(0)21-61259102(Shanghai) +86-(0)755-86170066(ShenZhen) +86-(0)10-88580358(Beijing)
  • E-Mail:sh@meryer.com
  • Land:China
  • Produktkatalog:40269
  • Edge Rate:62
  • Firmenname:Beijing dtftchem Technology Co., Ltd.
  • Telefon:13651141086; 86(10)60275028、60275820
  • Fax:86 (10) 60270825
  • E-Mail:dtftchem@sina.com
  • Land:China
  • Produktkatalog:1403
  • Edge Rate:62
  • Firmenname:BeiJing Hwrk Chemicals Limted
  • Telefon:4006990298;010-57411839;0757-86311057;021-51691807
  • Fax:010-87653215;0757-86311057;021-55236763
  • E-Mail:sales@hwrkchemical.com
  • Land:China
  • Produktkatalog:14684
  • Edge Rate:55
  • Firmenname:Energy Chemical
  • Telefon:021-58432009 / 400-005-6266
  • Fax:021-58436166-800
  • E-Mail:info@energy-chemical.com
  • Land:China
  • Produktkatalog:44025
  • Edge Rate:61
420-04-2, Cyanamide Verwandte Suche:
  • hydrogencyanamid
  • N-Cyanoamine
  • tsaks
  • USAF ek-1995
  • usafek-1995
  • CARBODIIMIDE
  • CYANAMIDE F1000
  • CYANAMIDE L500
  • CYANAMID
  • CYANAMIDE
  • HYDROGEN CYANAMIDE
  • 1-(2-methoxyphenyl)-N-methylpropan-2-amine hydrochloride
  • alzogur
  • Amidocyanogen
  • carbamonitrile
  • carbodiamide
  • Cyanoamine
  • Cyanogen nitride
  • Cyanogenamide
  • cyanogennitride
  • Cyanamide solution
  • Aminonitrile
  • Carbamic acid nitrile
  • cyanamide,urea anhydride
  • CYANAMIDE, 50 WT. % SOLUTION IN WATER
  • H2NCN
  • Cyanamide, 98+%, stab.
  • Cyanamide, 50% w/w aq. soln., stab.
  • Cyanamide,50% aq solution
  • Cyanamide ,95%
  • Cyanamide,Carbimide, Hydrogen cyanamide
  • Cyanamide, 98+%
  • CYANAMIDE, CRYST., M.P. 43 degrees
  • CYANAMIDE, 50% AQUEOUS SOLN
  • CyanaMide, 50wt.% in H2O
  • CyanaMide solution,50% in H2O
  • Carbamonitrile, Cyanoamine
  • Cyanamide, 50% aqueous solution
  • CyanaMide solution 50 wt. % in H2O
  • CyanaMide aq
  • Hydrogen Cyanamide 50% sl
  • Cyanamide solution,1000ppm
  • Cyanamide, 98%, stabilized
  • CYANAMIDE, STAB.
  • Cyanamide, stabilized, 95%
  • CYANAMIDE , STAB. WITH 0.5% PHOSPHORIC ACID
  • CYANAMIDE IN 50% WATER SOLUTION
  • Cyanamide, 50% w/w aq. soln.
  • Cyanamide, 98+%, stab. with ca 0.5% phosphoric acid
  • Carbaminonitrile
  • cyanamide carbanonitril
  • Carbodiimide, Hydrogen cyanamide
  • Cyanamide, 95%, stabilized
  • Amino cyanide
  • Carbamic nitrile
  • Cyanamide,50 wt.% in water, stabilized with phosphoric acid
  • cianamida
  • cianamida hidrogenada