2,4,6-Triallyloxy-1,3,5-triazi Struktur

2,4,6-Triallyloxy-1,3,5-triazin

Bezeichnung:2,4,6-Triallyloxy-1,3,5-triazin

CAS-Nr101-37-1

Englisch Name:2,4,6-Triallyloxy-1,3,5-triazi

CBNumberCB7666588

SummenformelC12H15N3O3

Molgewicht249.27

MOL-Datei101-37-1.mol

Synonyma

2,4,6-Triallyloxy-1,3,5-triazin

2,4,6-Triallyloxy-1,3,5-triazin physikalisch-chemischer Eigenschaften

Schmelzpunkt	26-28 °C
Siedepunkt	156 °C
Dichte	1.11 g/mL at 30 °C
Dampfdruck	1.3 hPa (100 °C)
Brechungsindex	1.5290 (estimate)
Flammpunkt	>230 °F
storage temp.	Store at <= 20°C.
Löslichkeit	0.3g/l
pka	2.04±0.10(Predicted)
Aggregatzustand	Oil
Farbe	Colourless
Wichte	1.11
Wasserlöslichkeit	6g/L(20 ºC)
BRN	235560
Stabilität	Stable, but moisture-sensitive. Incompatible with acids, peroxides, strong oxidizing agents, copper, iron and its salts.
LogP	3.51 at 20℃
CAS Datenbank	101-37-1(CAS DataBase Reference)
NIST chemische Informationen	2,4,6-Triallyloxy-1,3,5-triazine(101-37-1)
EPA chemische Informationen	1,3,5-Triazine, 2,4,6-tris(2-propenyloxy)- (101-37-1)

Sicherheit

Kennzeichnung gefährlicher	Xn,N
R-Sätze:	22-51/53
S-Sätze:	36-61
RIDADR	UN 3077 9/PG 3
WGK Germany	2
RTECS-Nr.	XZ2080000
F	21
TSCA	Yes
HS Code	2933 69 80
HazardClass	6.1(b)
PackingGroup	III
Toxizität	LD50 orally in Rabbit: 753 mg/kg LD50 dermal Rabbit > 2000 mg/kg

Gefahreninformationscode (GHS)

2,4,6-Triallyloxy-1,3,5-triazi Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R22:Gesundheitsschädlich beim Verschlucken.
R51/53:Giftig für Wasserorganismen, kann in Gewässern längerfristig schädliche Wirkungen haben.
S-Sätze Betriebsanweisung:
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
Chemische Eigenschaften
Colorless liquid or solid. Miscible with acetone, benzene, chloroform, dioxane, ethyl acetate, ethanol, and xylene. Combustible.
Verwenden
Polymers as monomer and modifier, organic intermediate. Triallyl Cyanurate is used preferentially as a cross-linking agent in copolymers. On heating it may polymerize violently and then isomerize to the more stable triallyl isocyanurate [1025-15-6] with the allyl groups attached to the nitrogen atoms.
At 30 ℃ viscous solutions of prepolymers form slowly. Triallyl cyanurate is used for the production of heat- and solvent-resistant coatings and moldings, reinforced plastics, and adhesives. Addition of 5 – 10% triallyl cyanurate to polyester – styrene or methyl methacrylate yields cast sheets of improved mechanical and thermal stability. Short-term heating of triallyl cyanurate with polymers in the presence of peroxides at 180 ℃ gives cross-linking; valuable copolymers are thus obtained from poly(vinyl chloride) elastomers and fluoroelastomers. Ethylene polymers and copolymers also may be crosslinked under similar reaction conditions. High-impact plastics have been obtained by grafting butyl acrylate-triallyl cyanurate copolymer with a styrene – acrylonitrile mixture. Other examples of peroxide-initiated curing with triallyl cyanurate (2 – 5 %) at 150 – 160 ℃ are polyurethanes, nylons, cellulose, polyoxyethylene, vinyl-substituted polysiloxanes, and acrylate copolymers. Crosslinking of polycarbonate with triallyl cyanurate by UV irradiation in the presence of polythiols gives scratch-resistant coatings.
Definition
ChEBI: 2,4,6-triallyloxy-1,3,5-triazine is a member of 1,3,5-triazines and an aromatic ether.
Hazard
Toxic by ingestion and inhalation.
Flammability and Explosibility
Non flammable
Sicherheitsprofil
Poison by intravenous route. Flammable when exposed to heat, flame, or oxidizers. To fight fire, use spray, foam, dry chemical. When heated to decomposition or on contact with acid or acid fumes it emits hghly toxic fumes of CNand NOx. See also ESTERS and ALLYL, COMPOUNDS.

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