trans-1,3-Dichloropropene

Bezeichnung:trans-1,3-Dichloropropene

CAS-Nr10061-02-6

Englisch Name:trans-1,3-Dichloropropene

CBNumberCB6324649

SummenformelC3H4Cl2

Molgewicht110.97

MOL-Datei10061-02-6.mol

trans-1,3-Dichloropropene physikalisch-chemischer Eigenschaften

Siedepunkt	97-112 °C(lit.)
Dichte	1.198 g/mL at 25 °C(lit.)
Dampfdruck	79.1 at 50 °C, 523.5 at 100 °C (Wilding et al., 2002)
Brechungsindex	n20/D 1.472(lit.)
Flammpunkt	78 °F
storage temp.	0-6°C
Löslichkeit	Miscible with acetone, benzene, carbon tetrachloride, heptane, methanol (Worthing and Hance, 1991), methylene chloride, chloroform, trichloroethylene, and 1,1,2,2-tetrachloroethane.
Farbe	Colorless to Light yellow to Light orange
Wichte	1.217
Wasserlöslichkeit	2.8g/L(20 ºC)
Merck	14,3075
Henry's Law Constant	1.3 x 10^-3 atm?m³/mol (Pankow and Rosen, 1988) 0.793 x 10^-3 atm?m³/mol at 20 °C, 1.87 at 40 °C (static headspace-GC, Kim et al., 2003)
Expositionsgrenzwerte	ACGIH TLV: TWA 1 ppm for cis and trans isomers (adopted).
Stabilität	Stable. Flammable. Incompatible with strong oxidizing agents, aluminium, aluminium alloys, some metal salts and halogens. May be light sensitive.
CAS Datenbank	10061-02-6(CAS DataBase Reference)
NIST chemische Informationen	1-Propene, 1,3-dichloro-, (E)-(10061-02-6)
EPA chemische Informationen	trans-1,3-Dichloropropene (10061-02-6)

Sicherheit

Kennzeichnung gefährlicher	T,N,Xn,F
R-Sätze:	10-20/21-25-36/37/38-43-50/53-40-22-39/23/24/25-23/24/25-11-52/53-65-24/25-20
S-Sätze:	36/37-45-60-61-16-7
RIDADR	UN 1992 3/PG 3
WGK Germany	3
RTECS-Nr.	UC8310000
HazardClass	3.2
PackingGroup	III
HS Code	29032990
Giftige Stoffe Daten	10061-02-6(Hazardous Substances Data)
Toxizität	LC50 (96-hour) for bluegill sunfish 7.1 mg/L and rainbow trout 7.1 mg/L (Worthing and Hance, 1991); acute oral LD50 of the isomeric mixture for male and female rats 713 and 470 mg/kg, respectively (Verschueren, 1983).

Gefahreninformationscode (GHS)

trans-1,3-Dichloropropene Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R10:Entzündlich.
R20/21:Gesundheitsschädlich beim Einatmen und bei Berührung mit der Haut.
R25:Giftig beim Verschlucken.
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
R43:Sensibilisierung durch Hautkontakt möglich.
R50/53:Sehr giftig für Wasserorganismen, kann in Gewässern längerfristig schädliche Wirkungen haben.
R40:Verdacht auf krebserzeugende Wirkung.
R22:Gesundheitsschädlich beim Verschlucken.
R39/23/24/25:Giftig: ernste Gefahr irreversiblen Schadens durch Einatmen, Berührung mit der Haut und durch Verschlucken.
R23/24/25:Giftig beim Einatmen, Verschlucken und Berührung mit der Haut.
R11:Leichtentzündlich.
S-Sätze Betriebsanweisung:
S36/37:Bei der Arbeit geeignete Schutzhandschuhe und Schutzkleidung tragen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
S60:Dieses Produkt und sein Behälter sind als gefährlicher Abfall zu entsorgen.
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
S16:Von Zündquellen fernhalten - Nicht rauchen.
S7:Behälter dicht geschlossen halten.
Beschreibung
Trans-1,3-dichloropropene appears as a clear colorless liquid with chloroform odor. Flash point 95 °F. Density 1.225 g/cm3 and insoluble in water. Hence sinks in water. A strong irritant. Used as a soil fumigant. It is used as an intermediate in the manufacture of 3,3-dichloro-1-propene and other pesticides.
Chemische Eigenschaften
1,3-Dichloropropene is a colorless to strawcolored liquid. Sharp, sweet, irritating, chloroform-like odor.
Chemische Eigenschaften
colourless liquid
Physikalische Eigenschaften
Colorless to pale yellow liquid with a chloroform-like odor. Evaporates quickly when spilled.
Verwenden
The isomer mixture is used as a soil fumigant and a nematocide.
Definition
ChEBI: (E)-1,3-dichloropropene is a 1,3-dichloropropene with a (E)-configuration. It has a role as a fumigant. It is a 1,3-dichloropropene and a chloroalkene. It derives from a hydride of a propene.
Allgemeine Beschreibung
A clear colorless liquid with chloroform odor . Flash point 95°. Density 1.225 g / cm3 and insoluble in water. Hence sinks in water. A strong irritant. Used as a soil fumigant.
Air & Water Reaktionen
Highly flammable. Insoluble in water.
Reaktivität anzeigen
trans-1,3-Dichloropropene reacts with aluminum, aluminum alloys, with other active metals and with some metal salts and halogens. Can react vigorously with oxidizing materials. .
Brandgefahr
Flash point data for trans-1,3-Dichloropropene are not available, however literature indicates that trans-1,3-Dichloropropene is flammable.
mögliche Exposition
Used as a soil fumigant prior to planting crops, such as cotton, sugar beet, potatoes; used in combinations with dichloropropanes as a soil fumigant. Workers engaged in manufacture, formulation and application of this soil fumigant and nematocide.
Environmental Fate
Biological. The isomeric mixture showed significant degradation with gradual adaptation in a static-culture flask-screening test (settled domestic wastewater inoculum) conducted at 25°C. At concentrations of 5 and 10 mg/L, percent losses after 4 weeks of incubation were 85 and 84, respectively. Ten days into the incubation study, 7–19% was lost due to volatilization (Tabak et al., 1981).
Chemical/Physical. Hydrolysis in distilled water at 25°C produced trans-3-chloro-2- propen-1-ol and hydrochloric acid. The reported half-life for this reaction is only 2 days (Kollig, 1993; Milano et al., 1988). trans-1,3-Dichloropropylene was reported to hydrolyze to 3-chloro-2-propen-1-ol and can be biologically oxidized to 3-chloropropenoic acid which is further oxidized to formylacetic acid. Decarboxylation of this compound yields carbon dioxide (Connors et al., 1990). Chloroacetaldehyde, formyl chloride and chloroacetic acid were formed from the ozonation of dichloropropylene at approximately 23°C and 730 mmHg. Chloroacetaldehyde and formyl chloride also formed from the reaction of dichloropropylene and hydroxyl radicals (Tuazon et al., 1984).
The evaporation half-life of trans-1,3-dichloropropylene (1 mg/L) from water at 25°C using a shallow-pitch propeller stirrer at 200 rpm at an average depth of 6.5 cm is 24.6 minutes (Dilling, 1977).
Emits chlorinated acids when incinerated. Incomplete combustion may release toxic phosgene (Sittig, 1985).
Solubility in water
Miscible with acetone, benzene, carbon tetrachloride, heptane, methanol (Worthing and Hance, 1991), methylene chloride, chloroform, trichloroethylene, and 1,1,2,2-tetrachloroethane.
Versand/Shipping
UN2047 Dichloropropene, Hazard Class: 3; Labels: 3-Flammable liquid.
Inkompatibilitäten
Vapor may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides. May accumulate static electrical charges, and may cause ignition of its vapors. Incompatible with strong acids; oxidizers, aluminum or magnesium compounds; aliphatic amines; alkanolamines, alkaline materials; halogens, or corrosives. Note: Epichlorohydrin may be added as a stabilizer.
Waste disposal
Incineration, preferably after mixing with another combustible fuel. Care must be exercised to assure complete combustion to prevent the formation of phosgene. An acid scrubber is necessary to remove the halo acids produced. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≧100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal.

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