FUBERIDAZOLE Struktur

Fuberidazol (ISO)

Bezeichnung:Fuberidazol (ISO)

CAS-Nr3878-19-1

Englisch Name:FUBERIDAZOLE

CBNumberCB4345158

SummenformelC11H8N2O

Molgewicht184.19

MOL-Datei3878-19-1.mol

Synonyma

Fuberidazol

Fuberidazol (ISO)

Fuberidazol (ISO) physikalisch-chemischer Eigenschaften

Schmelzpunkt	310-312℃
Siedepunkt	318.14°C (rough estimate)
Dichte	1.1820 (rough estimate)
Dampfdruck	<1 x 10^-3Pa (20 °C)
Brechungsindex	1.5300 (estimate)
storage temp.	0-6°C
Löslichkeit	DMSO (Slightly), Methanol (Slightly)
pka	4.6 (base)
Wasserlöslichkeit	200 mg l^-1 (pH 4), 71 mg l^-1 (pH 7) at 20 °C
Farbe	Off-White to Pale Beige
BRN	153833
LogP	2.670
CAS Datenbank	3878-19-1(CAS DataBase Reference)
EPA chemische Informationen	Fuberidazole (3878-19-1)

Sicherheit

Kennzeichnung gefährlicher	Xn,N,T
R-Sätze:	22-50/53-23-21-48/22-43-40-21/22
S-Sätze:	22-60-61-45-36/37
RIDADR	2588
WGK Germany	3
RTECS-Nr.	DD9010000
HazardClass	6.1(b)
PackingGroup	III
HS Code	29339900

Gefahreninformationscode (GHS)

FUBERIDAZOLE Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R22:Gesundheitsschädlich beim Verschlucken.
R50/53:Sehr giftig für Wasserorganismen, kann in Gewässern längerfristig schädliche Wirkungen haben.
S-Sätze Betriebsanweisung:
S22:Staub nicht einatmen.
S60:Dieses Produkt und sein Behälter sind als gefährlicher Abfall zu entsorgen.
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
Beschreibung
Fuberidazole is a crystalline powder.Molecular weight=184.21; Melting point=285℃(decomposition). Hazard Identification (based on NFPA-704 M Rating System): Health 2, Flammability 1,Reactivity 0. Very slightly soluble in water.
Chemische Eigenschaften
Fuberidazole is a crystalline powder.
Verwenden
Fuberidazole is a systemic fungicide used in cereal seed dressing to control a variety of soil and seed borne diseases caused by Fusarium spp. It is also used as an anthelmintic and an inhibitor of enteroviruses.
Verwenden
Fuberidazole is a benzimidazole based fungicide used as a fungicidal seed treatment of barley.
Definition
ChEBI: A ring assembly consisting of benzimidazole substituted at position 2 by a 2-furyl group. A fungicide used as a seed treatment to control Fusarium spp. in cereals.
Allgemeine Beschreibung
Crystalline powder. Used in cereal seed dressing and fungicidal non-mercurial seed dressing with special action against fusarium. Not registered as a pesticide in the U.S.
Reaktivität anzeigen
FUBERIDAZOLE is a benzimidazole and behaves as an amine. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides
Health Hazard
FUBERIDAZOLE is classified as moderately toxic. Its probable oral lethal dose in humans is 0.5-5 g/kg or between 1 ounce and 1 pint for a150 lb. person.
Brandgefahr
When heated to decomposition, FUBERIDAZOLE emits toxic fumes of nitrogen oxides.
Landwirtschaftliche Anwendung
Fungicide, Seed treatment: Uses include cereal seed dressing; and fungicidal non-mercurial seed dressing with special action against fusarium. Not registered as a pesticide for use in the U.S. Registered for use in EU countries.
Handelsname
BAYCOR®; BAYER 33172®; BAYTAN®; BAYTAN® FS; ICI BAYTAN®; NEOVORONIT®; SIBUTOL®; SIBUTROL®; VORONIT®; VORONITE®; W VII/117®
mögliche Exposition
Fuberidazole, a benzimidazole, uses include cereal seed dressing; and fungicidal, nonmercurial seed dressing with special action against fusarium. Not reg istered as a pesticide in the U.S.A.
Erste Hilfe
: If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit.
Stoffwechselwegen
Limited information is available describing the degradation and metabolic fate of fuberidazole. Information presented below was abstracted mainly from the Pesticide Manual (PM). The major degradation pathways observed include rearrangement of the fury1 moiety under UV light irradiation, hydrolysis and hydroxylation reactions in mammalian systems.
Lager
Color Code—Blue: Health Hazard/Poison: Storein a secure poison location. Prior to working with thischemical you should be trained on its proper handling andstorage. Store in tightly closed containers in a cool, wellventilated area.
Versand/Shipping
UN2588 Pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required. UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.
Degradation
Fuberidazole (1) is stable to hydrolysis in pure water and sensitive to light with a half-life (DT₅₀) of ca. 15 min (PM).
Photolysis (at 313 nm using a high pressure Hg lamp) of fuberidazole was much faster for the protonated state as compared to the neutral state (Melo et al., 1994), probably via a cyclopropanyl ketone intermediate (see Scheme 1). Reaction of this intermediate with either water or methanol yielded benzimidazole-2-carboxylic acid (2) or its methyl ester (3), methyl 4-oxo-4-(benzimidazol-2-yl)crotonate( 4, both the cis and trans isomers) and 1-methoxybenzimidazole (5) as major degradates (Melo et al., 1992). Benzimidazole (6) and 2,2'-bibenzimidazole (7) were also detected.
Inkompatibilitäten
Incompatible with acid halides, anhydrides, epoxides, halogenated organics, isocyanates, peroxides, phenols (acidic).
Waste disposal
In accordance with 40CFR 165 recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by follow ing package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

FUBERIDAZOLE Upstream-Materialien And Downstream Produkte

Fuberidazol (ISO) Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

3878-19-1, FUBERIDAZOLE Verwandte Suche:

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