Carboxyferrocen

Bezeichnung:Carboxyferrocen

CAS-Nr1271-42-7

Englisch Name:Ferrocenecarboxylic acid

CBNumberCB3215027

SummenformelC11H10FeO210*

Molgewicht230.04

MOL-Datei1271-42-7.mol

Synonyma

Carboxyferrocen

Carboxyferrocen physikalisch-chemischer Eigenschaften

Schmelzpunkt	210 °C (dec.)(lit.)
storage temp.	Inert atmosphere,Room Temperature
Löslichkeit	Chloroform (Sparingly), DMSO (Slightly), Methanol (Slightly)
Aggregatzustand	crystal
Farbe	yellow
Wasserlöslichkeit	Insoluble in water.
Expositionsgrenzwerte	ACGIH: TWA 1 mg/m3 NIOSH: TWA 1 mg/m3
Stabilität	Stable. Incompatible with strong oxidizing agents.
InChI	InChI=1S/C6H5O2.C5H5.Fe/c7-6(8)5-3-1-2-4-5;1-2-4-5-3-1;/h1-4H,(H,7,8);1-5H;
InChIKey	VUJLGCHOGQEAED-UHFFFAOYSA-N
SMILES	[C]1(C(=O)O)[CH][CH][CH][CH]1.[CH]1[CH][CH][CH][CH]1.[Fe] \|^1:0,4,5,6,7,8,9,10,11,12\|
CAS Datenbank	1271-42-7(CAS DataBase Reference)
NIST chemische Informationen	Ferrocene carboxylic acid(1271-42-7)

Sicherheit

Kennzeichnung gefährlicher	Xn
R-Sätze:	36/37/38-22
S-Sätze:	37/39-26
WGK Germany	3
HS Code	29319090

Gefahreninformationscode (GHS)

Ferrocenecarboxylic acid Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
R22:Gesundheitsschädlich beim Verschlucken.
S-Sätze Betriebsanweisung:
S37/39:Bei der Arbeit geeignete Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
Beschreibung
Ferrocenecarboxylic acid is a metal-organic compound characterized by connecting two ferrocene molecules through a carboxy ligand. Notably, ferrocene is a stable yet highly reactive metal-organic compound that has been extensively researched due to its potential applications in catalysis, materials science, and medicine. It serves as a catalyst in catalysis, facilitating the synthesis of diverse compounds through polymerization, oxidation, and reduction reactions. In materials science, it acts as a fundamental molecular building block for synthesizing polymers and nanomaterials. Although the precise mechanism of action of Ferrocenecarboxylic acid remains fully elucidated, it is believed that the carboxy ligand binds to the ferrocene molecules, forming a stable complex. This complex, in turn, engages with other molecules, including proteins, to facilitate various reactions[1-2].
Chemische Eigenschaften
dark brown powder
Verwenden
Ferrocenecarboxylic acid is used to esterify complex mixtures of phenols and alcohols for analysis by GCMS. It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals and Dyestuff.
reaction suitability
core: iron
reagent type: catalyst
läuterung methode
It crystallises as yellow crystals from pet ether (m 225-230odec), CHCl3 (m 208.5odec), toluene/pet ether (m 195-205odec), or aqueous ethanol. [Matsue et al. J Am Chem Soc 107 3411 1985.] The acid chloride m 49o crystallises from pentane, and has max at 458nm [Lau & Hart J Org Chem 24 280 1959]. The methyl ester crystallises from aqueous MeOH with m 70-71o. The anhydride has m 143-145o when recrystallised from pet ether [Acton & Silverstein J Org Chem 24 1487 1959]. The amide has m 168-170o when crystallised from CHCl3/Et2O or m 167-169o when crystallised from *C6H6/MeOH. [Arimoto & Haven J Am Chem Soc 77 6295 1955, Benkeser et al. J Am Chem Soc 76 4025 1954.] [Beilstein 16 IV 1807.]
Einzelnachweise
[1] C. Pess?a, L. Kubota, Y. Gushikem. “Ferrocenecarboxylic acid adsorbed on Nb2O5 film grafted on a SiO2 surface: NADH oxidation study.” Electrochimica Acta 46 1 (2001): 2499–2505.
[2] H. Tsukube, S. Shinoda, H. Fukui. “Synergistic binding and chirality sensing of unprotected amino acids with ferrocenecarboxylic acid–crown ether conjugate.” Tetrahedron Letters 42 1 (2001): 7583–7585.

Ferrocenecarboxylic acid Upstream-Materialien And Downstream Produkte

Carboxyferrocen Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

1271-42-7, Ferrocenecarboxylic acid Verwandte Suche:

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