Indolo[3,2-b]carbazole

Bezeichnung:Indolo[3,2-b]carbazole

CAS-Nr6336-32-9

Englisch Name:Indolo[3,2-b]carbazole

CBNumberCB21216097

SummenformelC18H12N2

Molgewicht256.3

MOL-Datei6336-32-9.mol

Indolo[3,2-b]carbazole physikalisch-chemischer Eigenschaften

Schmelzpunkt	460°C(lit.)
Siedepunkt	569.8±23.0 °C(Predicted)
Dichte	1.404±0.06 g/cm3(Predicted)
storage temp.	Keep in dark place,Sealed in dry,Room Temperature
Aggregatzustand	powder to crystal
pka	16.70±0.30(Predicted)
Farbe	White to Yellow to Green
maximale Wellenlänge (λmax)	338nm(DMF)(lit.)
InChI	InChI=1S/C18H12N2/c1-3-7-15-11(5-1)13-9-18-14(10-17(13)19-15)12-6-2-4-8-16(12)20-18/h1-10,19-20H
InChIKey	YCPBCVTUBBBNJJ-UHFFFAOYSA-N
SMILES	N1C2=C(C=CC=C2)C2=C1C=C1C3=C(NC1=C2)C=CC=C3

Sicherheit

HS Code

2933.99.8290

Gefahreninformationscode (GHS)

Indolo[3,2-b]carbazole Chemische Eigenschaften,Einsatz,Produktion Methoden

Beschreibung
indolo[3,2-b]carbazole has a large planar and rigid conjugated structure with fused alternating three benzene and two pyrrole rings. It is a heterocyclic analogue of pentacene – one of the most used organic semiconductors – and is considered to be a nitrogen-containing electron-rich heteroacene with a ladder-type structure. It is a potent agonist of the aryl hydrocarbon receptor (AhR) and was found in Brassica family vegetables. Since its electron-donating nature, indolo[3,2-b]carbazole derivative is commonly used as hole transporting, charge injection, host, and electroluminescent materials for OLED and OFET devices with good thermal, chemical, and environmental stability[1].
Verwenden
Indolo[3,2-b]carbazole (ICZ) is a popular class of organic materials for various electronic applications. It has been used in a number of devices such as organic light-emitting diodes (OLEDs), organic field-effect transistors (OFETs), solar cells, etc. ICZ is an important unit to synthesize various oligomers and polymers with interesting electrical, optical, magnetic and other features[2].
benefits
The nitrogen heteroatoms open up the possibility of functionalization and sensing capabilities, as well as lowering the HOMO energy levels, which renders them air-stable. Additionally, Indolo[3,2-b]carbazole exhibit very strong Nsingle bondH?π interactions, which can enhance charge transport by improving intermolecular interactions and thus result in an improved molecular packing motive. Because of the high glass transition temperature, ICZ compounds possess great thermal and morphological stability under ambient conditions[1].
Einzelnachweise
[1] Streckaite S, et al. Fluorescence quenching of indolo[3,2-b]carbazole compounds by conformational motions of attached substituents. Dyes and Pigments, 2016; 133: 120-126.
[2] Bintinger J, et al. Synthesis, characterization and printing application of alkylated indolo[3,2-b]carbazoles. Synthetic Metals, 2017; 288: 9-17.

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