Diphenylphosphinsure

Bezeichnung:Diphenylphosphinsure

CAS-Nr1707-03-5

Englisch Name:Diphenylphosphinic acid

CBNumberCB1181911

SummenformelC12H11O2P

Molgewicht218.19

MOL-Datei1707-03-5.mol

Synonyma

Diphenylphosphinsure

Diphenylphosphinsure physikalisch-chemischer Eigenschaften

Schmelzpunkt	193-195 °C(lit.)
Siedepunkt	194 °C
Dichte	1.25±0.1 g/cm3(Predicted)
storage temp.	Sealed in dry,Room Temperature
Löslichkeit	0.1 M NaOH: soluble0.5g/10 mL, clear, colorless
pka	2.30±0.10(Predicted)
Aggregatzustand	Fine Crystalline Solid
Farbe	White
Wasserlöslichkeit	Soluble in water.
BRN	2804567
CAS Datenbank	1707-03-5(CAS DataBase Reference)
NIST chemische Informationen	Diphenyl phosphinic acid(1707-03-5)

Sicherheit

R-Sätze:	36/37/38
S-Sätze:	22-24/25
WGK Germany	3
RTECS-Nr.	SZ5315000
HS Code	29310095

Gefahreninformationscode (GHS)

Diphenylphosphinic acid Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-Sätze Betriebsanweisung:
S22:Staub nicht einatmen.
S24/25:Berührung mit den Augen und der Haut vermeiden.
Chemische Eigenschaften
white fine crystalline solid
Verwenden
Diphenylphosphinic acid is used as a reagent employed in the synthesis of bidentate ligands and peptide coupling agents.
Definition
ChEBI: Diphenylphosphinic acid is a member of phosphinic acids.
Synthesis Reference(s)
The Journal of Organic Chemistry, 22, p. 1671, 1957 DOI: 10.1021/jo01363a037
Allgemeine Beschreibung
Diphenylphosphinic acid (DPPA, hdpp) is an organophosphinic acid compound. It finds application as a reactive flame-retardant and promoter for palladium catalytic systems. Thermal degradation of DPPA has been studied by thermogravimetric analysis (TGA) method. DPPA reacts with cadmium nitrate in dimethylformamide solvent to afford the one-dimensional coordination polymer catena-poly[[bis(dimethylformamide-κO)cadmium(II)]-bis(μ-diphenylphosphinato-κ(2)O:O′)]. It has been repoted to promote the carbonylation of nitrobenzene and aniline to diphenylurea. Ortho-lithiated DPPA can form mono ortho-functionalized derivatives by electrophilic trapping and biphenyl-2,2′-diylbis(phenylphosphinic acid) by copper catalyzed coupling.
läuterung methode
Recrystallise it from 95% EtOH and dry it under vacuum at room temperature. [see Kosolapoff Organophosphorus Compounds J Wiley, NY, 1950, Kosolapoff and Maier Organic Phosphorus Compounds Wiley-Interscience, NY, 1972-1976, Beilstein 16 IV 1036.]

Diphenylphosphinic acid Upstream-Materialien And Downstream Produkte

Diphenylphosphinsure Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

1707-03-5, Diphenylphosphinic acid Verwandte Suche:

Send Inquriy