97-72-3

Name Isobutyric anhydride
CAS 97-72-3
EINECS(EC#) 202-603-6
Molecular Formula C8H14O3
MDL Number MFCD00008913
Molecular Weight 158.19
MOL File 97-72-3.mol

Chemical Properties

Appearance clear colorless liquid
Melting point  -56 °C (lit.)
Boiling point  182 °C (lit.)
density  0.954 g/mL at 25 °C(lit.)
vapor density  5.45 (vs air)
vapor pressure  10 mm Hg ( 67 °C)
refractive index  n20/D 1.406(lit.)
Fp  152 °F
storage temp.  Store at 0°C
form  Liquid
color  Clear colorless
explosive limit 1.09%, 87°F
Water Solubility  decomposes
Sensitive  Moisture Sensitive
BRN  386267
Dielectric constant 13.9(20℃)
Exposure limits ACGIH: TWA 10 ppm
NIOSH: TWA 10 ppm(30 mg/m3); STEL 15 ppm(45 mg/m3)
InChI 1S/C8H14O3/c1-5(2)7(9)11-8(10)6(3)4/h5-6H,1-4H3
InChIKey LSACYLWPPQLVSM-UHFFFAOYSA-N
SMILES CC(C)C(=O)OC(=O)C(C)C
LogP 1.1 at 25℃
Uses
Chemical intermediate.
CAS DataBase Reference 97-72-3(CAS DataBase Reference)
NIST Chemistry Reference Propanoic acid, 2-methyl-, anhydride(97-72-3)
EPA Substance Registry System 97-72-3(EPA Substance)

Safety Data

Symbol(GHS)  Corrosion (GHS05)Skull and Crossbones (GHS06)
GHS05,GHS06
Signal word  Danger
Hazard statements  H301+H311-H314
Precautionary statements  P270-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P361+P364
Hazard Codes  C
Risk Statements 
R34:Causes burns.
R21/22:Harmful in contact with skin and if swallowed .
Safety Statements 
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
RIDADR  2922
WGK Germany  3
RTECS  NQ5550000
F  13-21
Autoignition Temperature 624 °F
TSCA  Yes
REACH Registrations Active
HazardClass  8
PackingGroup  II
HS Code  29159000
Storage Class 6.1A - Combustible acute toxic Cat. 1 and 2
very toxic hazardous materials
Hazard Classifications Acute Tox. 3 Dermal
Acute Tox. 3 Oral
Skin Corr. 1B
Hazardous Substances Data 97-72-3(Hazardous Substances Data)
Toxicity
LD50 orally in Rabbit: 266 mg/kg LD50 dermal Rabbit 475 mg/kg

Hazard Information

Material Safety Data Sheet(MSDS)

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