14523-22-9

Name Rhodium carbonyl chloride
CAS 14523-22-9
EINECS(EC#) 238-540-6
Molecular Formula CH2Cl3ORh
MDL Number MFCD00135610
Molecular Weight 239.29
MOL File 14523-22-9.mol
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Chemical Properties

Appearance red to brownish crystals, crystalline powder or
Melting point  120-125 °C (dec.)(lit.)
storage temp.  2-8°C
solubility  It is soluble in organic or non-aqueous solvent.
form  crystal
color  red
Water Solubility  soluble in most organic solvents; insoluble aliphatic hydrocarbons [MER06]
Sensitive  Air & Moisture Sensitive
Detection Methods T
Merck  14,8187
Exposure limits ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
InChI InChI=1S/4CO.2Cl.2Rh/c4*1-2;;;;/q;;;;2*+1;2*-1
InChIKey ODYPMWFHWPMOKS-UHFFFAOYSA-N
SMILES [Cl+]1[Rh-][Cl+][Rh-]1.[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-]
CAS DataBase Reference 14523-22-9(CAS DataBase Reference)
NIST Chemistry Reference Dirhodium tetracarbonyl dichloride(14523-22-9)
Storage Precautions Moisture sensitive

Safety Data

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302
Precautionary statements  P264-P270-P301+P312a-P330-P501a
Hazard Codes  T
Risk Statements 
R36/38:Irritating to eyes and skin .
R25:Toxic if swallowed.
Safety Statements 
S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes .
RIDADR  UN3466
WGK Germany  3
F  10-21-23
TSCA  No
HazardClass  6.1
PackingGroup  III
HS Code  28439000

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