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121-73-3

Name 3-Nitrochlorobenzene
CAS 121-73-3
EINECS(EC#) 204-496-1
Molecular Formula C6H4ClNO2
MDL Number MFCD00007202
Molecular Weight 157.55
MOL File 121-73-3.mol

Chemical Properties

Appearance Moist tan or pale yellow crystalline solid
Melting point  43-47 °C(lit.)
Boiling point  236 °C(lit.)
density  1.534 g/mL at 25 °C(lit.)
vapor pressure  1.9Pa at 25℃
refractive index  1.5545 (estimate)
Fp  218 °F
storage temp.  Store below +30°C.
solubility  alcohol: freely soluble (hot)(lit.)
form  powder to lump to clear liquid
color  White or Colorless to Yellow
PH 7 (0.26g/l, H2O, 20℃)
Stability: Stable. Incompatible with strong oxidizing agents, strong acids, strong reducing agents.
Water Solubility  INSOLUBLE
Merck  14,2151
BRN  1907947
LogP 2.49
Uses
Intermediate for dyes.
CAS DataBase Reference 121-73-3(CAS DataBase Reference)
NIST Chemistry Reference Benzene, 1-chloro-3-nitro-(121-73-3)
EPA Substance Registry System 121-73-3(EPA Substance)

Safety Data

Hazard Codes  Xn,N,T
Risk Statements 
R22:Harmful if swallowed.
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
Safety Statements 
S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes .
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S38:In case of insufficient ventilation, wear suitable respiratory equipment .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
RIDADR  UN 1578 6.1/PG 2
WGK Germany  2
RTECS  CZ0940000
Autoignition Temperature 500 °F
TSCA  Yes
HazardClass  6.1
PackingGroup  II
HS Code  29049085
Safety Profile
Poison by ingestion and inhalation. It forms methemoglobin in the body and gves rise to cyanosis and blood changes. Its effects are cumulative and analogous to those of nitrobenzene. The para compound is thought to be somewhat less toxic than the ortho compound. Chemically, it is probably converted in the body to chloroaniline, whch is also poisonous. In industry, it is the dust of hs material that is most often the source of intoxication. Flammable liquid and dangerous fire hazard when exposed to heat or flame. It can react with oxidizing materials. When heated to decomposition it emits toxic fumes of Cl-, NOx, and phosgene. See also other chloronitrobenzene entries and NITRO COMPOUNDS of AROMATIC HYDROCARBONS.
Hazardous Substances Data 121-73-3(Hazardous Substances Data)
Toxicity
mouse,LD50,oral,380mg/kg (380mg/kg),Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 25(8), Pg. 50, 1981.

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