112-90-3

Name Oleylamine
CAS 112-90-3
EINECS(EC#) 204-015-5
Molecular Formula C18H37N
MDL Number MFCD00066507
Molecular Weight 267.49
MOL File 112-90-3.mol
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Chemical Properties

Appearance beige paste or powder
Melting point  18-26 °C (lit.)
Boiling point  348-350 °C (lit.)
density  0.813 g/mL at 25 °C(lit.)
vapor pressure  8 mm Hg ( 135 °C)
refractive index  n20/D 1.4596(lit.)
Fp  310 °F
storage temp.  Keep in dark place,Inert atmosphere,Room temperature
form  liquid
pka 10.67±0.10(Predicted)
color  colorless
Odor slt amine/lemon odor
Stability: Stable. Incompatible with acids, acid chlorides, acid anhydrides, oxidizing agents.
Water Solubility  insoluble
Detection Methods GC
BRN  1723960
Cosmetics Ingredients Functions ANTISTATIC
InChI 1S/C18H37N/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18-19/h9-10H,2-8,11-19H2,1H3/b10-9-
InChIKey QGLWBTPVKHMVHM-MDZDMXLPSA-N
SMILES [H]\C(CCCCCCCC)=C(/[H])CCCCCCCCN
LogP 7.780 (est)
Uses
Oleylamine is a long-chain primary alkylamine broadly used in the synthesis of metallic nanostructures. A variety of metallic nanostructures including Au, Ag, Pt, Pd, and their alloy has been synthesized in the presence of oleylamine. It has several important functions in the synthesis of metallic nanostructure. Oleylamine can simultaneously function as a solvent for the reaction mixture and stabilizing agent for metallic nanostructures. In addition, oleylamine has a boiling point of 364 °C; therefore, it can be used to synthesize metallic nanostructures at high temperatures.
CAS DataBase Reference 112-90-3(CAS DataBase Reference)
EPA Substance Registry System 112-90-3(EPA Substance)
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Safety Data

Symbol(GHS)  Corrosion (GHS05)Exclamation Mark (GHS07)Health Hazard (GHS08)Environment (GHS09)
GHS05,GHS07,GHS08,GHS09
Signal word  Danger
Hazard statements  H302-H304-H314-H335-H373-H410
Precautionary statements  P260-P280-P301+P310-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes  C,N
Risk Statements 
R34:Causes burns.
R22:Harmful if swallowed.
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
Safety Statements 
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S24/25:Avoid contact with skin and eyes .
RIDADR  UN 2735 8/PG 2
WGK Germany  2
RTECS  RG4130000
TSCA  TSCA listed
HazardClass  8
PackingGroup  III
HS Code  29215900
Storage Class 8A - Combustible corrosive hazardous materials
Hazard Classifications Acute Tox. 4 Oral
Aquatic Acute 1
Aquatic Chronic 1
Asp. Tox. 1
Eye Dam. 1
Skin Corr. 1B
STOT RE 2
STOT SE 3
Safety Profile
Moderately toxic by intraperitoneal route. An experimental teratogen. Experimental reproductive effects. When heated to decomposition it emits toxic fumes of NOx. See also AMINES.
Hazardous Substances Data 112-90-3(Hazardous Substances Data)
Toxicity
LD50 intraperitoneal in mouse: 888mg/kg

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