109-09-1

Name	2-Chloropyridine
CAS	109-09-1
EINECS(EC#)	203-646-3
Molecular Formula	C5H4ClN
MDL Number	MFCD00006228
Molecular Weight	113.54
MOL File	109-09-1.mol

Chemical Properties

Appearance	Clear colourless to light yellow liquid
Melting point	-46 °C
Boiling point	166 °C/714 mmHg (lit.)
density	1.209
vapor pressure	1.7 mm Hg ( 20 °C)
refractive index	n20/D 1.532(lit.)
Fp	149 °F
storage temp.	Refrigerator
solubility	27g/l
form	Liquid
pka	0.49(at 25℃)
color	Clear colorless to light yellow
PH	6-7 (27g/l, H2O, 20℃)
Water Solubility	27 g/L (20 ºC)
Detection Methods	HPLC,NMR
BRN	105788
CAS DataBase Reference	109-09-1(CAS DataBase Reference)
NIST Chemistry Reference	Pyridine, 2-chloro-(109-09-1)
EPA Substance Registry System	2-Chloropyridine (109-09-1)

Safety Data

Hazard Codes	T
Risk Statements	R23/24/25:Toxic by inhalation, in contact with skin and if swallowed . R36/37/38:Irritating to eyes, respiratory system and skin . less more
Safety Statements	S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . S27:Take off immediately all contaminated clothing . less more
RIDADR	UN 2822 6.1/PG 2
WGK Germany	3
RTECS	US5950000
Hazard Note	Toxic
TSCA	Yes
HazardClass	6.1
PackingGroup	II
HS Code	29333999
Safety Profile	Poison by ingestion, inhalation, skin contact, and intraperitoneal routes. Combustible when exposed to heat or flame. Can react with oxidizing materials. When heated to decomposition it emits very toxic fumes of Cl-, NOx, and phosgene. less more
Hazardous Substances Data	109-09-1(Hazardous Substances Data)

Raw materials And Preparation Products

Hazard Information

General Description

A colorless oily liquid. Toxic by ingestion and/or skin absorption. Used to make other chemicals.

Air & Water Reactions

Slightly soluble in water and denser than water.

Hazard

Toxic by ingestion.

Fire Hazard

Combustible material: may burn but does not ignite readily. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form.

Chemical Properties

Clear colourless to light yellow liquid

Uses

2- Chloropyridine is used as an intermediate chemical in the production of various pyrithione, for use in cosmetics, personal care products and pharmaceutical products.

Uses

2-Chloropyridine (2-CPY) has been identified as a trace organic chemical in process streams, wastewater and even drinking water. Furthermore, it appears to be formed as a secondary pollutant during t he decomposition of specific insecticides.

Definition

ChEBI: 2-chloropyridine is a monochloropyridine.

Synthesis Reference(s)

Synthetic Communications, 19, p. 897, 1989 DOI: 10.1080/00397918908051009
Synthesis, p. 337, 1990

Purification Methods

Dry 2-chloropyridine with NaOH for several days, then distil it from CaO under reduced pressure. [Beilstein 20/5 V 402.]

Material Safety Data Sheet(MSDS)

Spectrum Detail

Well-known Reagent Company Product Information

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