ChemicalBook CAS DataBase List 10025-82-8

10025-82-8

Name	Indium chloride
CAS	10025-82-8
EINECS(EC#)	233-043-0
Molecular Formula	Cl3In
MDL Number	MFCD00011058
Molecular Weight	221.18
MOL File	10025-82-8.mol

Synonyms

INDIUM CHLORIDE INDIUM(II) CHLORIDE INDIUM(III) CHLORIDE INDIUM TRICHLORIDE InCl3 Indium chloride (InCl3) indiumchloride(incl3) IndiumchlorideanhydrousPURATREM Indium(Ⅲ) chloride INDIUM(III) CHLORIDE, 99.999% Indium(III) chloride, anhydrous, powder, 99.999+% metals basis INDIUM(III) CHLORIDE ANHYDROUS Indium(III) chloride, 99.995% Indium(III)chloride,anhydrous(99.999%-In)PURATREM indium(iii) chloride, ultra dry Indium (III) chloride Indium trichloride Indium(III) chloride, anhydrous, 99.99% (metals basis) Indium(III) chloride, anhydrous, 98+% Indium(III) chloride, ultra dry, 99.999% (metals basis)

Chemical Properties

Appearance

white crystalline powder

Melting point

262 °C (dec.)(lit.)

Boiling point

300°C

density

3.46 g/mL at 25 °C(lit.)

vapor pressure

1Pa at 25℃

300°C subl.

storage temp.

Inert atmosphere,Room Temperature

solubility

Water (Slightly)

form

powder

color

White to off-white

Specific Gravity

3.46

Water Solubility

reacts

Crystal Structure

AlCl3 type

Sensitive

Hygroscopic

crystal system

Monoclinic

Merck

14,4958

Space group

C2/m

Lattice constant

a/nm	b/nm	c/nm	α/o	β/o	γ/o	V/nm3
0.641	1.11	0.631	90	109.8	90	0.422

Exposure limits

ACGIH: TWA 0.1 mg/m3
NIOSH: TWA 0.1 mg/m3

Safety Data

Symbol(GHS)	GHS05,GHS08
Signal word	Danger
Hazard statements	H314-H372-H412
Precautionary statements	P260-P273-P280-P303+P361+P353-P305+P351+P338-P314
Hazard Codes	C
Risk Statements	R36/37/38:Irritating to eyes, respiratory system and skin . R34:Causes burns. R29:Contact with water liberates toxic gas. R22:Harmful if swallowed. less more
Safety Statements	S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . less more
RIDADR	UN 3260 8/PG 2
WGK Germany	3
RTECS	NL1400000
F	3-10
TSCA	Yes
REACH Registrations	Active
HazardClass	8
PackingGroup	III
HS Code	28273990
Storage Class	6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects
Hazard Classifications	Aquatic Chronic 3 Eye Dam. 1 Skin Corr. 1C STOT RE 1 Inhalation
Hazardous Substances Data	10025-82-8(Hazardous Substances Data)
Toxicity	MLD s.c. in rats: 10.2 mg/kg; MLD i.v. in rabbits: 0.64 mg/kg, McCord et al., J. Ind. Hyg. Toxicol. 24, 243 (1942) less more

Hazard Information

Hazard

See indium.

Chemical Properties

white crystalline powder

Uses

Catalyzes the enantioselective ring-opening of meso-aziridines with thiols.1,2 A highly efficient catalyst in water for the preparation of furyl glycosides.3

Uses

In electroplating using a solution of the salt with dextrose and NaCN. This solution is stable, though it turns dark on standing and deposits a mud which, however, contains no indium.

Production Methods

According to Klemm, metallic In is oxidized in InCl3 in a stream of Cl2, which has been carefully dried with concentrated H2SO4 and P2O5. A thoroughly dried quartz apparatus whose components have been fused or connected by ground joints is used. Chlorination proceeds rather vigorously at first, with a pale glow, and it proceeds through the mono- and dichloride steps. These compounds are melts. The end product of the chlorination, InCl3, sublimes around 600°C as lustrous spangles which appear on the walls of the receiver. The Indium chloride (LnCl3) may be purified by subliming in a stream of N2 (or CO2) to which some Cl2 has been added. The sublimate can cool in a stream of inert, Cl2-free gas to remove excess chlorine.

General Description

Indium(III) chloride (InCl₃) is an indium halide that is a Lewis acid in a variety of organic reactions.

reaction suitability

reagent type: catalyst
core: indium

Purification Methods

The anhydrous salt forms yellow deliquescent crystals which can be sublimed at 600o in the presence of Cl2/N2 (1:1) [does not melt]. It is resublimed in the presence of Cl2/N2 (1:10) and finally heated to 150o to expel excess Cl2. It is soluble in H2O and should be stored in a tightly closed container. [Baxter & Alter J Am Chem Soc 55 1943 1933.]

Material Safety Data Sheet(MSDS)

Questions And Answer

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