6-бензиламинопурин
- английское имя6-Benzylaminopurine
- CAS №1214-39-7
- CBNumberCB6740007
- ФормулаC12H11N5
- мольный вес225.25
- EINECS214-927-5
- номер MDLMFCD00005572
- файл Mol1214-39-7.mol
химическое свойство
| Температура плавления | 230-233 °C |
| Температура кипения | 145 °C(lit.) |
| плотность | 0.899 g/mL at 20 °C |
| плотность пара | >1 (vs air) |
| давление пара | 3.3 mm Hg ( 20 °C) |
| показатель преломления | n |
| Fp | 103 °F |
| температура хранения | 2-8°C |
| растворимость | H2O: soluble |
| пка | 9.36±0.20(Predicted) |
| форма | Liquid |
| цвет | White to very faint yellow |
| Запах | Characteristic acrylic. |
| Растворимость в воде | Soluble in water, methanol and acetone. Slightly soluble in ethyl acetate and dichloromethane and toluene. Insoluble in n-hexane. |
| БРН | 19406 |
| Стабильность | Stable. Incompatible with strong oxidizing agents. |
| ИнЧИКей | NWBJYWHLCVSVIJ-UHFFFAOYSA-N |
| LogP | 1.570 |
| FDA 21 CFR | 177.1010; 178.3790 |
| Справочник по базе данных CAS | 1214-39-7(CAS DataBase Reference) |
| Рейтинг продуктов питания EWG | 5 |
| FDA UNII | KXG6A989PS |
| Справочник по химии NIST | 1H-purin-6-amine, n-(phenylmethyl)-(1214-39-7) |
| Система регистрации веществ EPA | N-Benzyladenine (1214-39-7) |
| UNSPSC Code | 77101502 |
| NACRES | NA.77 |
больше
| Коды опасности | Xi,Xn | |||||||||
| Заявления о рисках | 36/37/38-20/21/22-22 | |||||||||
| Заявления о безопасности | 9-24/25-37/39-26-36-23 | |||||||||
| РИДАДР | UN 2348 3/PG 3 | |||||||||
| WGK Германия | 3 | |||||||||
| RTECS | UD3150000 | |||||||||
| F | 8 | |||||||||
| TSCA | Yes | |||||||||
| кода HS | 29335995 | |||||||||
| Банк данных об опасных веществах | 1214-39-7(Hazardous Substances Data) | |||||||||
| Токсичность | LD50 orl-rat: 2125 mg/kg TOIZAG 19,336,72 | |||||||||
| NFPA 704: |
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рисовальное письмо(GHS)
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рисовальное письмо(GHS)
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сигнальный язык
предупреждение
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вредная бумага
H302：Вредно при проглатывании.
H410：Чрезвычайно токсично для водных организмов с долгосрочными последствиями.
H361fd：Предполагается, что данное вещество может отрицательно повлиять на способность к деторождению. Предполагается, что данное вещество может отрицательно повлиять на неродившегося ребенка.
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оператор предупредительных мер
P202：Перед использованием ознакомиться с инструкциями по технике безопасности.
P264：После работы тщательно вымыть кожу.
P270：При использовании продукции не курить, не пить, не принимать пищу.
P273：Избегать попадания в окружающую среду.
P301+P312：ПРИ ПРОГЛАТЫВАНИИ: Обратиться за медицинской помощью при плохом самочувствии.
P308+P313：ПРИ подозрении на возможность воздействия обратиться за медицинской помощью.
6-бензиламинопурин химические свойства, назначение, производство
Химические свойства
Colorless to off-white or yellow powder. Corrosive. Insoluble in water, slightly soluble in ethanol, stable in acid and alkali.Использование
6-Benzylaminopurine is a plant growth regulator that belongs to the class of first generation synthetic cytokinin used in agriculture.6-Benzylaminopurine has been used:
to induce sprouting in plant materials.
in seed germination medium for culturing of seeds.
to modify Murashige and Skoog (MS) media for shoot initiation.
inhibitor of respiratory kinase in plants.
6-Benzylaminopurine, benzyl adenine (BAP) is a synthetic cytokinin which together with auxins elicits plant growth and development responses. BAP is a widely use cytokinin supplement to plant growth media such as Murashige and Skoog medium, Gamborg’s medium, and Chu’s N6 medium.
Подготовка
synthesis of 6-benzylaminopurine: To 5g hypoxanthine, add 20mL SOCl2, 0.25g DMAP, 10gBTC dissolved in 20mL SOCl2. Heat and add BTC/SOCl2 dropwise. Reflux (refrigerant cooling) to complete dissolution, steam out SOCl2 (containing phosgene, which is used for recovery), evaporated (drained), cooled to room temperature to obtain a milky yellow solid (6-chloropurine and DMAP.Hcl). Directly add 4g benzylamine and 25g triethylamine to it, heat to 70～80 ℃, or microwave heating, until the 6-chloropurine reaction is complete (TLC monitoring), add ethanol, the solid filtered out is washed with ethanol, and dried to obtain 7 g of product 6-benzylaminopurine with a brown color.Preparation and biological activity of 6-benzylaminopurine derivatives in plants and human cancer cells
Определение
ChEBI: 6-Benzylaminopurine is a member of the class of 6-aminopurines that is adenine in which one of the hydrogens of the amino group is replaced by a benzyl group. It has a role as a plant metabolite and a cytokinin. It derives from an adenine.прикладной
6-Benzylaminopurine solution has been used as a component in the Murashige & Skoog medium (MS) for culturing mandarin explants and plantlets of Dendrocalamus asper (Schultes f.). It has also been used as a supplement in Nitsch and Nitsch medium (NN) of grapevine explants.Общее описание
6-Benzylaminopurine is a plant growth regulator that belongs to the class of first generation synthetic cytokinin used in agriculture commodities.Угроза здоровью
6-benzylaminopurine (6-BA) is widely used in agriculture and horticulture as plant growth regulator. Its excessive use may pose a potential risk to both environment and human health, which is causing great concern. Vapor is irritating when breathed at high concentrations. Contact with liquid causes irritation of skin and burning of eyes; Vapors cause a slight smarting of the eyes or respiratory system if present in high concentrations; If spilled on clothing and allowed to remain, may cause smarting and reddening of the skin.Сельскохозяйственное использование
6-Benzylaminopurine is a plant growth promoter, is the first applied synthetic cytokinin, mainlyused as a broad- spectrum plant growth regulator. It can be used inagriculture, horticulture, for plants at different stages, from germination to harvest. It enhance the shape of apples and to increase the fruit set in pears. It increases the yield of pistachios and tomatoes. Not listed for use in EU countries. Registered for use in the U.S.Торговое название
ABG® 3034; ACCEL®; AGTROL®; 6-BA®; BA® (growth stimulant); CHRYSAL BVB®; EXILIS®; PERLAN®; PROMALIN®; SD® 4901; SQ® 4609Профиль безопасности
Moderately toxic by ingestion andskin contact. Human mutation data reported. Whenheated to decomposition it emits toxic vapors of NOx.Возможный контакт
A polyamine plant growth regulator used to lengthen and enhance the shape of apples and to increase the fruit set in pears. It increases the yield of pistachios and tomatoes. Not listed for use in the EU countries.Перевозки
UN3259 Amines, solid, corrosive, n.o.s, or Polyamines, solid, corrosive, n.o.s., Hazard class: 8; Labels: 8—Corrosive material, Technical Name Required.Методы очистки
It is purified by recrystallisation from aqueous EtOH. It has at 207 and 270nm (H2O), 268 nm max (pH 6), 274nm (0.1 N HCl) and 275nm (0.1 N NaOH). [Daly J Org Chem 21 1553 1956, Bullock et al. J Am Chem Soc 78 3693 1956, Beilstein 26 III/IV 3575.]Несовместимости
May react with strong oxidizers such as chlorates, peroxides, nitrates, etc. May release heat on contact with water. Solid and corrosive amines are chemical bases. Neutralize acids to form salts plus water in exothermic reactions. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. May generate flammable gaseous hydrogen in combination with strong reducing agents, such as hydrides.Утилизация отходов
Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.6-бензиламинопурин запасные части и сырье
сырьё
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6-бензиламинопурин поставщик
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