Synthesis of Potassium niobate
Potassium niobate (KNbO3) is an inorganic compound with the formula KNbO3. A colorless solid, it is classified as a perovskite ferroelectric material. It exhibits nonlinear optical properties, and is a component of some lasers. Nanowires of potassium niobate have been used to produce tunable coherent light.
On cooling from high temperature, KNbO3 undergoes a series of structural phase transitions. At 435 °C, the crystal symmetry changes from cubic centrosymmetric (Pm3m) to tetragonal non-centrosymmetric (P4mm). On further cooling, at 225 °C the crystal symmetry changes from tetragonal (P4mm) to orthorhombic (Amm2) and at −50 °C from orthorhombic (Amm2) to rhombohedral (R3m).
Applications and research
In addition to research in electronic memory storage, potassium niobate is used in resonant doubling. This technique allows small infrared lasers to convert output into blue light, a critical technology for the production of blue lasers and technology dependent upon them.
Potassium niobate has been found useful in many different areas of materials science, including properties of lasers, quantum teleportation, and it has been used to study the optical properties of particulate composite materials.
Synthesis
Nanoscale potassium niobate (KNbO3) powders of orthorhombic structure were synthesized using the sol-gel method. The heat-treatment temperature of the gels had a pronounced effect on KNbO3 particle size and morphology. Field emission scanning electron microscopy and transmission electron microscopy were used to determine particle size and morphology. The average KNbO3 grain size was estimated to be less than 100 nm, and transmission electron microscopy images indicated that KNbO3 particles had a brick-like morphology. Synchrotron X-ray diffraction was used to identify the room-temperature structures using Rietveld refinement. The ferroelectric orthorhombic phase was retained even for particles smaller than 50 nm. The orthorhombic to tetragonal and tetragonal to cubic phase transitions of nanocrystalline KNbO3 were investigated using temperature-dependent powder X-ray diffraction. Differential scanning calorimetry was used to examine the temperature dependence of KNbO3 phase transition. The Curie temperature and phase transition were independent of particle size, and Rietveld analyses showed increasing distortions with decreasing particle size.
