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Is sodium ethoxide stronger than NaOH?

May 8,2024

What is sodium ethoxide in ethanol?

Sodium ethoxide, 21% w/w in ethanol, is a strong base in organic synthesis. It finds application in various chemical reactions such as condensation, esterification, alkoxylation, and etherification. It is actively involved in Claisen condensation, Stobbe reaction, and Wolf-kishner reduction. It is an important starting material for synthesizing ethyl ester and diethyl ester of malonic acid. Williamson ether synthesis reacts with ethyl bromide to form diethyl ether.

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Is sodium ethoxide stronger than NaOH?

When ethanol reacts with Na, sodium ethoxide (CH3CH2ONa) is formed. Although sodium hydroxide is known as a strong base, sodium ethoxide has more basicity than NaOH.Basicity increases with the ekectron density on the molecule (on more eletronegative element or atom here Oxygen). Because of the +I effect -the CH2CH3 group shifts its electron density on Oxygen, making it more polarizable. Thus, Na ethoxide behaves as a stronger base than NaOH.

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