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网站主页CAS数据库列表 86-74-8更多图谱咔唑(86-74-8)核磁图(13CNMR)

咔唑

产品名称 咔唑

CAS号86-74-8

分子式C12H9N

分子量167.21

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  • Mass

    MS-NW-0378          
    carbazole
    C12H9N              (Mass of molecular ion:    167)
    

       Source Temperature: 140 °C
       Sample Temperature: 110 °C
       Direct, 75 eV
    

          39.0       1.3
          63.0       1.9
          69.0       1.2
          69.5       3.7
          70.0       1.4
          70.5       3.2
          75.0       1.1
          82.5       2.6
          83.0       1.2
          83.5      11.8
          84.0       1.6
          87.0       1.0
          89.0       1.2
         113.0       1.6
         114.0       1.1
         115.0       1.3
         138.0       1.2
         139.0       8.7
         140.0       6.7
         141.0       1.0
         164.0       2.1
         165.0       1.4
         166.0      16.1
         167.0     100.0
         168.0      13.5
         178.0       1.0
    

parameter in DMSO-d6

400 MHz in CDCl3


  • 1H NMR 300 MHz
    C12 H9 N 5 wt% in DMSO
    carbazole
    ChemicalStructure
        Parameter     ppm  Hz
    D(A) 8.104 D(B) 7.158 D(C) 7.388 D(D) 7.502 D(E) 11.21 J(A,A') 0.0 J(A,B) 7.89 J(A,B') 0.0 J(A,C) 1.23 J(A,C') 0.0 J(A,D) 0.67 J(A,D') 0.0 J(A,E) 0.7 J(A',B) 0.0 J(A',B') 7.89 J(A',C) 0.0 J(A',C') 1.23 J(A',D) 0.0 J(A',D') 0.67 J(A',E) 0.7 J(B,B') 0.0 J(B,C) 7.24 J(B,C') 0.0 J(B,D) 0.96 J(B,D') 0.0 J(B,E) 0.0 J(B',C) 0.0 J(B',C') 7.24 J(B',D) 0.0 J(B',D') 0.96 J(B',E) 0.0 J(C,C') 0.0 J(C,D) 8.13 J(C,D') 0.0 J(C,E) 0.0 J(C',D) 0.0 J(C',D') 8.13 J(C',E) 0.0 J(D,D') 0.0 J(D,E) 0.0 J(D',E) 0.0 BALKAU,F. & HEFFERNAN,M.L. AUST.J.CHEM. 26, 1501 (1973)

         Hz     ppm     Int.
    

       3363.05  11.210    955
       2435.21   8.117    667
       2427.34   8.091    709
       2255.14   7.517    613
       2247.07   7.490   1000
       2224.38   7.415    476
       2223.16   7.411    481
       2217.16   7.391    623
       2216.09   7.387    782
       2209.09   7.364    369
       2207.87   7.360    362
       2155.14   7.184    495
       2154.23   7.181    493
       2147.16   7.157    813
       2140.17   7.134    384
       2139.17   7.131    377
    


  • 1H NMR 399.65 MHz
    C12 H9 N saturated in CDCl3
    carbazole
    ChemicalStructure
        Assign.     Shift(ppm)
    A 8.084 B 8.03 C 7.42 D 7.42 E 7.24 CONFIRMED BY LAOCN PROGRAM.

         Hz     ppm     Int.
    

       3236.08   8.098    116
       3235.11   8.095    265
       3234.38   8.094    282
       3233.40   8.091    136
       3228.27   8.078    128
       3227.54   8.076    259
       3226.44   8.074    254
       3225.71   8.072    146
       3207.89   8.027     30
       2973.27   7.440     44
       2972.41   7.438     47
       2968.51   7.428    957
       2967.53   7.426   1000
       2965.09   7.420    499
       2964.23   7.418    515
       2963.62   7.416    531
       2962.52   7.413    484
       2955.57   7.396     55
       2954.47   7.393     57
       2906.13   7.272     42
       2901.25   7.260    261
       2897.95   7.252    258
       2896.48   7.248    203
       2893.43   7.240    305
       2890.26   7.232    239
       2888.55   7.228    194
       2885.38   7.220    205
    

in CDCl3



KBr disc



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