3-七氟丁酰-D-樟脑

Mass

MS-NW-7728          
3-heptafluorobutyryl-(+)-camphor
C14H15F7O2          (Mass of molecular ion:    348)

   Source Temperature: 130 °C
   Sample Temperature: 100 °C
   Direct, 75 eV

      18.0       3.2
      27.0      10.2
      28.0       1.9
      29.0       8.8
      31.0       1.0
      39.0      16.0
      40.0       3.3
      41.0      42.1
      42.0       2.6
      43.0      23.4
      45.0       3.3
      50.0       1.3
      51.0       4.5
      52.0       2.3
      53.0      10.3
      54.0       2.7
      55.0      28.8
      56.0       2.4
      57.0       5.3
      59.0       2.5
      63.0       1.6
      65.0       5.4
      66.0       2.4
      67.0      13.3
      68.0       3.9
      69.0      14.8
      70.0       3.1
      71.0       1.3
      75.0       1.4
      77.0       9.3
      78.0       3.0
      79.0       9.4
      80.0       4.3
      81.0      10.0
      82.0       4.1
      83.0      20.2
      84.0       5.4
      90.0       1.1
      91.0      12.6
      92.0       2.0
      93.0       7.3
      94.0       2.7
      95.0      31.2
      96.0       3.7
      97.0       2.3
     100.0       2.2
     103.0       1.1
     105.0       4.1
     106.0       1.2
     107.0       8.0
     108.0      20.2
     109.0      11.8
     110.0       2.8
     115.0       1.0
     117.0       1.6
     118.0       1.0
     119.0      22.2
     120.0       2.3
     121.0       4.7
     122.0       4.7
     123.0      26.3
     124.0       3.1
     131.0       1.2
     133.0      10.4
     134.0       1.4
     135.0       9.4
     136.0       7.8
     137.0       5.1
     139.0       1.1
     145.0       1.0
     146.0       1.0
     149.0       1.8
     150.0       1.7
     151.0      50.7
     152.0       6.4
     153.0       1.0
     159.0       1.0
     161.0       3.0
     164.0       1.3
     169.0       5.0
     179.0      12.9
     180.0       1.5
     181.0       1.8
     201.0       1.3
     209.0       1.0
     249.0       1.0
     251.0       1.1
     259.0       1.1
     263.0       1.5
     264.0       1.2
     265.0       5.1
     273.0       1.2
     277.0       4.0
     278.0       1.3
     279.0       1.2
     285.0       2.1
     287.0       2.4
     291.0       4.1
     292.0       1.2
     293.0       1.1
     300.0       4.7
     301.0       5.2
     302.0       2.4
     304.0       1.8
     305.0      27.1
     306.0       9.1
     307.0       1.4
     315.0       2.6
     319.0       1.7
     320.0      43.1
     321.0       6.3
     329.0       1.0
     333.0      26.6
     334.0       3.9
     348.0     100.0
     349.0      16.3
     350.0       1.7

Assign. Shift(ppm) A 12. B 2.870 C 2.09 D 1.78 E 1.48 F 1.45 G 1.020 J 0.976 K 0.832 ASSIGNED BY C-H COSY.

     Hz     ppm     Int.

   1147.27   2.871     70
   1146.84   2.870     70
   1141.50   2.857     39
    840.85   2.104     49
    837.00   2.095     65
    832.94   2.085     30
    829.52   2.076     30
    825.46   2.066     50
    730.37   1.828     42
    727.17   1.820     45
    717.55   1.796     55
    715.84   1.792     49
    714.35   1.788     61
    706.23   1.768     44
    607.72   1.521     32
    598.53   1.498     62
    594.68   1.489     86
    588.06   1.472    115
    585.92   1.467    141
    580.37   1.453     73
    577.16   1.445     59
    408.14   1.022   1000
    390.40   0.977    827
    385.49   0.965     41
    332.92   0.834    744