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MS-NW-9994 ethyl 1-methyl-1,2,3,6-tetrahydro-4-pyridinecarboxylate C9H15NO2 (Mass of molecular ion: 169)
Source Temperature: 220 °C Sample Temperature: 160 °C Reservoir, 75 eV
15.0 2.1 18.0 1.7 27.0 5.8 28.0 2.8 29.0 4.1 30.0 1.5 31.0 1.0 39.0 2.7 41.0 4.1 42.0 24.3 43.0 15.4 44.0 8.5 45.0 1.0 48.0 1.3 51.0 1.4 52.0 1.3 53.0 8.6 54.0 1.7 55.0 2.7 57.0 1.1 67.0 2.8 68.0 2.4 69.0 3.6 70.0 3.3 79.0 1.5 80.0 2.2 81.0 8.1 82.0 2.3 94.0 17.6 95.0 3.0 96.0 100.0 97.0 8.0 98.0 10.4 99.0 4.2 110.0 1.0 112.0 2.6 122.0 3.0 124.0 15.4 125.0 1.3 126.0 1.2 138.0 3.4 140.0 32.1 141.0 2.6 142.0 1.5 168.0 4.5 169.0 13.4 170.0 2.5
400 MHz in CDCl3
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1H NMR 399.65 MHz C9 H15 N O2 0.05 ml : 0.5 ml CDCl3 ethyl 1-methyl-1,2,3,6-tetrahydro-4-pyridinecarboxylate Assign. Shift(ppm)
A 6.887 B 4.197 C 3.09 D 2.545 E 2.44 F 2.371 G 1.289
Hz ppm Int.
2757.81 6.901 30 2756.10 6.897 61 2754.39 6.893 87 2752.56 6.888 123 2750.85 6.884 90 2749.15 6.879 64 2747.44 6.875 32 1688.23 4.225 118 1681.03 4.207 345 1673.95 4.189 359 1666.87 4.171 128 1240.97 3.106 96 1237.92 3.098 228 1234.62 3.090 238 1231.69 3.082 109 1024.17 2.563 104 1017.94 2.548 280 1012.70 2.534 196 978.88 2.450 62 976.44 2.444 82 973.51 2.436 110 971.68 2.432 100 968.75 2.424 69 966.06 2.418 40 965.45 2.416 40 947.75 2.372 1000 522.34 1.307 370 515.14 1.289 711 512.70 1.283 35 508.06 1.272 390