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MS-NW-6060 N-tert-butylformamide C5H11NO (Mass of molecular ion: 101)
Source Temperature: 250 °C Sample Temperature: 190 °C Reservoir, 75 eV
15.0 6.4 18.0 9.1 26.0 1.3 27.0 7.0 28.0 6.2 29.0 10.6 30.0 7.0 38.0 1.2 39.0 9.8 40.0 2.6 41.0 33.2 42.0 17.4 43.0 4.1 44.0 1.8 45.0 1.4 46.0 53.7 55.0 4.2 56.0 16.5 57.0 11.0 58.0 100.0 59.0 5.0 86.0 41.8 87.0 2.2 101.0 11.4
400 MHz in CDCl3
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1H NMR 399.65 MHz C5 H11 N O 0.05 ml : 0.5 ml CDCl3 N-tert-butylformamide Assign. Shift(ppm)
A 8.244 B 8.006 C 7.51 D 6.83 E *1 1.368 F *1 1.343 MIXTURE OF ISOMERS DUE TO C-N HINDERED ROTATION
Hz ppm Int.
3301.27 8.261 100 3288.94 8.230 107 3201.05 8.010 109 3198.73 8.004 109 570.92 1.429 23 570.31 1.428 22 547.00 1.369 1000 536.74 1.344 981
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