三环[5,2,1,0(2,6)]癸-8-酮

Mass

MS-IW-0072          
tricyclo(5.2.1.0(2,6))decane-8-one
C10H14O             (Mass of molecular ion:    150)

   Source Temperature: 260 °C
   Sample Temperature: 150 °C
   Reservoir, 75 eV

      27.0      12.6
      28.0       2.0
      29.0       3.7
      38.0       1.3
      39.0      22.8
      40.0       5.7
      41.0      20.9
      42.0       2.1
      43.0       1.9
      50.0       2.0
      51.0       6.4
      52.0       4.0
      53.0      14.4
      54.0      14.5
      55.0       9.6
      63.0       1.9
      65.0       8.4
      66.0      17.8
      67.0      37.2
      68.0      13.6
      69.0       1.8
      70.0       1.1
      77.0      19.6
      78.0      13.1
      79.0      85.1
      80.0      53.9
      81.0      39.9
      82.0      10.4
      83.0       3.9
      84.0       1.8
      85.0       2.1
      91.0      22.2
      92.0       8.3
      93.0      38.6
      94.0      16.3
      95.0       6.7
      96.0       2.1
     103.0       1.2
     104.0       5.3
     105.0       5.8
     106.0     100.0
     107.0      42.3
     108.0      24.5
     109.0      47.8
     110.0       3.9
     117.0       5.6
     119.0      10.9
     120.0       2.7
     121.0      31.0
     122.0      14.8
     123.0       1.7
     131.0       1.3
     132.0       5.1
     133.0       2.0
     134.0       2.0
     135.0       5.5
     148.0       3.0
     149.0       4.9
     150.0      78.2
     151.0       9.3
     152.0       1.1

Assign. Shift(ppm) A *1 2.403 B 2.360 C *1 2.12 D 2.021 E 1.98 F 1.78 G 1.77 to 1.75 J 1.529 K 1.347 L 1.09 ASSIGNED BY C-H COSY

     Hz     ppm     Int.

    963.26   2.411    451
    962.04   2.408    466
    958.86   2.400    480
    958.13   2.398    471
    957.64   2.397    472
    943.24   2.361   1000
    857.91   2.147    311
    852.29   2.133    417
    849.12   2.125    621
    845.70   2.117    456
    840.33   2.103    365
    831.42   2.081    118
    822.88   2.060    327
    818.36   2.048    319
    805.66   2.016    538
    801.27   2.005    487
    799.07   2.000    277
    797.61   1.996    309
    795.90   1.992    300
    794.43   1.988    249
    790.65   1.979    336
    789.06   1.975    357
    787.60   1.971    336
    786.25   1.968    305
    785.03   1.965    369
    783.69   1.961    368
    781.86   1.957    333
    777.95   1.947    235
    776.37   1.943    295
    774.90   1.939    283
    767.94   1.922    141
    723.14   1.810    620
    718.75   1.799    877
    715.33   1.790    311
    714.84   1.789    309
    709.11   1.775    557
    704.35   1.763    624
    701.54   1.756    817
    698.36   1.748    419
    696.17   1.742    347
    618.77   1.549    193
    617.31   1.545    470
    615.97   1.542    596
    614.50   1.538    413
    613.04   1.534    167
    609.74   1.526    133
    608.03   1.522    164
    606.57   1.518    330
    605.10   1.515    469
    603.64   1.511    365
    602.17   1.507    163
    564.45   1.413    106
    557.74   1.396    176
    551.88   1.381    300
    545.29   1.365    496
    539.43   1.350    365
    532.84   1.334    528
    526.37   1.318    288
    520.39   1.303    255
    517.21   1.295     31
    513.92   1.286    137
    457.89   1.146    136
    455.20   1.139     59
    450.93   1.129    264
    445.07   1.114    332
    443.36   1.110    300
    438.35   1.097    437
    437.26   1.095    410
    431.76   1.081    386
    430.66   1.078    428
    425.78   1.066    249
    423.95   1.061    322
    417.85   1.046    196
    413.94   1.036     54
    411.01   1.029     98