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二氯二茂钛

产品名称 二氯二茂钛

CAS号1271-19-8

分子式C10H10Cl2Ti

分子量248.96

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  • Mass

    MS-NW-2436          
    titanocene dichloride
    C10H10Cl2Ti         (Mass of molecular ion:    248)
    

       Source Temperature: 200 °C
       Sample Temperature: 120 °C
       Direct, 75 eV
    

          18.0       3.1
          28.0       1.7
          36.0       2.1
          37.0       1.0
          38.0       3.3
          39.0      30.6
          40.0       2.2
          48.0       1.7
          62.0       1.6
          63.0       4.0
          64.0       1.3
          65.0      26.7
          66.0       4.9
          73.0       1.5
          81.0       1.3
          82.0       1.3
          83.0      13.1
          84.0       1.6
          85.0       6.0
          86.0       2.2
          87.0       1.1
         108.0       1.4
         110.0       1.1
         112.0       1.6
         113.0       1.7
         116.0       1.0
         117.0       1.0
         118.0      10.1
         119.0       1.5
         120.0       7.4
         121.0       3.5
         122.0       6.4
         123.0       1.9
         124.0       2.4
         128.0       1.3
         146.0       4.7
         147.0       6.6
         148.0      38.8
         149.0       7.2
         150.0      15.0
         151.0       1.9
         152.0       1.1
         176.0       2.3
         178.0       1.5
         181.0      10.1
         182.0      10.1
         183.0     100.0
         184.0      18.3
         185.0      67.2
         186.0       9.2
         187.0      13.8
         188.0       1.4
         211.0       2.1
         212.0       3.7
         213.0      11.1
         214.0       3.1
         215.0       4.0
         246.0       2.1
         247.0       2.1
         248.0      20.1
         249.0       4.7
         250.0      13.5
         251.0       2.5
         252.0       2.9
    

400 MHz in DMSO-d6


  • 1H NMR 399.65 MHz
    C10 H10 Cl2 Ti 0.038 g : 0.5 ml DMSO-d6
    titanocene dichloride
    ChemicalStructure
        Assign.     Shift(ppm)
    A 6.673

         Hz     ppm     Int.
    

       2671.26   6.684     33
       2667.11   6.674   1000
    

KBr disc



TI(III) COMPLEX IN C6H6/(CH3)C6H5, X-BAND

GRIGNARD REACTION WITH PROPYLENE IN THF

REDUCTION WITH NA AND ALCL3 IN THF

4)

TI(III) COMPLEX IN C6H6/(CH3)C6H5, Q-BAND

TI(III) COMPLEX IN C6H6/(CH3)C6H5, HALF FIELD