TRANS-TRIPHENYL(1-PROPENYL)PHOSPHONIUMCHLORIDE

Mass

MS-NW-7019          
trans-triphenyl(1-propenyl)phosphonium chloride
C21H20ClP           (Mass of molecular ion:    338)

   Source Temperature: 240 °C
   Sample Temperature: 140 °C
   Direct, 75 eV

      27.0       1.9
      35.0       1.4
      36.0       3.4
      38.0       1.1
      39.0       5.3
      41.0       1.1
      50.0       4.3
      51.0      14.0
      52.0       1.8
      56.0       1.1
      57.0       4.0
      63.0       3.0
      65.0       3.5
      69.0       1.2
      74.0       1.2
      75.0       1.5
      76.0       1.6
      77.0       7.9
      78.0       3.8
      79.0       1.4
      80.0       1.6
      81.0       3.8
      82.0       1.3
      83.0       2.0
      89.0       1.7
      91.0       5.2
     102.0       1.5
     105.0       1.1
     107.0      18.3
     108.0      27.8
     109.0       3.7
     115.0       7.4
     116.0       1.8
     117.0       1.5
     120.0       1.1
     121.0       1.3
     126.0       1.0
     128.0       2.7
     129.0       1.1
     131.0       2.0
     133.0       5.0
     139.0       2.9
     141.0       2.8
     151.0       1.4
     152.0      10.9
     153.0       3.1
     154.0       3.1
     157.0       6.0
     165.0       1.5
     170.0       3.7
     181.0       2.0
     182.0       1.2
     183.0      76.4
     184.0      15.8
     185.0      12.1
     186.0       2.3
     259.0       1.3
     260.0       1.4
     261.0      16.2
     262.0     100.0
     263.0      20.6
     264.0       2.3
     275.0      11.0
     276.0       4.5
     277.0       2.1
     301.0       3.5
     302.0       3.4
     303.0       1.6
     328.0       1.4
     342.0       1.3

Assign. Shift(ppm) A 7.850 B 7.746 C 7.686 D 7.66 E 6.646 F 2.354 J(A,P-31)=2.0HZ J(B,P-31)=3.8HZ J(C,P-31)12.9HZ J(E,F)=6.8HZ J(D,E)=16.7HZ J(E,P-31)=22HZ J(D,P-31)=22HZ

     Hz     ppm     Int.

   3154.91   7.895     30
   3152.22   7.888     40
   3150.27   7.883     51
   3149.78   7.882     51
   3147.58   7.876    120
   3146.12   7.873    216
   3144.41   7.868    242
   3143.07   7.865    165
   3140.99   7.860    173
   3138.92   7.855    506
   3136.84   7.849    563
   3135.01   7.845    208
   3133.06   7.840    236
   3131.47   7.836    381
   3130.74   7.834    327
   3129.39   7.831    389
   3128.17   7.828    217
   3124.27   7.818     56
   3123.05   7.815     49
   3122.44   7.813     47
   3121.46   7.811     46
   3120.61   7.809     46
   3119.26   7.805     53
   3118.53   7.804     54
   3117.80   7.802     56
   3117.43   7.801     56
   3116.94   7.800     58
   3115.84   7.797     63
   3105.96   7.772    444
   3104.13   7.768    314
   3102.17   7.763    524
   3100.59   7.759    367
   3099.37   7.756    464
   3097.90   7.752    912
   3095.58   7.746    544
   3094.12   7.743    937
   3090.33   7.733    683
   3086.67   7.724    636
   3084.59   7.719    293
   3083.37   7.716    310
   3081.79   7.712    827
   3080.69   7.709   1000
   3075.56   7.696    235
   3073.61   7.691    570
   3072.02   7.687    474
   3067.75   7.677    992
   3062.38   7.663    301
   3060.55   7.659    675
   3059.20   7.655    505
   3052.12   7.637     34
   3051.51   7.636     32
   2677.61   6.700     90
   2670.90   6.684     94
   2667.60   6.675     31
   2664.31   6.667     35
   2662.11   6.662     47
   2661.01   6.659     93
   2655.64   6.645    107
   2654.42   6.642    104
   2649.05   6.629     98
   2645.75   6.621     32
   2642.33   6.612     32
   2639.16   6.604     84
   2632.45   6.587     83
    952.88   2.385     31
    952.51   2.384     31
    946.29   2.368    382
    944.58   2.364    489
    943.97   2.362    508
    942.26   2.358    424
    939.58   2.352    405
    937.87   2.347    492
    937.38   2.346    499
    935.67   2.342    396
    931.27   2.331     37