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MS-NW-9787 4-bromoisophthalic acid C8H5BrO4 (Mass of molecular ion: 244)
Source Temperature: 170 °C Sample Temperature: 140 °C Direct, 75 eV
17.0 1.5 18.0 7.6 27.0 1.1 28.0 1.8 37.0 2.8 38.0 2.8 39.0 4.3 44.0 2.0 45.0 5.7 49.0 1.7 50.0 14.0 51.0 5.1 53.0 6.5 55.0 1.1 61.0 1.0 62.0 2.4 63.0 11.8 64.0 7.8 65.0 3.1 66.0 1.0 68.5 2.7 69.0 1.4 73.0 4.5 74.0 23.3 75.0 27.5 76.0 8.5 77.0 3.2 78.0 1.0 80.0 1.3 81.0 5.2 82.0 1.3 90.0 1.2 91.0 5.5 92.0 17.5 93.0 1.5 102.0 2.8 103.0 4.7 105.0 1.5 106.0 1.3 109.0 1.8 117.0 2.3 119.0 5.2 120.0 3.9 143.0 19.7 144.0 1.2 145.0 19.0 146.0 1.0 149.0 1.2 153.0 1.8 154.0 1.7 155.0 5.1 156.0 1.8 157.0 3.3 165.0 1.2 171.0 2.0 173.0 1.7 181.0 1.3 183.0 4.4 185.0 3.1 199.0 18.5 200.0 2.2 201.0 17.6 202.0 1.8 216.0 1.3 227.0 87.8 228.0 7.8 229.0 85.6 230.0 7.6 244.0 100.0 245.0 9.0 246.0 97.9 247.0 8.8 248.0 1.1
400 MHz in DMSO-d6
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1H NMR 399.65 MHz C8 H5 Br O4 0.033 g : 0.5 ml DMSO-d6 4-bromoisophthalic acid Assign. Shift(ppm)
A 13.6 B 8.277 C 7.952 D 7.886 J(B,C)=2.1HZ J(C,D)=8.3HZ
Hz ppm Int.
5424.80 13.574 54 3309.33 8.281 881 3307.19 8.276 895 3184.75 7.969 416 3182.61 7.964 401 3179.62 7.957 49 3176.41 7.948 692 3174.28 7.943 731 3155.05 7.895 1000 3146.71 7.874 599
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