Diethyl chlorothiophosphate

Mass

MS-NW-2937          
O,O'-diethyl chlorothiophosphate
C4H10ClO2PS         (Mass of molecular ion:    188)

   Source Temperature: 280 °C
   Sample Temperature: 180 °C
   Reservoir, 75 eV

      14.0       1.4
      15.0       7.3
      26.0       6.6
      27.0      44.1
      28.0      16.0
      29.0      70.4
      30.0       1.5
      31.0       2.0
      32.0       3.9
      34.0       1.6
      35.0       1.6
      36.0       2.4
      42.0       1.3
      43.0      11.9
      44.0       2.7
      45.0      64.7
      46.0       1.9
      47.0      17.9
      48.0       2.4
      58.0       1.3
      59.0       2.2
      60.0       9.0
      61.0       5.2
      62.0       1.4
      63.0       5.9
      64.0       1.1
      65.0      17.7
      67.0       2.2
      79.0       7.2
      80.0       5.0
      81.0       1.0
      83.0      18.3
      85.0       5.6
      91.0       1.7
      93.0       3.5
      96.0       5.1
      97.0      76.3
      98.0       1.9
      99.0       9.8
     100.0       6.0
     101.0       2.2
     102.0       1.8
     108.0       1.5
     110.0       1.2
     111.0      15.9
     113.0       5.3
     114.0       2.0
     115.0      28.9
     116.0      62.2
     117.0      13.1
     118.0      22.2
     119.0       1.6
     121.0       1.9
     125.0      24.8
     126.0       1.7
     127.0       4.2
     128.0       1.5
     129.0       1.5
     131.0       2.4
     132.0      71.5
     133.0      40.7
     134.0      26.7
     135.0      14.8
     136.0       1.3
     143.0       8.7
     144.0      64.7
     145.0       8.2
     146.0      24.2
     147.0       2.0
     148.0       1.1
     153.0      10.8
     159.0       2.2
     160.0       7.7
     161.0      16.1
     162.0       3.3
     163.0       5.5
     188.0     100.0
     189.0       5.9
     190.0      36.1
     191.0       1.9
     192.0       1.5

Assign. Shift(ppm) A 4.300 B 1.414 J(P-31,H(B))=1.0HZ J(P-31,H(A))=11.0HZ

     Hz     ppm     Int.

    401.69   4.486     71
    400.56   4.473     77
    394.44   4.405    222
    393.50   4.394    235
    390.69   4.363     87
    390.00   4.355     93
    387.25   4.324    251
    386.50   4.316    249
    383.44   4.282    284
    382.94   4.276    266
    380.13   4.245    107
    379.63   4.239    109
    376.19   4.201    354
    369.13   4.122    173
    133.94   1.496    491
    132.94   1.485    510
    129.13   1.442     30
    126.94   1.418    973
    125.94   1.407   1000
    119.75   1.338    436
    118.81   1.327    445