Testosterone acetate

Mass

MS-NW-7361          
3-oxo-4-androsten-17beta-yl acetate
C21H30O3            (Mass of molecular ion:    330)

   Source Temperature: 190 °C
   Sample Temperature: 170 °C
   Direct, 75 eV

      15.0       1.1
      27.0       2.8
      29.0       4.5
      39.0       6.0
      40.0       1.1
      41.0      19.1
      42.0       1.0
      43.0      71.6
      44.0       1.9
      45.0       1.4
      51.0       2.1
      52.0       1.4
      53.0       9.3
      54.0       1.3
      55.0      20.3
      56.0       1.1
      57.0       2.6
      60.0       1.2
      65.0       6.1
      66.0       2.6
      67.0      16.0
      68.0       1.9
      69.0       4.8
      71.0       1.5
      77.0      19.4
      78.0       4.6
      79.0      28.2
      80.0       4.8
      81.0      17.5
      82.0       2.3
      83.0       4.3
      91.0      34.5
      92.0       6.6
      93.0      26.3
      94.0      11.4
      95.0      20.5
      96.0       4.2
      97.0       6.9
     103.0       3.4
     104.0       3.1
     105.0      28.8
     106.0       8.0
     107.0      22.8
     108.0       7.7
     109.0      17.2
     110.0       5.7
     111.0       6.3
     115.0       5.0
     116.0       2.4
     117.0       9.4
     118.0       4.3
     119.0      19.8
     120.0       8.0
     121.0      15.4
     122.0      11.7
     123.0      25.4
     124.0     100.0
     125.0      11.5
     127.0       1.1
     128.0       3.6
     129.0       5.6
     130.0       2.5
     131.0      18.2
     132.0       8.1
     133.0      25.5
     134.0      18.9
     135.0      10.8
     136.0       7.1
     137.0      10.3
     138.0       3.5
     141.0       2.1
     142.0       2.0
     143.0       5.7
     144.0       7.3
     145.0      15.0
     146.0      30.4
     147.0      88.4
     148.0      21.9
     149.0      12.0
     150.0       2.4
     151.0       2.4
     153.0       1.0
     155.0       1.9
     156.0       1.3
     157.0       5.6
     158.0       4.2
     159.0      10.9
     160.0       6.5
     161.0       9.0
     162.0       5.8
     163.0       4.2
     164.0       1.7
     165.0       6.9
     166.0       1.4
     169.0       1.7
     170.0       1.3
     171.0       5.0
     172.0       4.7
     173.0       6.0
     174.0       5.4
     175.0       4.3
     176.0       3.0
     177.0       2.5
     181.0       1.2
     183.0       2.0
     184.0       1.2
     185.0      20.7
     186.0       6.0
     187.0       7.2
     188.0       3.3
     189.0       2.9
     190.0       1.1
     195.0       1.2
     197.0       2.2
     198.0       1.1
     199.0       6.0
     200.0       4.2
     201.0       3.5
     202.0       1.8
     203.0       3.5
     204.0       1.0
     206.0       2.2
     207.0       1.7
     209.0       1.2
     211.0       2.6
     212.0       1.2
     213.0      15.2
     214.0       4.3
     215.0       2.8
     216.0       1.1
     217.0       1.0
     225.0       1.1
     226.0       2.0
     227.0       6.9
     228.0      50.5
     229.0      12.2
     230.0       9.1
     231.0       3.4
     232.0       1.8
     237.0       2.7
     241.0       1.7
     242.0       3.1
     243.0       1.9
     244.0       1.4
     245.0      17.5
     246.0      13.7
     247.0       2.8
     248.0       1.0
     251.0       1.1
     252.0       4.1
     253.0       2.8
     255.0       9.2
     256.0       2.1
     259.0       1.0
     260.0       1.5
     268.0       1.4
     269.0       2.1
     270.0      20.9
     271.0       6.6
     272.0       1.4
     273.0       5.0
     274.0       1.7
     286.0       1.3
     287.0       3.1
     288.0      53.6
     289.0      11.0
     290.0       1.4
     302.0       2.7
     312.0       1.4
     315.0       2.9
     330.0      64.1
     331.0      16.1
     332.0       2.6

Assign. Shift(ppm) A 5.729 B 4.601 C 2.409 D 2.39 E 2.35 F 2.288 G 2.182 J 2.046 K 2.04 L 1.85 M 1.795 N 1.70 P 1.66 Q 1.63 to 1.550 R 1.52 S 1.41 T 1.363 U 1.196 V 1.19 W 1.07 X 1.04 Y 0.953 Z 0.841 ASSIGNED BY H-H COSY. J(B,G)=9.2HZ J(B,R)=7.9HZ J(C,E)=-16.8HZ J(C,K)=5.2HZ J(C,N)=16.8HZ J(E,K)=3.3HZ J(E,N)=5.1HZ J(F,D)=-14.6HZ J(F,L)=2.3HZ J(F,X)=4.3HZ J(G,P)=6.0HZ J(G,R)=-13.8HZ J(G,S)=9.5HZ J(K,N)=-13.4HZ J(L,X)=-12.9HZ J(M,V)=-12.8HZ J(T,M)=6.8HZ J(T,V)=12.8HZ

     Hz     ppm     Int.

   2290.41   5.732    113
   2289.31   5.729    114
   1847.29   4.623     57
   1839.36   4.603     72
   1838.13   4.600     71
   1830.20   4.580     58
    969.48   2.426     56
    964.48   2.414     50
    961.91   2.407     32
    960.21   2.403     30
    955.20   2.391     79
    950.20   2.378     54
    948.12   2.373     36
    946.29   2.368     55
    942.75   2.359     65
    941.53   2.356     63
    941.04   2.355     64
    938.23   2.348     43
    922.85   2.310     38
    920.41   2.304     49
    918.58   2.299     45
    916.02   2.293     39
    882.32   2.208     30
    876.22   2.193     31
    868.65   2.174     33
    862.55   2.159     33
    822.14   2.058     39
    817.63   2.046   1000
    814.09   2.038     50
    808.84   2.024     39
    805.66   2.016     43
    803.96   2.012     39
    800.66   2.004     30
    734.86   1.839     30
    723.63   1.811     37
    711.18   1.780     41
    684.08   1.712     50
    679.20   1.700     43
    671.26   1.680     39
    668.70   1.674     30
    664.55   1.663     40
    661.62   1.656     30
    644.78   1.614     41
    641.48   1.606     47
    633.54   1.586     49
    630.62   1.578     48
    626.95   1.569     52
    623.78   1.561     53
    619.38   1.550     44
    615.48   1.541     31
    572.75   1.434     32
    568.73   1.424     30
    560.06   1.402     33
    556.40   1.393     39
    551.03   1.379     43
    544.80   1.364     44
    538.94   1.349     39
    532.59   1.333     36
    485.23   1.215     31
    478.15   1.197    618
    472.41   1.183     47
    438.60   1.098     30
    431.40   1.080     46
    427.73   1.071     34
    426.39   1.067     35
    422.24   1.057     34
    419.31   1.050     53
    408.45   1.023     34
    393.19   0.984     38
    382.32   0.957     31
    381.10   0.954     34
    378.17   0.947     33
    336.30   0.842    629