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Propineb

Product NamePropineb
CAS12071-83-9
MFC5H10N2S4
MW226.41
EINECS235-134-0
MOL File12071-83-9.mol

Chemical Properties

Melting point	157-159°C
storage temp.	0-6°C
solubility	DMSO (Slightly, Heated)
form	Solid
color	Off-White to Light Beige
Merck	13,7911
Major Application	agriculture environmental
InChI	1S/C5H10N2S4.Zn/c1-3(7-5(10)11)2-6-4(8)9;/h3H,2H2,1H3,(H2,6,8,9)(H2,7,10,11);/q;+2/p-2
InChIKey	KKMLIVYBGSAJPM-UHFFFAOYSA-L
SMILES	CC1CNC(=S)S[Zn]SC(=S)N1
CAS DataBase Reference	12071-83-9(CAS DataBase Reference)
EPA Substance Registry System	Propineb (12071-83-9)

Safety Information

Hazard Codes	N
Risk Statements	51/53
Safety Statements	60-61
RIDADR	UN3077 9/PG 3
WGK Germany	WGK 2
RTECS	ZH4950000
HS Code	29302000
Storage Class	11 - Combustible Solids
Hazard Classifications	Aquatic Chronic 2 STOT RE 2
Toxicity	LD50 in male rats, rabbits, cats (mg/kg): 8500, >2500, >2500 orally (Grewe)

MSDS

Provider	Language
(1-Methyl-1,2-ethanediyl)bis-carbamodithioic acid zinc complex	English

Usage And Synthesis

Chemical Properties

Faintly yellow crystals or powder; becomes dark when heated. Decomposes in the presence of strong acids or bases. Insoluble in most common solvents.

Uses

Agricultural fungicide.

Uses

Pesticides and plant growth

Uses

Propineb is a dithiocarbamate compound, which is used as a fungicide. Sensitization was reported in an agricultural worker.

Definition

ChEBI: A polymeric complex of zinc with the propylene 1,2-bis(dithiocarbamate) anionic ligand. A fungicide, it is used to control a wide range of fungal diseases, including downy mildew, brown rot, black rot, red fire, leaf spot, and blight in crops such as grape , tomatoes, potatoes, berries, citrus, rice and tea.

Hazard

Toxic by ingestion.

Agricultural Uses

Fungicide: Used to control downy mildew, black rot, brown rot and other fungi on vines, apples, pears, citrus, berry fruit, stone fruit, tomatoes, potatoes, tobacco, vegetables, rice, ornamentals and tea. Not currently registered in the U.S. Used in more than a dozen European countries. There are more than 15 global suppliers.

Trade name

AIRONE®; ANTRACOL®; BAY®-46131; BAYER®-46131; LH 3012®; LH 30/Z®; MEZINEB®; PROPINEBE®; ZIPROMAT®

Contact allergens

Ziram is a rubber vulcanization accelerator of the dithiocarbamate group. Sensitization was reported in several patients. Ziram is also used as a fungicide and can cause contact dermatitis in agricultural workers.

Propineb Supplier

Propineb manufacturers

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