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9-Bromophenanthrene

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9-Bromophenanthrene Basic information
9-Bromophenanthrene Chemical Properties
  • Melting point:60-64 °C(lit.)
  • Boiling point:180-190 °C2 mm Hg(lit.)
  • Density 1.4251 (rough estimate)
  • refractive index 1.6404 (estimate)
  • Flash point:>230 °F
  • storage temp. Store below +30°C.
  • solubility chloroform: 50 mg/mL, clear
  • form Powder
  • color Light yellow
  • BRN 1869927
  • InChIKeyRSQXKVWKJVUZDG-UHFFFAOYSA-N
  • CAS DataBase Reference573-17-1(CAS DataBase Reference)
  • NIST Chemistry ReferencePhenanthrene, 9-bromo-(573-17-1)
Safety Information
MSDS
9-Bromophenanthrene Usage And Synthesis
  • Chemical Propertieslight yellow powder
  • Uses9-Bromophenanthrene is used as halogenated building block. Isotope labelled 9-Bromophenanthrene (B687200), a halogenated polycyclic aromatic hydrocarbon that has been seen to have a room temperature phosphorescence that can be induced by β-cyclodextrin (β-CD) in the presence of cyclohexane; however, trace Fe(III) causes a decrease of the RTP emission.
  • Preparation9-Bromophenanthrene (90-94%) is produced by adding bromine to a refluxing solution of phenanthrene in carbon tetrachloride. This is the starting-point of 9-substituted phenanthrenes, e.g, when heated with cuprous cyanide at 260℃, 9-bromophenanthrene forms the corresponding cyano-compound; this may be hydrolysed to phenanthrene-9-carboxylic acid. Phenanthrene undergoes the Friedel-Crafts reaction mainly in the 3-, and to a small extent, in the 2-position. It is chloromethylated in the 9-position. When nitrated, phenanthrene gives a mixture of three mononitro-derivatives, the 3-isomer predominating. Sulphonation of phenanthrene gives a mixture of 1-, 2-, 3- and 9-phenanthrenesulphonic acids, and the ratio of these isomers depends on the temperature.
9-Bromophenanthrene Preparation Products And Raw materials
9-Bromophenanthrene(573-17-1)Related Product Information
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