ChemicalBook > Product Catalog > Organic Chemistry > Hydrocarbons and derivatives > Hydrocarbon halides > 9-Bromophenanthrene
9-Bromophenanthrene
- Product Name:9-Bromophenanthrene
- CAS:573-17-1
- MF:C14H9Br
- MW:257.13
- EINECS:209-351-6
- Mol File:573-17-1.mol
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9-Bromophenanthrene Chemical Properties
- Melting point:60-64 °C(lit.)
- Boiling point:180-190 °C2 mm Hg(lit.)
- Density 1.4251 (rough estimate)
- refractive index 1.6404 (estimate)
- Flash point:>230 °F
- storage temp. Store below +30°C.
- solubility chloroform: 50 mg/mL, clear
- form Powder
- color Light yellow
- BRN 1869927
- InChIKeyRSQXKVWKJVUZDG-UHFFFAOYSA-N
- CAS DataBase Reference573-17-1(CAS DataBase Reference)
- NIST Chemistry ReferencePhenanthrene, 9-bromo-(573-17-1)
- Hazard Codes Xi,Xn
- Risk Statements 20/21/22-36/37/38
- Safety Statements 22-24/25-36-26
- WGK Germany 3
- RTECS SF7197000
- F 8
- Hazard Note Irritant
- HS Code 29036990
- Language:EnglishProvider:9-Bromophenanthrene
- Language:EnglishProvider:SigmaAldrich
- Language:EnglishProvider:ACROS
- Language:EnglishProvider:ALFA
9-Bromophenanthrene Usage And Synthesis
- Chemical Propertieslight yellow powder
- Uses9-Bromophenanthrene is used as halogenated building block. Isotope labelled 9-Bromophenanthrene (B687200), a halogenated polycyclic aromatic hydrocarbon that has been seen to have a room temperature phosphorescence that can be induced by β-cyclodextrin (β-CD) in the presence of cyclohexane; however, trace Fe(III) causes a decrease of the RTP emission.
- Preparation9-Bromophenanthrene (90-94%) is produced by adding bromine to a refluxing solution of phenanthrene in carbon tetrachloride. This is the starting-point of 9-substituted phenanthrenes, e.g, when heated with cuprous cyanide at 260℃, 9-bromophenanthrene forms the corresponding cyano-compound; this may be hydrolysed to phenanthrene-9-carboxylic acid. Phenanthrene undergoes the Friedel-Crafts reaction mainly in the 3-, and to a small extent, in the 2-position. It is chloromethylated in the 9-position. When nitrated, phenanthrene gives a mixture of three mononitro-derivatives, the 3-isomer predominating. Sulphonation of phenanthrene gives a mixture of 1-, 2-, 3- and 9-phenanthrenesulphonic acids, and the ratio of these isomers depends on the temperature.
9-Bromophenanthrene Preparation Products And Raw materials
- Raw materialsPhenanthrene
- Preparation Products9-CYANOPHENANTHRENE
- Bromobenzene Anthracene Phenanthrene 3,8-Dibromophenanthroline 3-Bromophenanthrene-9,10-dicarbimide 2,7-Dibromophenanthrene BROMOPHENANTHRENE Ethidium bromide (3-BROMO-2,4,6-TRIMETHYLPHENYLCARBAMOYL)METHYLIMINODIACETIC ACID 2,7-Dibromo-9,10-phenanthrenedione 4-Bromophenanthrene 3-Acetyl-9-bromophenanthrene 3-BROMOPHENANTHRENE 1-bromophenathrene 9,10-DibromoPhenanthrene 6,12-Dibromochrysene 4-bromopyrene 9-Bromophenanthrene
9-BromophenanthreneSupplierMore
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- Company Name:Meryer (Shanghai) Chemical Technology Co., Ltd.
- Tel:21-61259100-
- Email:sh@meryer.com
- Company Name:INTATRADE GmbH
- Tel:+49 3493/605464
- Email:sales@intatrade.de
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General Description of 9-Bromophenanthrene
Aug 16，2019