PCN-224(H)金属有机骨架

配位金属	Zr
配体	四羧基苯基卟啉H2TCPP
孔径	1.9nm
孔容	1.59cm3/g
比表面	BET比表面2600m2/g

荧光:激发波长430nm，发射波长652nm，显示红光 空气中持久稳定，水溶液和酸性-弱碱溶液中较为稳定（PH0-1；热分解温度约>400℃ PCN-224(Co)对CO2/环氧丙烷偶联反应表现出高催化活性 [1] Construction of Ultrastable Porphyrin Zr Metal–Organic Frameworks through Linker Elimination. https://doi.org/10.1021/ja408084j
[2] Size-Controlled Synthesis of Porphyrinic Metal–Organic Framework and Functionalization for Targeted Photodynamic Therapy. https://doi.org/10.1021/jacs.6b00007
[3] Cancer Cell Membrane Camouflaged Cascade Bioreactor for Cancer Targeted Starvation and Photodynamic Therapy. https://doi.org/10.1021/acsnano.7b02533
[4] Enhanced photocatalytic activity and photothermal effects of cu-doped metal-organic frameworks for rapid treatment of bacteria-infected wounds. https://doi.org/10.1016/j.apcatb.2019.118248
[5] Light-Promoted CO₂ Conversion from Epoxides to Cyclic Carbonates at Ambient Conditions over a Bi-Based Metal–Organic Framework. https://doi.org/10.1021/acscatal.0c05145